公开(公告)号：US5279613A

公开(公告)日：1994-01-18

申请号：US829565

申请日：1992-02-05

Applicant: Ortwin Schaffer ,  Herbert Bay ,  Karl Stork ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

Inventor： Ortwin Schaffer ,  Herbert Bay ,  Karl Stork ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

IPC: C14C9/00 ,  C14C11/00

CPC classification number: C14C9/00

Abstract: Copolymers which are obtainable by free radical copolymerization of (a) C.sub.8 --C.sub.40 -monoolefins with (b) ethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic anhydrides by mass polymerization at from 80.degree. to 300.degree. C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, subsequent solvolysis of the anhydride groups of the copolymers and partial or complete neutralization of the carboxyl groups formed during the solvolysis, in an aqueous medium by means of a base, and which are present in the form of aqueous dispersions or solutions, are used as agents for rendering leathers and skins water-repellent.

Abstract translation: 共聚物可以通过（a）C8-C40-单烯烃与（b）烯键式不饱和C4-C8-二羧酸酐在80摄氏度至300摄氏度下进行大量聚合而自由基共聚获得，得到分子量为 500至20,000g / mol，随后溶剂分解共聚物的酸酐基团，并在溶剂分解期间形成的羧基部分或完全中和，在水性介质中通过碱，并以水分散体的形式存在 或溶液，用作皮革和皮肤防水剂的制剂。

公开(公告)号：US4959077A

公开(公告)日：1990-09-25

申请号：US243072

申请日：1988-09-12

Applicant: Franz-Dieter Martischius ,  Hans P. Rath ,  Hans-Henning Vogel ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

Inventor： Franz-Dieter Martischius ,  Hans P. Rath ,  Hans-Henning Vogel ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

IPC: C10L1/234 ,  C08F8/44 ,  C10L1/18 ,  C10L1/192 ,  C10L1/195 ,  C10L1/196 ,  C10L1/22 ,  C10L1/236 ,  C10L10/08 ,  F02B1/04 ,  F02B75/02

CPC classification number: C10L1/2364 ,  C08F8/44 ,  C10L1/1955 ,  C10L1/1966 ,  F02B1/04 ,  F02B2075/027

Abstract: A fuel for gasoline engines contains a small amount of a copolymer of an olefin of from 2 to 40 carbon atoms and/or a cycloolefin of from 3 to 10 carbon atoms with maleic anhydride and/or a copolymer of an alkyl vinyl ether of from 1 to 30 carbon atoms in the alkyl group and/or a cycloalkyl vinyl ether of from 3 to 10 carbon atoms in the alkyl group with maleic anhydride and/or a copolymer of an alkyl vinyl ether of from 1 to 30 carbon atoms in the alkyl group and/or a cycloalkyl vinyl ether of from 3 to 10 carbon atoms in the alkyl group and an olefin of from 2 to 40 carbon atoms and/or a cycloolefin of from 3 to 10 carbon atoms with maleic anhydride having a total molecular weight of from 500 to 20,000 g per mole, the carboxyl groups on the copolymer having been wholly or partly converted with an alkali metal or alkaline earth metal to form an alkali metal or alkaline earth metal salt and the remaining carboxyl groups having been converted with an alcohol and/or an amine of up to 50 carbon atom into the corresponding ester and/or amide groups and/or ammonium salts.

Abstract translation: 汽油发动机的燃料含有少量的含有2-40个碳原子的烯烃和/或3-10个碳原子的烯烃与马来酸酐和/或烷基乙烯基醚共聚物的共聚物，其中共聚物为1 烷基中的至少30个碳原子和/或烷基中具有3至10个碳原子的环烷基乙烯基醚与烷基中的马来酸酐和/或1至30个碳原子的烷基乙烯基醚的共聚物 和/或烷基中具有3至10个碳原子的环烷基乙烯基醚和2至40个碳原子的烯烃和/或3至10个碳原子的环烯烃与马来酸酐的总分子量为 每摩尔500至20,000g，共聚物中的羧基已经用碱金属或碱土金属完全或部分转化，以形成碱金属或碱土金属盐，剩余的羧基已被醇和/ 或高达50的胺 碳原子进入相应的酯和/或酰胺基和/或铵盐。

