摘要:
A semifinished leather product is produced from an animal hide by pretanning with the use of a chromium-free tanning agent and of a clay mineral which, after stirring for 30 minutes in water at 50° C. at a circumferential rotor speed of from 5 to 25 m/s, has a number average particle diameter of less than 2 μm or a bimodal particle size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 μm and a second, coarser fraction whose number average particle diameter is less than 5 μm, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, a proportion of the first, finely divided fraction being from 10 to 90% by weight, and drying of the pretanned animal hide to a water content of from 5 to 45%, based on the total weight of the semifinished leather product.
摘要:
Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an α-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.
摘要:
Leather is prepared by tanning animal skins with a poly(glycidylamine) such as trigycidyl isocyanurate. After retannage with vegetable tannins, it is possible to obtain both a mineral-free and aldehyde-free white leather having Ts >85° C. and suitable for automotive internal trim and a mineral-free and aldehyde-free high thermal stable organic leather having Ts >100° C. and suitable for shoe production.
摘要:
The present invention relates to fatliquoring agents for leathers, skins or hides, which contain neutral halogen-free organic phosphorus compounds, and the use of such fatliquoring agents for the flame-retardant treatment of leather and a process for fatliquoring in the production of flame-retardant leather, skin or hides.
摘要:
A method of treating aldehyde-tanned biological tissue minimizes in vivo calcification and reduces cytotoxicity without impairing the mechanical strength of the tanned tissue. The method includes the step of treating the aldehyde-tanned biological tissue with at least one liquid polyol having the formula: ##STR1## where R is CH.sub.2 OH or an alkyl group, and R' is H, an alkyl group or an O-acyl where the acyl is C.sub.2 -C.sub.9 or a carboxyalkyl; or ##STR2## where R is H or an alkyl group, and R' is H, an alkyl group, O-alkyl or O-carboxyalkyl. Preferred polyols are propylene glycol, 1,3-propanediol, 2,3-butylene glycol and glycerol, and the polyol is preferably a diol.
摘要:
A tanning agent formulation obtained by reacting 1 mole of an aliphatic .omega.,.omega.'-dialdehyde having 2-8 carbon atoms in the form of an aqueous solution of about 3-60% strength with about 0.2-4 moles of a hydroxy compound of the formulaR.sub.1 --O--[(C.sub.2 H.sub.4 O).sub.x --(C.sub.3 H.sub.6 O).sub.y --C.sub.4 H.sub.8 O).sub.z].sub.n --Hwherebyn is an integer from 0 to 10,x+y+z is an integer from 1 to 20, wherein the alkoxy groups may be arranged in any order, andR.sub.1 is H, C.sub.1 -C.sub.12 alkyl, or C.sub.1 C.sub.12 alkylhaving one or more hydroxyl groups,wherein n is not 0 for R.sub.1 .dbd.His disclosed. Pelts pretanned with the formulation have improved mold resistance and are free of tanning metal salts and formaldehyde.
摘要:
Copolymers which are obtainable by free radical copolymerization of (a) C.sub.8 -C.sub.40 -alkyl vinyl ethers, if necessary as a mixture with not more than 50 mol % of C.sub.8 -C.sub.40 -monoolefins, with (b) ethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic anhydrides at from 80.degree. to 300.degree. C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, subsequent solvolysis of the anhydride groups of the copolymers and partial or complete neutralization of the carboxyl groups formed during the solvolysis, in an aqueous medium by means of a base, and which are present in the form of aqueous dispersions or solutions, are used as agents for imparting water repellency to leathers and skins.
摘要:
Leather treatment agent containing a mixture a) of a carboxylic acidX--COOH Iwherein X represents--[R--CO--Z--(R'--Z).sub.a ].sub.b --CO--R--COOH 1or--R"--(Z--R').sub.c --Z--CO--R--COOH 2and the symbols have the meaning described in more detail in the description, and b) of a compound containing at least one primary, secondary or tertiary amino group, with a molecular weight of 200-20,000, are used in processes for tanning, pretanning, retanning, dyeing or fat liquoring pelts or pretanned leather or fully tanned leather.
摘要:
Reversible treated hides are obtained by a process for treating animal skins. The process includes physiochemical operations, such as tanning, retanning, and finishing, to provide an aniline, semi-aniline, or pigmented hair-side appearance on the flesh side of the skin. By providing reversible skins in accordance with the process, finished leather articles can be manufactured without the necessity of providing linings.
摘要:
The novel compounds, sulfonated alkylphenoxy acetones. In dyeing nylon textiles, with acid dyes, barre' is reduced by using these novel compounds as a dye leveler.