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1.发明授权Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom 失效自分散固化性环氧树脂，由其制成的分散体和由其制成的涂料组合物
公开(公告)号：US5604269A
公开(公告)日：1997-02-18
申请号：US296281
申请日：1994-08-25
IPC分类号： C08G59/22 , C08G59/06 , C08G59/18 , C08G59/50 , C08G59/62 , C09D163/00 , C08K3/20 , C08L63/02
CPC分类号： C08G59/066 , C08G59/184 , C08G59/621 , C09D163/00
摘要： A self-dispersing curable epoxy composition is prepared upon contacting (a) 1.0 reactive equivalents of an epoxy resin, (b) between 0.005 and 0.5 reactive equivalents of an amine-epoxy adduct, and optionally (c) from about 0.01 to 1.0 reactive equivalents of a polyhydric phenol, wherein the amine-epoxy adduct is formed upon contacting 1.0 equivalents of an aliphatic polyepoxide and greater than 1.0 but no more than about 2.5 reactive equivalents of a polyoxyalkyleneamine. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.
摘要翻译： 通过使（a）1.0反应当量的环氧树脂接触，（b）0.005至0.5当量的胺 - 环氧加合物的反应当量和任选的（c）约0.01至1.0当量的反应等同物，制备自分散可固化的环氧组合物 的多元酚，其中胺 - 环氧加合物是在接触1.0当量的脂族聚环氧化物和大于1.0但不超过约2.5反应当量的聚氧化烯胺时形成的。 自分散固化型环氧树脂与水混合时形成水分散体。 当固化时，分散体可用作涂料组合物。
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2.发明授权Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom 失效自分散固化性环氧树脂，由其制成的分散体和由其制成的涂料组合物
公开(公告)号：US5565505A
公开(公告)日：1996-10-15
申请号：US255732
申请日：1994-06-14
IPC分类号： C08G59/14 , C08G59/06 , C08G59/10 , C08G59/22 , C08G59/50 , C08L63/00 , C08K3/20 , C08L63/02
CPC分类号： C08L63/00 , C08G59/066 , C08G59/10 , C08G59/226
摘要： A self-dispersing curable epoxy composition is prepared upon contacting (a) 1.0 reactive equivalents of an epoxy resin, (b) from about 0.01 to 1.0 reactive equivalents of a polyhydric phenol, and (c) between 0.005 and 0.025 reactive equivalents of an amine-epoxy adduct, wherein the amine-epoxy adduct is formed upon contacting 1.0 equivalents of an aliphatic polyepoxide and between 0.3 and 0.9 reactive equivalents of a polyoxyalkyleneamine. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.
摘要翻译： 通过使（a）1.0反应当量的环氧树脂（b）约0.01-1.0当量的多元酚与（c）0.005至0.025反应性当量的胺接触来制备自分散可固化的环氧组合物 - 环氧加合物，其中胺 - 环氧加合物在接触1.0当量的脂族聚环氧化物和0.3至0.9当量的聚氧化烯胺反应时形成。 自分散固化型环氧树脂与水混合时形成水分散体。 当固化时，分散体可用作涂料组合物。
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3.发明授权
公开(公告)号：US4256871A
公开(公告)日：1981-03-17
申请号：US31113
申请日：1979-04-18
申请人： John G. Papalos , Ronald W. Kavchok
发明人： John G. Papalos , Ronald W. Kavchok
CPC分类号： C08G16/0237 , B01F17/0057 , C08F2/26 , C08F36/04
摘要： A condensation product of naphthalenesulfonic acid and linear alkyl benzenesulfonic acid having an alkyl moiety of from about 4 to about 20 carbon atoms with formaldehyde or salt thereof is useful as a secondary emulsifier and co-emulsifier in synthetic polymer latex processes. From about 0.05 to about 5 parts by weight of the condensation product per 100 parts by weight of latex monomer is used as a secondary emulsifier and from about 0.5 to about 5 parts by weight of the condensation product per 100 parts by weight of latex monomer is used as a co-emulsifier. Additionally, products can be prepared which have been found to be biodegradable. Use of these condensation products eliminates pollution caused by a secondary emulsifier or co-emulsifier in polymer manufacture effluent.
摘要翻译： 萘磺酸和具有约4至约20个碳原子的烷基部分的直链烷基苯磺酸与甲醛或其盐的缩合产物可用作合成聚合物胶乳方法中的第二乳化剂和辅助乳化剂。 每100重量份胶乳单体约0.05至约5重量份的缩合产物用作二次乳化剂，每100重量份胶乳单体约0.5至约5重量份的缩合产物为 用作共乳化剂。 此外，可以制备已被发现是可生物降解的产品。 使用这些冷凝产品消除了聚合物制造废水中二次乳化剂或辅助乳化剂引起的污染。
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公开(公告)号：US4054617A
公开(公告)日：1977-10-18
申请号：US651959
申请日：1976-01-23
申请人： John G. Papalos , James M. Kelly
发明人： John G. Papalos , James M. Kelly
CPC分类号： C14C3/18
摘要： Leather treating compositions are prepared which comprise condensed or polymeric alkyl phenol phosphates generally and more particularly a phenol-alkylphenol condensate which is subsequently alkoxylated and phosphated. These compositions may be utilized for leather processing, and specifically for: retanning, lubricating, and imparting water resistance to chrome and/or mineral tanned leather. Additionally, these compositions may be used to effect modifications of base mineral tannages for the purpose of dyeing, bleaching, and fatliquoring leather.