公开(公告)号：US4375565A

公开(公告)日：1983-03-01

申请号：US311669

申请日：1981-10-15

Applicant: Norbert Greif ,  Erhard Klahr ,  Wolfgang Trieselt

Inventor： Norbert Greif ,  Erhard Klahr ,  Wolfgang Trieselt

IPC: C07C43/11 ,  C11D1/72 ,  C07C43/03 ,  C07C43/10

CPC classification number: C11D3/0026 ,  C07C43/11 ,  C11D1/721

Abstract: The subject invention relates to compositions of matter having the following structural formula: ##STR1## In this formula, R.sup.1 represents a C.sub.8 -C.sub.20 alkyl radical, R.sup.2 stands for a C.sub.1 -C.sub.5 alkyl radical, and n is a number, 4 through 15. These compounds are low foaming and have acceptable biodegradability. They are particularly useful in the formulation of automatic dishwashing detergents.

Abstract translation: 本发明涉及具有以下结构式的物质组合物：在该式中，R 1表示C 8 -C 20烷基，R 2表示C 1 -C 5烷基，n表示4〜15的数 这些化合物具有低发泡性和可接受的生物降解性。 它们在配制自动洗碗洗涤剂时特别有用。

公开(公告)号：US4229174A

公开(公告)日：1980-10-21

申请号：US974621

申请日：1978-12-27

Applicant: Paul Boerzel ,  Peter Freyberg ,  Norbert Greif ,  Rudi Widder

Inventor： Paul Boerzel ,  Peter Freyberg ,  Norbert Greif ,  Rudi Widder

IPC: D06P1/52 ,  C09B67/00

CPC classification number: D06P1/5221

Abstract: A process for dyeing textile materials, containing natural and/or synthetic fibers, in an aqueous liquor by means of dyes which are sparingly soluble or insoluble in water, in the presence of dyeing assistants, wherein the dispersant used is a water-soluble sulfonic acid which is derived from a random copolymer of olefins of 3 to 6 carbon atoms and styrene and/or substituted styrenes and/or their alkali metal salts or ammonium salts.

Abstract translation: 在染色助剂存在下，通过在水中微溶或不溶于水的染料在含水液体中染色包含天然和/或合成纤维的纺织材料的方法，其中使用的分散剂是水溶性磺酸 其衍生自具有3至6个碳原子的烯烃的无规共聚物和苯乙烯和/或取代的苯乙烯和/或其碱金属盐或铵盐。

公开(公告)号：US5266165A

公开(公告)日：1993-11-30

申请号：US955270

申请日：1992-10-01

Applicant: Arnold DeClercq ,  Walter Denzinger ,  Norbert Greif ,  Heinrich Hartmann ,  Knut Oppenlaender ,  Ulrich Riebeling

Inventor： Arnold DeClercq ,  Walter Denzinger ,  Norbert Greif ,  Heinrich Hartmann ,  Knut Oppenlaender ,  Ulrich Riebeling

IPC: C08F8/32 ,  C08F8/44 ,  C08F10/00 ,  C08F210/00 ,  D21H17/16 ,  D21H19/16 ,  D21H17/45 ,  C08F8/30 ,  C08F222/06 ,  D21H21/16

CPC classification number: D21H17/16 ,  C08F8/44

Abstract: Abstract of the Disclosure: Copolymers of (a) C.sub.12 - to C.sub.24 -monoolefins and (b) maleic anhydride or itaconic anhydride, having molecular weights of from 800 to 100,000 g/mol, in the form of partially or completely neutralized semiamides with morpholine, in aqueous solution or dispersion, can be used as sizes for paper.

Abstract translation: 公开的摘要：（a）C12-至C24-单烯烃和（b）分子量为800至100,000g / mol的马来酸酐或衣康酸酐的共聚物为部分或完全中和的具有吗啉的半酰胺形式， 在水溶液或分散体中，可用作纸张的尺寸。

公开(公告)号：US5009670A

公开(公告)日：1991-04-23

申请号：US352418

申请日：1989-05-16

Applicant: Franz-Dieter Martischius ,  Hans-Henning Vogel ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

Inventor： Franz-Dieter Martischius ,  Hans-Henning Vogel ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

IPC: C10L1/224 ,  C10L1/196 ,  C10L1/197 ,  C10L1/24 ,  C10L1/26 ,  C10L1/30 ,  C10L10/08 ,  F02B1/04

CPC classification number: C10L10/04 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/2468 ,  C10L1/2675 ,  C10L10/08 ,  F02B1/04

