公开(公告)号：US5364941A

公开(公告)日：1994-11-15

申请号：US70245

申请日：1993-06-02

申请人： Katsuyoshi Yamakawa ,  Kozo Sato ,  Takashi Suginome

发明人： Katsuyoshi Yamakawa ,  Kozo Sato ,  Takashi Suginome

IPC分类号： C07D495/04 ,  C07D471/04

CPC分类号： C07D495/04

摘要： An intermediate, 5-Acyl-4,5,6,7-tetrahydrothieno [3,2-c ]pyridine- 2-carboxylic acid derivative of the following general formula (I): ##STR1## wherein R.sup.1 represents an acyl group and R.sup.2 represents a hydrogen atom or an alkyl group is useful for synthesizing ticlopidine hydrochloride from an inexpensive, easily available compound in short steps.

摘要翻译： 具有下列通式（I）的中间体5-酰基-4,5,6,7-四氢噻吩并[3,2-c]吡啶-2-甲酸衍生物：其中R 1表示酰基 基团，R 2表示氢原子或烷基可用于从廉价的易于获得的化合物以短步骤合成噻氯匹定盐酸盐。

公开(公告)号：US5292630A

公开(公告)日：1994-03-08

申请号：US18454

申请日：1993-02-16

申请人： Yasuhiro Shimada ,  Kozo Sato

发明人： Yasuhiro Shimada ,  Kozo Sato

IPC分类号： G03C7/305 ,  G03C7/38

CPC分类号： G03C7/30529 ,  G03C7/3835

摘要： A silver halide color photographic material containing one or more imidazotriazole cyan couplers each having an electron attracting group with a .sigma.p of 0.35 or more in at least one layer on the support. The material provides a cyan color image having a sharp light absorption characteristic absorbing light having a relatively long wavelength falling within a narrow wavelength range. The imidazotriazole cyan coupler is of the following structural formula (I): ##STR1## where R.sub.1 represents a hydrogen atom or a substituent; R.sub.2 represents an electron attracting group having a Hammett's constant value .sigma.p of 0.35 or ore; X represents a hydrogen atom or a group released by coupling with an oxidation product of an aromatic primary amine color developing agent; and R.sub.1 or R.sub.2 may also be a divalent group forming a dimer or higher polymer, or they each may be bonded to a polymer chain to form a homopolymer or copolymer.

摘要翻译： 含有一种或多种咪唑并三唑青色成色剂的卤化银彩色照相材料，其各自具有在载体上的至少一层中（Sigma）p为0.35以上的吸电子基团。 该材料提供了具有吸收特征的清晰吸收特征的青色图像，该特征吸收了波长较小的较长波长的光。 咪唑并三唑青色成色剂具有以下结构式（I）：（*化学结构*）（I）其中R1表示氢原子或取代基; R2表示哈米特常数值（Sigma）p为0.35或矿石的吸电子基团; X表示氢原子或通过与芳族伯胺显色剂的氧化产物偶联而释放的基团; 并且R 1或R 2也可以是形成二聚体或更高级聚合物的二价基团，或者它们各自可以与聚合物链结合以形成均聚物或共聚物。

公开(公告)号：US5260181A

公开(公告)日：1993-11-09

申请号：US796359

申请日：1991-11-22

申请人： Kozo Sato ,  Koshin Matsuoka ,  Yoshio Ishii

发明人： Kozo Sato ,  Koshin Matsuoka ,  Yoshio Ishii

IPC分类号： G03C7/38

CPC分类号： G03C7/3815

摘要： There is disclosed a cyan dye-forming coupler represented by formula (I) and a silver color photographic material containing same. ##STR1## wherein EWG represents an electron-attractive group having a Hammett substituent constant .sigma..sub.p value of 0.30 or more, R represents a substituent, l represents an integer of 0 to 2, X represents a hydrogen atom or a group capable of being released upon coupling reaction with the oxidized product of an aromatic primary amine derivative, R and EWG may bond together to form a ring, and when l is 2, two Rs may be the same or different or may bond together to form a ring.

