LITHIUM IRON PHOSPHATE BATTERY
    72.
    发明公开

    公开(公告)号:US20240194871A1

    公开(公告)日:2024-06-13

    申请号:US18279052

    申请日:2022-03-29

    CPC classification number: H01M4/5825 H01M10/052 H01M10/0567 H01M2004/021

    Abstract: Provided is a lithium iron phosphate battery, comprising a positive electrode, a negative electrode and a non-aqueous electrolyte, wherein the positive electrode comprises a positive electrode material layer with a compacted density of 2.3-2.8 g/cc, and the positive electrode material layer comprises a positive electrode active material, the positive electrode active material comprises LiFePO4; the non-aqueous electrolyte comprises a solvent, an electrolyte salt, vinylene carbonate and a compound represented by Structural formula 1; an addition amount of the compound represented by Structural formula 1 is 0.01-5% based on a total mass of the non-aqueous electrolyte being 100%. The lithium iron phosphate battery provided by the application adopts the combination of vinylene carbonate and the compound represented by Structural formula 1, which can inhibit the generation of lithium dendrites and dissolution of Fe, and ultimately improve the high-temperature and safety performance of the High-compacted-density lithium iron phosphate battery.


    A-D-B-E-C  Structural formula 1

    Secondary Battery
    73.
    发明公开
    Secondary Battery 审中-公开

    公开(公告)号:US20240178368A1

    公开(公告)日:2024-05-30

    申请号:US18010818

    申请日:2022-11-16

    CPC classification number: H01M4/134 H01M10/0567 H01M2004/027 H01M2300/0028

    Abstract: The present application provides a secondary battery, including a positive electrode, a negative electrode with a negative electrode material layer, and a non-aqueous electrolyte, the negative electrode material layer comprises a negative electrode active material, and the negative electrode active material comprises a silicon-based material;
    the non-aqueous electrolyte comprises a solvent, an electrolyte salt and an additive, the additives comprises a compound represented by structural formula 1;




    wherein n is 0 or 1, A is selected from C or O, X is selected from






    R1 and R2 are each independently selected from H,
    R1 and R2 are not selected from H at the same time, and X, R1 and R2 comprise at least one sulfur atom;








    the secondary battery meets the following requirements:







    0
    .
    2


    1




    m
    *
    n
    *
    r

    S


    40

    ;




    and 40%≤m≤90%, 0.05%≤n≤2%, 1.2 g/cm3≤r≤1.8 g/cm3, 5%≤S≤30%.

    Method for purifying ethylene carbonate through dynamic crystallization

    公开(公告)号:US11958820B2

    公开(公告)日:2024-04-16

    申请号:US18081715

    申请日:2022-12-15

    CPC classification number: C07D317/38

    Abstract: The present invention relates to the technical field of chemical industry, and in particular to a method for purifying ethylene carbonate through dynamic crystallization, which includes the following steps: adding an ethylene carbonate-containing raw material into a cavity of a crystallization device under a condition of stirring for dynamic crystallization, wherein the crystallization device further includes a jacket attached and circumferentially disposed along the outer wall of the cavity, the jacket is provided with cooling water therein, a temperature of the cooling water is 1-2.5° C. lower than the temperature in the cavity until a granular ethylene carbonate crystal is generated. The present invention using a rake dryer as the crystallization device to realize dynamic crystallization at a certain rotating speed. The technical solution is simple to operate and short in processing cycle, which facilitates improvement in production efficiency and product quality and is suitable for industrial application.

    LINEAR CARBONATE AND PREPARATION METHOD THEREOF

    公开(公告)号:US20230212108A1

    公开(公告)日:2023-07-06

    申请号:US18080682

    申请日:2022-12-13

    CPC classification number: C07C69/96

    Abstract: The present invention relates to the technical field of chemical engineering, and in particular to a linear carbonate and a preparation method thereof, which includes one or more of compounds of structural formula 1 below:




    wherein R1 and R2 are respectively selected from one of alkyl groups containing 1˜4 carbon atoms;
    a hydroxyl concentration of the linear carbonate is no more than 100 ppm, and a free acid conversion rate of a solution with a concentration of 1 mol/L as formulated from the linear carbonate and lithium hexafluorophosphate is less than 1.2 after storage under 25° C. for 30 days. An acidity conversion rate was reduced when lithium hexafluorophosphate is dissolved in the linear carbonate by controlling the hydroxyl concentration, the energy density, discharge capacity, safety performance and service life of a battery can be improved when it's electrolyte solution contains the linear carbonate.

    NON-AQUEOUS ELECTROLYTE FOR LITHIUM-ION BATTERY AND LITHIUM-ION BATTERY

    公开(公告)号:US20220263133A1

    公开(公告)日:2022-08-18

    申请号:US17735109

    申请日:2022-05-02

    Abstract: A non-aqueous electrolyte for a lithium-ion battery and a lithium-ion battery. The non-aqueous electrolyte includes an unsaturated phosphate compound and a cyclic unsaturated carboxylic anhydride compound. The unsaturated phosphate compound has a structure represented by structural formula (4). R13, R11 and R12 are each independently selected from a hydrocarbon group having 1 to 5 carbon atoms, and at least one of R13, R11 and R12 is an unsaturated hydrocarbon group having a double bond or a triple bond. The unsaturated cyclic carboxylic anhydride compound having a structure represented by Structural Formula 5. R14 is selected from the group consisting of an alkenylene group having 2 to 4 carbon atoms or a fluorinated alkenylene group having 2 to 4 carbon atoms. By means of the synergistic effect of two compounds, the non-aqueous electrolyte has excellent high-temperature cycling performance and storage performance, and also has lower impedance and good low-temperature performance.

    Non-aqueous electrolyte for lithium ion battery and lithium ion battery

    公开(公告)号:US11380937B2

    公开(公告)日:2022-07-05

    申请号:US16632862

    申请日:2017-12-28

    Abstract: Provide is a non-aqueous electrolyte for lithium ion battery, comprising a compound represented by structural formula I: In formula I, R1, R2, R3 and R4 are each independently selected from hydrogen atom, fluorine atom, cyano group, hydrocarbyl group or halogenated hydrocarbyl group having 1-5 carbon atoms, oxygen-containing hydrocarbyl group having 1-5 carbon atoms, silicon-containing hydrocarbyl group having 1-5 carbon atoms, X is a —O—R5—CN group, R5 is a hydrocarbyl group or a halogenated hydrocarbyl group having 1-5 carbon atoms, m, n, z and y are integers of 0 or 1, and m+n+y+z≠0. When the non-aqueous electrolyte is used for lithium ion battery, the decomposition of electrolyte on the surface of electrode can be inhibited, and the high-temperature storage performance is improved with less gas generation and small expansion rate, therefore the high-temperature cycle performance and high-temperature storage performance of the battery are effectively improved.

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