Abstract: Fuels for gasoline engines contain small amounts of copolymers of alkyl (meth)-acrylates where the alkyl radical is of 8 to 40 carbon atoms and/or vinyl esters of carboxylic acids of 8 to 40 carbon atoms and monoethylenically unsaturated mono- and/or dicarboxylic acids of 3 to 12 carbon atoms and/or monoethylenically unsaturated compounds having sulfo and/or phosphonic acid groups, having a total molecular weight of from 500 to 20,000 g per mole, some or all of the carboxyl, sulfo and phosphonic acid groups of the copolymers having been reacted with an alkali or alkaline earth with formation of the alkali metla salts or alkaline earth metal salts and the remainder of the acid groups having been reacted with ammonia and/or amines of not more than 50 carbon atoms to give the corresponding amide groups and/or ammonium salts.

Abstract translation: 汽油发动机的燃料含有少量的（甲基）丙烯酸烷基酯（其中烷基为8〜40个碳原子）和/或碳原子数为8〜40的羧酸的乙烯基酯和单烯属不饱和单 - 和/或二羧酸的共聚物 3至12个碳原子的酸和/或具有磺基和/或膦酸基团的单烯属不饱和化合物，总分子量为每摩尔500至20,000克，部分或全部羧基，磺基和膦酸基团 已经与碱金属或碱土金属反应形成碱金属盐或碱土金属盐，其余的酸基已经与不超过50个碳原子的氨和/或胺反应得到相应的酰胺 基团和/或铵盐。

公开(公告)号：US4767707A

公开(公告)日：1988-08-30

申请号：US889392

申请日：1986-07-25

Applicant: Stefan Marcinowski ,  Axel Sanner ,  Chung-Ji Tschang ,  Wolfgang Ladner ,  Norbert Greif

Inventor： Stefan Marcinowski ,  Axel Sanner ,  Chung-Ji Tschang ,  Wolfgang Ladner ,  Norbert Greif

IPC: C12N11/08 ,  C07K17/08 ,  C12N11/04

CPC classification number: C12N11/04

Abstract: Enzymes are immobilized by mixing the following components with one another in aqueous solution:(a) an enzyme or a dispersed microorganism,(b) a water-soluble glycidyl ether, prepared by subjecting from 1 to 30 equivalents of an epoxide of the formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, methyl or ethyl, to an addition reaction with 1 equivalent (based on OH groups) of a polyfunctional alcohol of 2 to 6 carbon atoms or of a mono- or disaccharide to produce an adduct, reacting the adduct with epichlorohydrin and, if required, then carrying out cyclization to give the epoxide, and(c) a water-soluble amine possessing two or more NH groups, if necessary in a partially neutralized form,and allowing the mixture thus obtained to gel.

Abstract translation: 通过在水溶液中将以下组分彼此混合来固定酶：（a）酶或分散的微生物，（b）水溶性缩水甘油醚，其通过将1至30当量的式I的环氧化物 （I）其中R 1，R 2和R 3各自为氢，甲基或乙基，与1当量（基于OH基）的2至6个碳原子的多官能醇或单糖或二糖的加成反应 以产生加合物，使加合物与表氯醇反应，并且如果需要，然后进行环化以得到环氧化物，和（c）具有两个或更多个NH基团的水溶性胺，如果需要，以部分中和的形式，并允许 由此获得的混合物凝胶化。

公开(公告)号：US4496439A

公开(公告)日：1985-01-29

申请号：US565217

申请日：1983-12-23

Applicant: Norbert Greif ,  Knut Oppenlaender ,  Albert Hettche ,  Christos Vamvakaris

Inventor： Norbert Greif ,  Knut Oppenlaender ,  Albert Hettche ,  Christos Vamvakaris

IPC: C25D3/22

CPC classification number: C25D3/22

Abstract: In an aqueous acidic plating bath for the electrolytic deposition of zinc, which contains conventional conductive salts, brighteners and surfactants, one of the surfactants is a surfactant of the formula I ##STR1## where R.sup.1 is C.sub.4 -C.sub.20 -alkyl, R.sup.2 is identical to R.sup.1 or is hydrogen, X and Y are each a radical --SO.sub.3 H, where the hydrogen atom can be replaced by an alkali metal or alkaline earth metal atom or by one equivalent of zinc and n is an integer from 5 to 50.

