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    Partial combustion process for manufacturing a purified gas containing hydrogen and carbon monoxide
    61.
    发明授权
    Partial combustion process for manufacturing a purified gas containing hydrogen and carbon monoxide 失效
    用于制造含有氢气和一氧化碳的净化气体的部分燃烧过程

    公开(公告)号：US4007129A

    公开(公告)日：1977-02-08

    申请号：US525799

    申请日：1974-11-21

    Applicant: Jaap E. Naber ,  Bernardus H. Mink

    Inventor： Jaap E. Naber ,  Bernardus H. Mink

    IPC: C10G9/38 ,  B01D53/14 ,  C01B3/36 ,  C01B3/50 ,  C01B3/52 ,  C01B2/02 ,  C01B2/14

    CPC classification number: C01B3/36 ,  B01D53/14 ,  C01B3/50 ,  C01B2203/0465 ,  C01B2203/0475 ,  C01B2203/0485 ,  Y02P20/129

    Abstract: An improved process for manufacture of a purified gas containing hydrogen and carbon monoxide is described wherein a fuel is partially combusted in a reactor to produce a crude gas product containing soot, ash and contaminating gases such as HCN, H.sub.2 S and COS, the crude gas product is subsequently cooled in a waste heat boiler and the cooled gas is washed in a scrubber to remove the entrained soot particles. In this improved process, removal of soot, ash and gaseous contaminants from the cooled crude gas product is facilitated by washing the cooled gas in a scrubber with an aqueous salt solution containing at least 10% by weight of an alkaline water-soluble salt, which salt solution is subsequently regenerated by removal of absorbed gases and suspended solids (soot and ash) and recycled to the scrubber.

    Abstract translation: 描述了一种用于制造含有氢气和一氧化碳的净化气体的改进方法，其中燃料在反应器中部分燃烧以产生含有烟灰，灰分和污染气体的原油产品，例如HCN，H 2 S和COS，原油产品 随后在废热锅炉中冷却，并将冷却的气体在洗涤器中洗涤以除去夹带的烟灰颗粒。 在该改进方法中，通过用含有至少10重量％碱性水溶性盐的盐水溶液洗涤洗涤器中的冷却气体来促进从冷却的粗气体产物中除去烟灰，灰分和气态污染物， 盐溶液随后通过去除吸收的气体和悬浮固体（烟灰和灰分）并再循环到洗涤器中再生。

    Production of methane-rich gas
    62.
    发明授权
    Production of methane-rich gas 失效
    生产富甲烷气

    公开(公告)号：US3922148A

    公开(公告)日：1975-11-25

    申请号：US47070174

    申请日：1974-05-16

    Applicant: TEXACO DEVELOPMENT CORP

    Inventor： CHILD EDWARD T

    IPC: C07B61/00 ,  C01B3/22 ,  C01B3/36 ,  C07C1/00 ,  C07C1/02 ,  C07C1/04 ,  C07C7/00 ,  C07C9/04 ,  C07C67/00 ,  C10G9/38 ,  C10J3/46 ,  C10L3/00 ,  C10J3/06

    CPC classification number: C10L3/00 ,  C01B3/22 ,  C01B3/36 ,  C07C1/0485 ,  C07C7/00 ,  C07C9/04 ,  C07C2521/04 ,  C07C2523/755 ,  Y02A50/2327

    Abstract: This is an improved continuous process for producing a clean methane-rich gas stream without the concomitant formation of particulate carbon which would ordinarily decrease the efficiency of the process and shorten the life of the catalyst. By-product superheated steam is simultaneously produced at a maximum temperature. The product stream may have a methane content up to 98 to 99 mole % or higher and a gross heating value up to 1000 BTU per SCF or more. Process steps include partial oxidation of a hydrocarbonaceous fuel under operating conditions that produce a synthesis gas containing 10 to 30 mole % methane (dry and CO2free basis) and a H2/CO mole ratio of 2.6 or higher, and reacting the methane-rich process gas stream in one to three catalytic methanation stages under critical operating conditions that increase the methane content in the process gas stream stepwise up to 98 mole % or higher without incipient soot formation for each corresponding CH4 content of the feed as one proceeds from one methanation step to another. Heat from the highly exothermic methanation reaction is used to make valuable by-product superheated steam. The product gas may be burned without polluting the atmosphere.

    Abstract translation: 这是一种用于生产清洁的富甲烷气流而不伴随形成颗粒碳的改进的连续方法，这通常会降低该方法的效率并缩短催化剂的使用寿命。 在最高温度下同时生产副产物过热蒸汽。 产物流可以具有高达98至99摩尔％或更高的甲烷含量和高达1000BTU / SCF或更高的总热值。 工艺步骤包括在产生含有10至30摩尔％甲烷（基于干和无CO2的基础）和H2 / CO摩尔比为2.6或更高的合成气的操作条件下的烃类燃料的部分氧化，以及使富甲烷 在一至三个催化甲烷化阶段的过程气流在临界操作条件下，其逐步增加工艺气体流中甲烷含量高达98％（摩尔）或更高，而不会因为一种甲烷化进行的每种相应CH4含量的烟灰形成 一步到另一个 来自高放热甲烷化反应的热量用于制造有价值的副产物过热蒸汽。 产品气体可能在不污染大气的情况下燃烧。

    Process for the partial combustion of hydrocarbonaceous fuels to produce substantially soot-free gases
    63.
    发明授权
    Process for the partial combustion of hydrocarbonaceous fuels to produce substantially soot-free gases 失效
    用于部分燃烧石油燃料以生产大量无烟气的方法

    公开(公告)号：US3868331A

    公开(公告)日：1975-02-25

    申请号：US37099673

    申请日：1973-06-18

    Applicant: SHELL OIL CO

    Inventor： VAN LOOKEREN CAMPAGNE NICOLAAS

    IPC: C10J3/72 ,  C01B3/02 ,  C01B3/22 ,  C01B3/36 ,  C10G9/38 ,  C10K1/02 ,  C10K3/00 ,  C01B2/14

    CPC classification number: C01B3/22 ,  C01B3/36 ,  Y02P20/129

    Abstract: The soot content of a hydrogen and carbon monoxide-containing gas mixture obtained by the partial combustion of a hydrocarbonaceous fuel is substantially reduced by passing the partially-combusted gases through a soot-conversion zone maintained at an elevated temperature and pressure, and retarding the passage of soot particles through the zone for a sufficient period of time that the soot is substantially converted to carbon monoxide. An apparatus suitable for effecting soot-conversion is also disclosed.

    Abstract translation: 通过使部分燃烧的气体通过保持在升高的温度和压力下的烟灰转化区，通过烃类燃料的部分燃烧获得的含氢和一氧化碳的气体混合物的烟灰含量大大降低，并且阻止通道 的烟灰颗粒通过该区段持续足够的时间，使得烟灰基本上转化为一氧化碳。 还公开了适用于进行烟灰转化的装置。

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