公开(公告)号：US06509290B1

公开(公告)日：2003-01-21

申请号：US09617714

申请日：2000-07-17

申请人： Stephen N. Vaughn ,  Luc R. M. Martens ,  Keith H. Kuechler ,  Albert E. Schweizer

发明人： Stephen N. Vaughn ,  Luc R. M. Martens ,  Keith H. Kuechler ,  Albert E. Schweizer

IPC分类号： B01J27182

CPC分类号： B01J29/005 ,  B01J29/85 ,  B01J2229/26 ,  B01J2229/42 ,  C10G3/45 ,  C10G3/49 ,  C10G2300/4081 ,  C10G2300/708 ,  C10G2400/20 ,  Y02P30/20 ,  Y02P30/42 ,  Y10S423/30 ,  Y10S502/514

摘要： Disclosed is a molecular sieve catalyst which contains molecular sieve-containing attrition particles and virgin molecular sieve, the attrition particles having been recycled from a catalyst manufacture process or from a reaction system. The catalyst can be used in a variety of catalytic reaction processes. A desired process is making olefins from an oxygenate feedstock. The recovery and use of the attrition particles in the catalyst is beneficial in minimizing waste, thereby reducing problems relating to both environmental and economic constraints.

摘要翻译： 公开了一种分子筛催化剂，其含有含分子筛的磨损颗粒和原始分子筛，磨损颗粒已经从催化剂制备方法或从反应体系再循环。 催化剂可用于各种催化反应过程。 所需的方法是从含氧化合物原料制备烯烃。 在催化剂中回收和使用磨耗颗粒有利于最小化废物，从而减少与环境和经济限制有关的问题。

公开(公告)号：US06316683B1

公开(公告)日：2001-11-13

申请号：US09391770

申请日：1999-09-08

申请人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

发明人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

IPC分类号： C07C120

CPC分类号： B01J37/08 ,  B01J29/85 ,  B01J2229/24 ,  B01J2229/40 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G2300/4018 ,  C10G2400/20 ,  Y02P30/42 ,  C07C11/02

摘要： This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within the molecular sieve; shielding the catalytic sites to protect from loss of catalytic activity; and contacting the protected sieve in its activated state with an oxygenate feedstock under conditions effective to produce an olefin product before undesirable loss of catalytic activity. Undesirable loss in catalytic activity occurs when activated molecular sieve contacting the oxygenate feedstock has a methanol uptake index of at least 0.15.

公开(公告)号：US5151173A

公开(公告)日：1992-09-29

申请号：US455658

申请日：1989-12-21

申请人： Stephen N. Vaughn ,  Michael Siskin ,  Alan Katritzky ,  Glen Brons ,  Steve N. Reynolds ,  Claude C. Culross ,  Dan R. Neskora

发明人： Stephen N. Vaughn ,  Michael Siskin ,  Alan Katritzky ,  Glen Brons ,  Steve N. Reynolds ,  Claude C. Culross ,  Dan R. Neskora

IPC分类号： C10G1/00

CPC分类号： C10G1/00

摘要： This invention is directed to a process for pretreating coal preliminary to a primary liquefaction or hydroconversion block. In the process, a coal feed, slurried in a solvent, is reacted with carbon monoxide in the presence of a chemical promoter at an elevated temperature and pressure. The promoter enhances the depolymerization and hydrogenation of the coal during pretreatment.

摘要翻译： 本发明涉及一种用于预处理初级液化或加氢转化阻挡物的煤的方法。 在此过程中，在升高的温度和压力下，在化学助催化剂存在下，将一种在溶剂中浆化的煤料与一氧化碳反应。 该促进剂在预处理期间增强了煤的解聚和氢化。

公开(公告)号：US07763765B2

公开(公告)日：2010-07-27

申请号：US11698511

申请日：2007-01-26

申请人： Keith H. Kuechler ,  James H. Beech ,  Doron Levin ,  Stephen N. Vaughn ,  Stephen H. Brown

发明人： Keith H. Kuechler ,  James H. Beech ,  Doron Levin ,  Stephen N. Vaughn ,  Stephen H. Brown