摘要翻译： 制备皮革处理组合物，其通常包含稠合或聚合的烷基酚磷酸盐，更特别是酚烷基酚缩合物，其随后被烷氧基化和磷酸化。 这些组合物可用于皮革加工，特别用于：复鞣，润滑和赋予铬和/或矿物鞣皮革耐水性。 此外，这些组合物可用于对染色，漂白和加脂皮革的目的进行基础矿物鞣制的改性。
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公开(公告)号：USH1712H
公开(公告)日：1998-02-03
申请号：US255493
申请日：1994-06-08
申请人： John G. Papalos , Joseph V. Sinka
发明人： John G. Papalos , Joseph V. Sinka
CPC分类号： C07C69/54
摘要： Radiation-curable compositions containing monoalkyl or mono-aralkyl ether di-acrylates or di-methacrylates of particular ethoxylated and/or propoxylated polyols of formulae I and II have been developed. These polyol derivatives substituted with hydrophobic ether functionalities constitute UV-curable diluents that can be isolated in excellent yields with minimal losses during the manufacturing process.
摘要翻译： 已经开发了包含式I和II的特定乙氧基化和/或丙氧基化多元醇的单烷基或单芳烷基醚二丙烯酸酯或二 - 甲基丙烯酸酯的可辐射固化组合物。 用疏水醚官能团取代的这些多元醇衍生物构成了紫外线固化的稀释剂，可以在制造过程中以最小的损失以优异的产率分离。
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6.发明授权Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom 失效自分散固化性环氧树脂，由其制成的分散体和由其制成的涂料组合物
公开(公告)号：US5652323A
公开(公告)日：1997-07-29
申请号：US470391
申请日：1995-06-06
CPC分类号： C08L63/00 , C08G59/066 , C08G59/10 , C08G59/226
摘要： A self-dispersing curable epoxy composition is prepared upon contacting (a) 1.0 reactive equivalents of an epoxy resin, (b) from about 0.01 to 1.0 reactive equivalents of a polyhydric phenol, and (c) between 0.005 and 0.025 reactive equivalents of an amine-epoxy adduct, wherein the amine-epoxy adduct is formed upon contacting 1.0 equivalents of an aliphatic polyepoxide and between 0.3 and 0.9 reactive equivalents of a polyoxyalkyleneamine. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.
摘要翻译： 通过使（a）1.0反应当量的环氧树脂，（b）约0.01至1.0当量的多元酚反应，和（c）0.005至0.025当量的胺的反应当量来制备自分散可固化的环氧组合物 - 环氧加合物，其中胺 - 环氧加合物在接触1.0当量的脂族聚环氧化物和0.3至0.9当量的聚氧化烯胺反应时形成。 自分散固化型环氧树脂与水混合时形成水分散体。 当固化时，分散体可用作涂料组合物。
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7.发明授权Aqueous self-dispersible epoxy resin based on epoxy-amine adducts containing aromatic polyepoxide 失效基于含有芳族聚环氧化物的环氧 - 胺加合物的水性自分散型环氧树脂
公开(公告)号：US5648409A
公开(公告)日：1997-07-15
申请号：US366343
申请日：1994-12-29
申请人： Kartar S. Arora , David I. Devore , Reuben H. Grinstein , Grannis S. Johnson , John G. Papalos , Shailesh Shah
发明人： Kartar S. Arora , David I. Devore , Reuben H. Grinstein , Grannis S. Johnson , John G. Papalos , Shailesh Shah
IPC分类号： C08G59/06 , C08G59/10 , C08L63/00 , C09D163/00 , C08K3/20
CPC分类号： C08L63/00 , C08G59/066 , C08G59/10 , C09D163/00
摘要： There is disclosed a self-disbursing curable epoxy resin composition comprising the addition product of reactants comprising (a) 1.0 reactive equivalent of an epoxy resin, (b) from about 0.40 to 0.95 reactive equivalents of a polyhydric phenol, and (c) from about 0.005 to 0.5 reactive equivalents of an amine-epoxy adduct comprising the addition product of reactants comprising 1.0 reactive equivalent of an aromatic polyepoxide and from about 0.3 to 0.9 reactive equivalents of a polyoxyalkyleneamine.
