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公开(公告)号：US5405718A
公开(公告)日：1995-04-11
申请号：US952743
申请日：1992-11-30
申请人： Tooraj Hashemi
发明人： Tooraj Hashemi
CPC分类号： H01M10/26 , H01M4/48 , H01M4/5825
摘要： Ceramic electrodes of cadmium germanate and other ternary oxide materials, provide electrodes for secondary battery cells. Open circuit voltages of 1.5 volts are attainable. The absence of crystallographic phase changes on charge/discharge is noted and renders possible the use of solid electrolytes, possibly in a unitary ceramic structure.
摘要翻译： PCT No.PCT / GB91 / 00876 Sec。 371日期：1992年11月30日 102（e）日期1992年11月30日PCT提交1991年5月31日PCT公布。 WO91 / 19327 PCT出版物 日期1991年12月12日。锗酸镉和其他三元氧化物材料的电极为二次电池提供电极。 1.5伏的开路电压是可以实现的。 注意到在充电/放电时不存在晶体相变，并且可能使用固体电解质，可能在一体的陶瓷结构中。
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公开(公告)号：US5378550A
公开(公告)日：1995-01-03
申请号：US153416
申请日：1993-11-15
CPC分类号： H01G9/022 , H01M10/08 , H01M10/26 , H01M6/166 , H01M8/08 , H01M2300/0002 , H01M6/16 , H01M6/181 , H01M8/1016 , Y02E60/13
摘要： Electrolytes for power sources, particularly alkaline and acidic power sources, comprising benzene polysulfonic acids and benzene polyphosphonic acids or salts of such acids.
摘要翻译： 用于电源的电解质，特别是碱性和酸性电源，包括苯多磺酸和苯多膦酸或这些酸的盐。
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公开(公告)号：US5077149A
公开(公告)日：1991-12-31
申请号：US674186
申请日：1991-03-25
申请人： Munehisa Ikoma , Masashi Enokido , Yasuko Ito , Shingo Tsuda
发明人： Munehisa Ikoma , Masashi Enokido , Yasuko Ito , Shingo Tsuda
CPC分类号： H01M10/345 , H01M10/26 , H01M2/361 , H01M4/383 , H01M4/52 , Y02E60/124 , Y10T29/49115
摘要： A nickel/hydrogen storage battery comprises a nickel positive electrode having nickel oxide as a main active material, a negative electrode mainly composed of a hydrogen absorbing alloy capable of carrying out the electrochemical hydrogen absorbing and desorbing reaction, an alkaline electrolyte, and a separator, a zinc compound being contained in the nickel positive electrode, the negative electrode and the separator.The content of the zinc compound in terms of zinc oxide is 30-500 mg per Ah of battery capacity in the nickel positive electrode and 0.3-15 mg in the negative electrode and the separator.Thus, the expansion of the nickel positive electrode can be inhibited and the electrolyte retention of the negative electrode and the separator can be improved and the cycle life of the battery can be prolonged.
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64.发明授权Alkaline zinc battery having improved shelf-life, rechargeability, charge retention and capacity retention 失效碱性锌电池具有改善的保质期，再充电性，电荷保持性和容量保持性
公开(公告)号：US4948684A
公开(公告)日：1990-08-14
申请号：US235127
申请日：1988-08-23
摘要： An alkaline zinc battery having a zinc electrode comprising a copper-containing conductor embedded in a zinc-rich active and immersed in a concentrated alkaline electrolyte containing a benzotriazole to suppress dissolution of copper in the electrolyte when the cell is fully discharged.
摘要翻译： 一种具有锌电极的碱性锌电池，其包含嵌入富含锌的活性物质中的含铜导体并浸渍在含有苯并三唑的浓缩碱性电解质中，以在电池完全放电时抑制铜在电解质中的溶解。
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65.发明授权Enhanced charge retention electrochemical hydrogen storage alloys and an enhanced charge retention electrochemical cell 失效增强的电荷保留电化学储氢合金和增强的电荷保持电化学电池
公开(公告)号：US4728586A
公开(公告)日：1988-03-01
申请号：US947162
申请日：1986-12-29
IPC分类号： C22C19/00 , C01B3/00 , C22C19/05 , H01M2/16 , H01M4/24 , H01M4/38 , H01M10/26 , H01M10/28 , H01M10/30 , H01M10/34 , H01M4/86 , H01M12/06
CPC分类号： C01B3/0078 , C01B3/0031 , H01M10/26 , H01M10/345 , H01M4/242 , H01M4/383 , Y02E60/327 , Y10S420/90
摘要： A high charge retention, reversible, multicomponent, multiphase, electrochemical hydrogen storage alloy comprising titanium, vanadium, zirconium, nickel, and chromium. The hydrogen storage alloy is capable of electrochemically charging and discharging hydrogen in alkaline aqueous media. In one preferred exemplification the hydrogen storage alloy comprises(Ti.sub.2-x Zr.sub.x V.sub.4-y Ni.sub.y).sub.1-z Cr.sub.zwhere 0.0 is less than x is less than 1.5, 0.6 is less than y is less than 3.5, and z is an effective amount less than 0.20. Also disclosed is a rechargeable, electrochemical cell utilizing a negative electrode formed of the alloy.