IPC分类号： C07C1/00

CPC分类号： C07C1/20 ,  B01J29/90 ,  B01J38/06 ,  C07C2529/85 ,  C08F10/00 ,  C10G3/49 ,  C10G3/57 ,  C10G3/62 ,  C10G2300/308 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/802 ,  C10G2300/805 ,  C10G2400/20 ,  Y02P20/584 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02 ,  C08F2/00

摘要： A gas-solids reaction system is provided for improving product recovery in a multiple reactor reaction system. An oxygenate feedstock, desirably of high concentration in oxygenate, is reacted with a catalyst having a low to modest acidity and a Si/Al2 ratio of from 0.10 to 0.32. The reaction occurs in a reaction zone of a fluidized bed reactor at an oxygenate partial pressure of at least 45 psia and a reactor gas superficial velocity of at least 10 ft/s, conveying catalyst through the reaction zone to a circulation zone. The catalyst undergoes displacement with an inert gas in the circulation zone at a displacement gas superficial velocity of at least 0.03 m/s, after which at least a portion, preferably a large portion is returned to the reaction zone. The catalyst has a residence time in the circulation zone of at least twice that of the residence time of catalyst in the reaction zone. Extraordinary catalyst activity at high olefin selectivity results despite insignificant changes in coke on catalyst and coke yield when compared to lower pressure operations.

摘要翻译： 提供了一种气体 - 固体反应系统，用于改善多反应器反应体系中的产物回收。 含氧化合物中期望含有高浓度的含氧化合物原料与低至中等酸度和Si / Al 2比为0.10至0.32的催化剂反应。 反应在流化床反应器的反应区中发生，氧化分压至少为45psia，反应器气体表观速度为至少10ft / s，将催化剂通过反应区输送到循环区。 催化剂在循环区中以惰性气体置换，位移气体空速为至少0.03m / s，此后至少一部分，优选大部分返回到反应区。 催化剂在循环区中的停留时间至少是催化剂在反应区中的停留时间的两倍。 尽管与较低压力操作相比，尽管催化剂上的焦炭和焦炭产率都没有显着变化，但是在高烯烃选择性方面具有特殊的催化剂活性。

公开(公告)号：US20090018378A1

公开(公告)日：2009-01-15

申请号：US12136843

申请日：2008-06-11

申请人： Luc R. M. Martens ,  Stephen N. Vaughn ,  John R. Shutt

发明人： Luc R. M. Martens ,  Stephen N. Vaughn ,  John R. Shutt

IPC分类号： C07C1/00

CPC分类号： C10G3/62 ,  B01J29/90 ,  B01J2038/005 ,  C10G3/49 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/703 ,  C10G2300/802 ,  C10G2400/20 ,  Y10S585/906 ,  Y10S585/91

摘要： This invention, in one embodiment, is drawn to a process for forming olefin product by contacting an oxygenate with an olefin-forming catalyst under supercritical conditions to form an olefin product. This invention also relates to methods for activating molecular sieve catalyst, regenerating molecular sieve catalyst, and forming and/or disposing a co-catalyst within a molecular sieve catalyst, each under supercritical conditions.

摘要翻译： 在一个实施方案中，本发明涉及通过在超临界条件下使含氧物与形成烯烃的催化剂接触以形成烯烃产物来形成烯烃产物的方法。 本发明还涉及分子筛催化剂的活化方法，再生分子筛催化剂，以及在分子筛催化剂中，在超临界条件下形成和/或配置助催化剂。

公开(公告)号：US07345213B2

公开(公告)日：2008-03-18

申请号：US10615753

申请日：2003-07-09

申请人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

发明人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

IPC分类号： C01C1/00 ,  B01J27/82

CPC分类号： B01J29/85 ,  B01J37/08 ,  B01J2229/24 ,  B01J2229/40 ,  B23K1/002 ,  B23K2101/06 ,  C07C1/20 ,  C07C2529/85 ,  Y02P30/20 ,  Y10S502/514 ,  Y10S585/906 ,  C07C11/02

摘要： This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within the molecular sieve; shielding the catalytic sites to protect from loss of catalytic activity; and contacting the protected sieve in its activated state with an oxygenate feedstock under conditions effective to produce an olefin product before undesirable loss of catalytic activity. Undesirable loss in catalytic activity occurs when activated molecular sieve contacting the oxygenate feedstock has a methanol uptake index of at least 0.15.