Abstract translation: 在含有常规导电盐，增白剂和表面活性剂的电解沉积锌的酸性电镀浴中，一种表面活性剂是式I的表面活性剂，其中R 1是C 4 -C 20 - 烷基，R 2与 R1或为氢，X和Y各自为-SO 3 H基团，其中氢原子可被碱金属或碱土金属原子替代，或由1当量的锌代替，n为5至50的整数。

公开(公告)号：US4200733A

公开(公告)日：1980-04-29

申请号：US25174

申请日：1979-03-29

Applicant: Johannes Perner ,  Norbert Greif ,  Rolf Fikentscher ,  Paul Diessel

Inventor： Johannes Perner ,  Norbert Greif ,  Rolf Fikentscher ,  Paul Diessel

IPC: A01N59/12 ,  C08G65/26 ,  C11D3/48 ,  C08L71/02 ,  C08G65/32

CPC classification number: C11D3/485 ,  A01N59/12 ,  C08G65/2609

Abstract: Iodine-containing block copolymers which contain from 5 to 25% by weight of bonded iodine, and which are based on iodine-free compounds of the formula IR(AB).sub.z Iwhereif z=1, R is hydrogen or a C.sub.1 -C.sub.18 -aliphatic hydrocarbon radical,if z.noteq.1, R is a z-valent aliphatic hydrocarbon radical of 2 to 8 carbon atoms, which may or may not carry up to z ethylene oxide units,z is from 1 to 6,A is a polymer or copolymer block of from 4 to 100 1,4-butylene oxide units and from 0 to 25 ethylene oxide units andB is a polymer or copolymer block of from 0 to 50 1,4-butylene oxide units and from 1 to 100 ethylene oxide units, the proportion of 1,4-butylene oxide being >50 mole % in A and

Abstract translation: 含有5〜25重量％的结合碘的含碘嵌段共聚物，其基于式IR（AB）zI的无碘化合物，其中如果z = 1，R为氢或C1-C18- 脂族烃基，如果z NOTEQUAL 1，R是2至8个碳原子的z价脂族烃基，其可以或可以不携带至z环氧乙烷单元，z为1-6，A为聚合物或 共聚物嵌段为4至100个1,4-环氧丁烷单元和0至25个环氧乙烷单元，B为0至50个1,4-环氧丁烷单元和1至100个环氧乙烷单元的聚合物或共聚物嵌段 ，A环中1,4-环氧丁烷的比例> 50摩尔％，B中的<50摩尔％

公开(公告)号：US5124181A

公开(公告)日：1992-06-23

申请号：US582329

申请日：1990-09-14

Applicant: Ortwin Schaffer ,  Herbert Bay ,  Karl Stork ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

Inventor： Ortwin Schaffer ,  Herbert Bay ,  Karl Stork ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

IPC: C08L33/04 ,  C08L33/06 ,  C09K3/18 ,  C14C9/00

CPC classification number: C14C9/00

Abstract: Copolymers which containa) from 50 to 90% by weight of C.sub.8 -C.sub.40 -alkyl methacrylates, vinyl esters of C.sub.8 -C.sub.40 -carboxylic acids or mixtures thereof andb) from 10 to 50% by weight of monoethylenically unsaturated C.sub.3 -C.sub.12 -carboxylic acids, monoethylenically unsaturated dicarboxylic anhydrides, monoesters or monoamides of monoethylenically unsaturated C.sub.4 -C.sub.12 -dicarboxylic acids, amides of C.sub.3 -C.sub.12 -monocarboxylic acids or mixtures thereofas copolymerized units and have molecular masses of from 500 to 30,000 are used in at least partially neutralized form in aqueous solution or dispersion for making leather and furs water repellent.

Abstract translation: 包含a）50-90％重量的甲基丙烯酸C 8 -C 40烷基酯，C 8 -C 40羧酸的乙烯基酯或其混合物的共聚物，和b）10-50％重量的单烯属不饱和C 3 -C 12羧酸 酸，单烯键式不饱和二羧酸酐，单烯属不饱和C4-C12-二羧酸的单酯或单酰胺，C3-C12-一元羧酸的酰胺或其混合物作为共聚单元，分子量为500至30,000，至少部分中和 在水溶液或分散体中形成皮革和毛皮防水剂。