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公开(公告)号：US4224391A
公开(公告)日：1980-09-23
申请号：US75408
申请日：1979-09-14
申请人： Morris Eisenberg
发明人： Morris Eisenberg
CPC分类号： H01M10/26
摘要： A battery having a zinc or zinc alloy anode, a metal oxide or hydroxide cathode and an alkaline electrolyte comprising a solution of a salt formed by the reaction of one or more acids selected from the group consisting of boric acid, phosphoric acid and arsenic acid with an alkali or earth alkali hydroxide present in a sufficient amount to produce a stoichiometric excess of hydroxide to acid in the range of 0.02 to 3.0 equivalents per liter.
摘要翻译： 具有锌或锌合金阳极，金属氧化物或氢氧化物阴极的电池和碱性电解质，其包含通过一种或多种选自硼酸，磷酸和砷酸的酸与砷酸反应形成的盐的溶液与 碱金属或碱土金属氢氧化物以足够的量存在，以产生化学计量过量的氢氧化物至0.02至3.0当量/升范围内的酸。
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公开(公告)号：US4195120A
公开(公告)日：1980-03-25
申请号：US957387
申请日：1978-11-03
摘要： Hydrogen evolution in cells having zinc anodes is reduced or eliminated by incorporating in the cell a surfactant which is a complex phosphate ester of a surfactant of the ethylene oxide-adduct type. This surfactant is added in such a manner that, directly or upon wetting of the anode by the electrolyte, there is an adsorption of surfactant on the surface of the zinc anode material, whereby hydrogen evolution is inhibited. The surfactant is desirably present in the cell in an amount of from 0.001% to 5% by weight of the zinc component of the cell.
摘要翻译： 通过在细胞中加入作为环氧乙烷加成物类型的表面活性剂的复合磷酸酯的表面活性剂，可以减少或消除具有锌阳极的细胞中的氢析出。 以这样的方式加入该表面活性剂，即直接或通过电解液润湿阳极，在锌阳极材料的表面上吸附表面活性剂，从而抑制析氢。 表面活性剂理想地以电池的锌成分的0.001重量％〜5重量％的量存在于电池中。
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68.发明授权
公开(公告)号：US4015053A
公开(公告)日：1977-03-29
申请号：US636603
申请日：1975-12-01
CPC分类号： H01M10/4214 , H01M10/26 , H01M2/38
摘要： An improvement in accumulator batteries having a zinc anode and an oxide cathode (e.g., nickel oxide or silver oxide cathode) is disclosed. The zinc anode and/or separator part between the anode and cathode is vibrated at a frequency and amplitude sufficient to inhibit dendrite growth on the zinc anode. The electrolyte contains excess zinc such that solid zinc oxide is present in the fully charged condition. The separator may be provided with circulation enhancement means. The resulting batteries have long life with a large number of charging and discharging cycles.
摘要翻译： 公开了具有锌阳极和氧化物阴极（例如，氧化镍或氧化银阴极）的蓄电池的改进。 阳极和阴极之间的锌阳极和/或隔板部分以足以抑制锌阳极上的枝晶生长的频率和幅度振动。 电解质含有过量的锌，使得固体氧化锌以完全充电的状态存在。 分离器可以设置有循环增强装置。 所产生的电池具有长时间的充电和放电循环。
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公开(公告)号：US3944430A
公开(公告)日：1976-03-16
申请号：US73582
申请日：1970-09-18
申请人： Tien Shuey Lee
发明人： Tien Shuey Lee
摘要： A rechargeable galvanic cell having a zinc anode and a zinc-containing electrolyte which comprises an aqueous alkaline or aqueous acidic medium containing dissolved zinc ions and a quaternary ammonium compound for suppressing zinc dendrite formation during the charging cycle.
摘要翻译： 具有锌阳极和含锌电解质的可充电电池，其包含含有溶解的锌离子的碱性或含水酸性介质水溶液和用于在充电循环期间抑制锌枝晶形成的季铵化合物。
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公开(公告)号：US3853625A
公开(公告)日：1974-12-10
申请号：US27103472
申请日：1972-07-12
申请人： UNION CARBIDE CORP
发明人： LOUZOS D
CPC分类号： H01M10/26 , C25C1/16 , H01M4/02 , H01M4/38 , Y10S75/952
摘要： Stable, high surface area, virtually pure zinc filaments and in particular zinc fibers and needles having a unique crystal structure consisting essentially of one or more single crystals preferentially orientated with an ''''a'''' axis parallel to the axis of the filament. The zinc fibers and needles are prepared by the electrolysis of a soluble zinc salt-containing electrolyte solution under conditions of extremely high cathode current density. Galvanic cell anodes are fabricated using the zinc fibers or needles by compression molding techniques.
摘要翻译： 稳定的高表面积，实际上纯锌丝，特别是具有独特晶体结构的锌纤维和针，该晶体结构基本上由一个或多个单晶组成，优选以平行于丝的轴线的“a”轴取向。 通过在极高的阴极电流密度的条件下电解含可溶性含锌盐的电解质溶液来制备锌纤维和针。 使用锌纤维或针通过压缩成型技术制造电镀细胞阳极。
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