摘要翻译： 本发明涉及从含氧化合物原料制备烯烃产物的方法和保护硅铝磷酸盐分子筛的催化活性的方法。 所述方法包括提供在分子筛内具有催化位点的硅铝磷酸盐分子筛; 屏蔽催化部位以防止催化活性的丧失; 并且在有效产生烯烃产物的条件下，在不期望的催化活性丧失之前，将处于其活化状态的受保护筛与含氧化合物原料接触。 当活化分子筛与含氧化合物原料接触的甲醇吸收指数至少为0.15时，催化活性就会出现不希望的损失。

公开(公告)号：US06844476B2

公开(公告)日：2005-01-18

申请号：US10192206

申请日：2002-07-10

申请人： Stephen N. Vaughn ,  Peter G. Ham ,  Keith H. Kuechler

发明人： Stephen N. Vaughn ,  Peter G. Ham ,  Keith H. Kuechler

IPC分类号： B01J29/04 ,  B01J29/85 ,  B01J29/90 ,  B01J38/12 ,  C07C1/20 ,  C07C11/02 ,  C10G3/00 ,  C07C4/06

CPC分类号： C07C11/02 ,  B01J29/04 ,  B01J29/85 ,  B01J29/90 ,  B01J38/12 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G3/57 ,  C10G3/62 ,  C10G2300/1088 ,  C10G2300/4093 ,  C10G2300/708 ,  C10G2400/20 ,  Y02P20/584 ,  Y02P30/42

摘要： A method for converting heavy olefins present in a product stream exiting a first reaction zone into light olefins and carbonaceous deposits on a catalyst without separation of the heavy olefins from the product stream exiting the first reaction zone. The method comprises creating the product stream exiting the first reaction zone, the product stream exiting the first reaction zone comprising the heavy olefins, moving the product stream exiting the first reaction zone to a second reaction zone without separation of the heavy olefins from the product stream exiting the first reaction zone, and contacting the product stream exiting the first reaction zone with the catalyst under conditions effective to form the light olefins, the contacting causing the carbonaceous deposits to form on at least a portion of the catalyst.

摘要翻译： 将离开第一反应区的产物流中存在的重质烯转化成轻质烯烃和催化剂上的碳质沉积物的方法，而不将重质烯烃与离开第一反应区的产物流分离。 该方法包括产生离开第一反应区的产物流，离开包含重烯烃的第一反应区的产物流将离开第一反应区的产物流移动到第二反应区，而不将重质烯烃与产物流​​分离 离开第一反应区，并在有效形成轻质烯烃的条件下使离开第一反应区的产物流与催化剂接触，使得在至少一部分催化剂上形成碳质沉积物。

公开(公告)号：US06768034B2

公开(公告)日：2004-07-27

申请号：US10339044

申请日：2003-01-09

申请人： Shun C. Fung ,  Keith H. Kuechler ,  Jeffrey S. Smith ,  Nicolas P. Coute ,  Stephen N. Vaughn ,  Chunshe Cao

发明人： Shun C. Fung ,  Keith H. Kuechler ,  Jeffrey S. Smith ,  Nicolas P. Coute ,  Stephen N. Vaughn ,  Chunshe Cao

IPC分类号： C07C120

CPC分类号： C07C1/20 ,  C07C2529/85 ,  Y02P30/42 ,  C07C11/02

摘要： Disclosed is a catalytic method for operating an oxygenate to olefins conversion reaction to provide a substantial quantity of prime olefin in the product. The product is provided by operating within desired parameters of weight hourly space velocity and oxygenate partial pressure. Operating the reaction to supply oxygenate at an oxygenate proportion index of at least 0.5, and controlling weight hourly space velocity and molar flow rate of oxygenate to the reactor to maintain a partial pressure-velocity compensation factor of at least 0.1 psia−1hr−1, a prime olefin selectivity of at least 45 wt. % can be maintained.