摘要翻译： 公开了一种自发式可固化环氧树脂组合物，其包含反应物的加成产物，其包含（a）1.0反应当量的环氧树脂，（b）约0.40至0.95反应性当量的多元酚，和（c）约 0.005至0.5反应当量的胺 - 环氧加合物，其包含反应物的加成产物，其包含1.0反应当量的芳族聚环氧化物和约0.3至0.9反应性当量的聚氧化烯胺。
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公开(公告)号：US4457762A
公开(公告)日：1984-07-03
申请号：US456394
申请日：1983-01-07
申请人： John G. Papalos , Jose L. Villa , Kathy A. Knitter , Arpad Savoly
发明人： John G. Papalos , Jose L. Villa , Kathy A. Knitter , Arpad Savoly
CPC分类号： C10L1/326 , Y10S516/03
摘要： Improved stabilized water slurries of carbonaceous materials are obtained by having present a condensation product or a salt thereof of a substituted phenol sulfonic acid which is(a) an arylphenol sulfonic acid,(b) an aralkylphenol sulfonic acid,(c) an arylphenol sulfonic acid and arylsulfonic acid mixture, or(d) an aralkylphenol sulfonic acid and arylsulfonic acid mixture,condensed with from about 0.5 to about 4.0 moles of formaldehyde per mole of sulfonic acid with the proviso that the weight ratio if substituted phenol sulfonic acid to arylsulfonic acid is from about 0.95:0.05 to about 0.05:0.95 in the mixtures, the condensation product being present in an amount sufficient to reduce viscosity of the water slurry of carbonaceous materials, to stabilize carbonaceous materials in the water network and to improve its pumpability. If desired, an acid form or a salt of the condensation product may be used.
摘要翻译： 通过具有取代苯酚磺酸的缩合产物或其盐，它是（a）芳基苯酚磺酸，（b）芳烷基苯酚磺酸，（c）芳基苯酚磺酸 和芳基磺酸混合物，或（d）芳烷基苯酚磺酸和芳基磺酸混合物，每摩尔磺酸与约0.5至约4.0摩尔甲醛缩合，条件是取代的苯酚磺酸与芳基磺酸的重量比为 在混合物中约0.95:0.05至约0.05:0.95，所述缩合产物的存在量足以降低碳质材料的水浆液的粘度，以稳定水网中的碳质材料并提高其可泵性。 如果需要，可以使用缩合产物的酸形式或盐。
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公开(公告)号：US4297259A
公开(公告)日：1981-10-27
申请号：US147383
申请日：1980-05-07
申请人： John G. Papalos , Ronald W. Kavchok
发明人： John G. Papalos , Ronald W. Kavchok
CPC分类号： C08G16/0237 , B01F17/0057 , C08F2/26 , C08F36/04
摘要： A condensation product of naphthalenesulfonic acid and linear alkylbenzenesulfonic acid having an alkyl moiety of from about 4 to about 20 carbon atoms with formaldehyde or salt thereof is useful as a secondary emulsifier and co-emulsifier in synthetic polymer latex processes. From about 0.05 to about 5 parts by weight of the condensation product per 100 parts by weight of latex monomer is used as a secondary emulsifier and from about 0.5 to about 5 parts by weight of the condensation product per 100 parts by-weight of latex monomer is used as a co-emulsifier. Additionally, products can be prepared which have been found to be biodegradable. Use of these condensation products eliminates pollution caused by a secondary emulsifier or co-emulsifier in polymer manufacture effluent.
摘要翻译： 具有约4-约20个碳原子的烷基部分的萘磺酸和直链烷基苯磺酸与甲醛或其盐的缩合产物可用作合成聚合物胶乳方法中的第二乳化剂和辅助乳化剂。 每100重量份胶乳单体约0.05至约5重量份的缩合产物用作二次乳化剂，每100重量份胶乳单体使用约0.5至约5重量份的缩合产物 用作共乳化剂。 此外，可以制备已被发现是可生物降解的产品。 使用这些冷凝产品消除了聚合物制造废水中二次乳化剂或辅助乳化剂引起的污染。
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10.发明授权Method of reducing barre in synthetic polymide textiles dyed with acid dyes 失效用酸性染料染色的合成聚酰亚胺纺织品中减少棒料的方法
公开(公告)号：US3936268A
公开(公告)日：1976-02-03
申请号：US521548
申请日：1974-11-07
申请人： John G. Papalos
发明人： John G. Papalos
摘要： In dyeing nylon textiles with acid dyes, barre is reduced by using a synergistic mixture of a dye-leveling alkyl sulfonate and a dye-leveling alkyl aryl sulfonate.
摘要翻译： 在用酸性染料染色尼龙纺织品时，通过使用染料平整的烷基磺酸盐和染料均化的烷基芳基磺酸盐的协同混合物来减少巴勒。
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