摘要:
Volume grafted elastomer surfaces and a method for providing a volume grafted elastomer surface on a supporting substrate which includes dissolving a fluoroelastomer in a solvent, adding a nucleophilic dehydrofluorinating agent, preferably an amino silane which acts as both a dehydrofluorinating agent and curing agent, a polymerization initiator and a polyorganosiloxane in amounts sufficient to effect formation of a volume graft elastomer, optionally adding an additional amount of amino silane as a curative in order to ensure complete curing of the volume grafted elastomer, and subsequently providing a layer of the homogeneous volume grafted elastomer solution to the supporting substrate are provided herein.
摘要:
A fuser member comprised of a supporting substrate comprising an outer layer of a volume grafted elastomer, which is a substantially uniform integral interpenetrating network of a hybrid composition of a fluoroelastomer and a polyorganosiloxane, said volume graft having been formed by dehydrofluorination of said fluoroelastomer by a nucleophilic dehydrofluorinating agent, followed by addition polymerization by the addition of an alkene or alkyne functionally terminated polyorganosiloxane and a polymerization initiator; and wherein said outer layer contains a reactive metal oxide in an amount of from about 2 to about 7 weight percent.
摘要:
An electrographic imaging member comprising a supporting substrate and an outer layer of a volume grafted fluoroelastomer comprised of a substantially uniform integral interpenetrating or crosslinked network of a polyorganosiloxane grafted fluoroelastomer.
摘要:
A fuser member for fusing thermoplastic resin toner images to a substrate has an aluminum base member and an elastomer fusing surface of a poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) where the vinylidenefluoride is present in an amount less than 40 mole percent, the elastomer having been cured from a solvent solution thereof with a nucleophilic curing agent soluble in the solution and in the presence of 5 or less than 4 parts by weight of inorganic base per 100 parts of polymer, the inorganic base being effective to at least partially dehydrofluorinate the vinylidenefluoride, and an adhesive layer between the surface of said aluminum base member and the elastomer fusing surface, the adhesive layer having been cured from a solvent solution of a poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) where the vinylidenefluoride is present in an amount less than 40 mole percent and from about 6 to 20 parts by weight per 100 parts by weight of said poly(vinylidenefluoride hexafluoropropylene-tetrafluoroethylene) of an amino silane represented by the formula: ##STR1## where R can be an alkyl group having 1 to 7 carbon atoms; R' can be an alkyl group having 1 to 7 carbon atoms or a polyalkoxyalkyl group of less than 7 carbon atoms; Y is an amino group or an amino substituted alkyl, or a polyamino substituted alkyl, or an alkenylalkoxy amino, or an aryl amino group of less than 15 carbon atoms, h is 1 to 3, b is 0 to 2, q is 1 or 2 and h+b=3.
摘要:
A multilayered member for fusing thermoplastic resin toner images to a substrate in a fuser system of the type wherein a polymeric release agent having functional groups is applied to the surface of the fuser member. The multilayered fuser member has in sequential order a base support member, an adhesive layer comprising a copolymer of vinylidene fluoride and hexafluoropropylene and at least 20% by weight of the adhesive layer of a coupling agent comprising at least one organo functional silaneand an activator, a tie coat layer of active ingredients comprising a copolymer of vinylidene fluoride and hexafluoropropylene and an outer elastomeric fusing surface comprising a copolymer of vinylidene fluoride and hexafluoropropylene and containing a metal oxide present in an amount sufficient to interact with a polymeric release agent having functional groups to provide an interfacial barrier layer between said fusing surface and toner.
摘要:
A fusing assembly for use in an electrostatographic imaging apparatus includes a release agent donor member having a conformable donor surface comprising the crosslinked product of at least one addition curable vinyl terminated or vinyl pendant polyorganosiloxane having the formula: ##STR1## where A,B and R are methyl or vinyl provided the vinyl functionality is at least 2, 0
摘要翻译:用于静电成像设备的定影组件包括具有适形供体表面的脱模剂供体构件,其包含至少一种具有下式的可加成固化的乙烯基封端或乙烯基侧挂聚有机硅氧烷的交联产物:其中A,B和R 提供乙烯基官能度至少为2,0 / s / r = 1,350
摘要:
A novel fuser roll is disclosed which has a rigid core and having coated on the core a thin layer of a composition which comprises the crosslink product of a mixture of about 100 parts by weight of .alpha.,.omega.-hydroxypolydimethylsiloxane, about 128 to 250 parts by weight of finely divided tabular alumina, about 13 to 50 parts by weight of a finely divided iron oxide, together with effective amounts of a crosslinking agent and a crosslinking catalyst.