摘要翻译： 公开了一种用于操作含氧化合物至烯烃转化反应以在产品中提供大量初烯烃的催化方法。 该产品通过在重时小时空间速度和含氧化合物分压的期望参数内操作来提供。 操作该反应以以含氧化合物比例指数为至少0.5提供含氧化合物，并控制含氧化合物与反应器的重量时空速和摩尔流速以保持至少0.1psia -1小时的分压力 - 速度补偿系数 <-1>，至少45重量％的主要烯烃选择性。 可以维持％。

公开(公告)号：US06740790B2

公开(公告)日：2004-05-25

申请号：US10145003

申请日：2002-05-14

申请人： Keith H. Kuechler ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Shun C. Fung ,  Nicolas P. Coute ,  Jeffrey Scott Smith ,  James R. Lattner ,  Jeffrey L. White ,  Teng Xu ,  William L. Kuechler, Sr. ,  Machteld M. Mertens ,  Cornelius W. M. Van Oorschot

发明人： Keith H. Kuechler ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Shun C. Fung ,  Nicolas P. Coute ,  Jeffrey Scott Smith ,  James R. Lattner ,  Jeffrey L. White ,  Teng Xu ,  William L. Kuechler, Sr. ,  Machteld M. Mertens ,  Cornelius W. M. Van Oorschot

IPC分类号： C07C1207

CPC分类号： C10G50/00 ,  B01J29/85 ,  B01J29/90 ,  B01J35/0006 ,  B01J2229/123 ,  C10G3/49 ,  C10G3/57 ,  C10G3/62 ,  C10G2300/1022 ,  C10G2300/1029 ,  C10G2300/4018 ,  C10G2300/708 ,  C10G2400/02 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P30/42

摘要： Disclosed is a method for making olefin product from an oxygenate-containing feedstock. In the method, a silicoaluminophosphate molecular sieve catalyst is contacted with the oxygenate-containing feedstock in a reactor at an average catalyst feedstock exposure index of at least 1.0. The method produces lower coke yield and provides an olefin product which is low in C1-C4 paraffin content. The invention is particularly effective in producing an olefin product having a very low propane content.

摘要翻译： 公开了一种从含氧化合物的原料制备烯烃产物的方法。 在该方法中，将硅铝磷酸盐分子筛催化剂在反应器中与含氧化合物的原料接触，其平均催化剂原料暴露指数为至少1.0。 该方法产生较低的焦炭产量，并提供C1-C4链烷烃含量低的烯烃产物。 本发明在生产丙烷含量非常低的烯烃产物方面特别有效。

公开(公告)号：US06717023B2

公开(公告)日：2004-04-06

申请号：US10350502

申请日：2003-01-24

申请人： James R. Lattner ,  Stephen N. Vaughn ,  Keith H. Kuechler ,  David C. Skouby ,  Hsiang-Ning Sun

发明人： James R. Lattner ,  Stephen N. Vaughn ,  Keith H. Kuechler ,  David C. Skouby ,  Hsiang-Ning Sun

IPC分类号： C07C1207

CPC分类号： C10G3/60 ,  B01J29/85 ,  B01J29/90 ,  B01J38/30 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G3/62 ,  C10G2300/4018 ,  C10G2300/4081 ,  C10G2300/802 ,  C10G2400/20 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/02

摘要： The present invention provides a method for converting a feed containing oxygenates to olefins and comprises the following steps: providing a feed including an oxygenate; contacting the feed in a reactor apparatus with a catalyst including a molecular sieve, the contacting taking place under conditions effective to convert the oxygenate to a product including a light olefin, the conditions including a gas superficial velocity of at least two meters per second at at least one point in the reaction zone; and recirculating a first portion of the catalyst to recontact the feed.

摘要翻译： 本发明提供一种将含有含氧物的进料转化为烯烃的方法，包括以下步骤：提供包含含氧化合物的进料; 将反应器装置中的进料与包含分子筛的催化剂接触，在有效地将含氧化合物转化为包含轻质烯烃的产物的条件下进行接触，所述条件包括在至少两米/秒的气体空塔速度 反应区至少有一点; 并再循环催化剂的第一部分以重新进料。