公开(公告)号：US5215871A

公开(公告)日：1993-06-01

申请号：US789020

申请日：1991-11-07

申请人： Kozo Sato ,  Yoshio Ishii

发明人： Kozo Sato ,  Yoshio Ishii

IPC分类号： G03C7/30 ,  G03C7/32 ,  G03C7/34 ,  G03C7/38

CPC分类号： G03C7/3825

摘要： A method of forming a cyan dye image in an exposed silver halide color photographic material comprising a support and a photosensitive silver halide emulsion, said method comprising developing the exposed silver halide color photographic material with a color developing solution containing an aromatic primary amine color developing agent in the presence of a cyan coupler represented by formula (I): ##STR1## wherein EWG.sub.1 and EWG.sub.2 each represents an electron attractive group having a Hammett's substituent constant .sigma..sub.p value of at least 0.30 or;R.sub.1 represents a hydrogen atom or a substituent;R.sub.2 represents a substituent;X represents a hydrogen atom or a group capable of splitting off by a coupling reaction with an oxidation product of an aromatic primary amine color developing agent;R.sub.1 and R.sub.2 may be bonded to each other to form a ring; provided that R.sub.2 must not be a halogen atom; and a silver halide color photographic material containing the cyan dye forming coupler.

公开(公告)号：US5100760A

公开(公告)日：1992-03-31

申请号：US309980

申请日：1989-02-13

申请人： Kozo Sato ,  Soichiro Yamamoto

发明人： Kozo Sato ,  Soichiro Yamamoto

IPC分类号： G03F7/004 ,  G03C1/00 ,  G03C1/498 ,  G03F7/028 ,  G03F7/031 ,  G03F7/06

CPC分类号： G03F7/031 ,  G03C1/00 ,  G03F7/0285

摘要： A light-sensitive material comprising a support and a light-sensitive layer which contains silver halide, a reducing agent, a polymerizable compound and an azo-compound having the following formula:Ri--N.dbd.N--Cpin which Ri is an aryl group or a heterocyclic group, each of which may have one or more substituent groups; Cp is a group having a function of coupling with an oxidation product of the reducing agent. Image-forming methods utilizing the light-sensitive materials are also disclosed.

摘要翻译： 一种感光材料，其包含载体和感光层，其含有卤化银，还原剂，可聚合化合物和具有下式的偶氮化合物：其中R 1是芳基的R 1 -N = N-Cp 或杂环基，其各自可以具有一个或多个取代基; Cp是具有与还原剂的氧化产物偶联的功能的基团。 还公开了利用感光材料的图像形成方法。

公开(公告)号：US5055537A

公开(公告)日：1991-10-08

申请号：US491907

申请日：1990-03-12

申请人： Ken Kawata ,  Kozo Sato ,  Masayoshi Tsuboi

发明人： Ken Kawata ,  Kozo Sato ,  Masayoshi Tsuboi

IPC分类号： C08F38/00 ,  C23C18/20 ,  C23C18/30 ,  H05K3/18

CPC分类号： C23C18/20 ,  C08F38/00 ,  C23C18/30 ,  H05K3/181

摘要： A metal-containing organic polymer produced by the step of polymerizing a compound represented by formula (I):(R--C.tbd.C).sub.l).sub.k k (L) (S).sub.m (I)whereinS represents a hydrogen atom, a hydroxy group, an amino group, a mercapto group, a polyoxyether group, a polyaminoether group, a polythioether group, a sulfino group or a salt thereof, a sulfo group or a salt thereof, a carboxyl group or a salt thereof or a polymerizable group;R represents a metallic atom, a hydrogen atom, or a group --COOM wherein M represents a hydrogen atom or a metallic atom;provided that when R represents a carboxyl group or a hydrogen atom, said compound represented by formula (I) is polymerized in the presence of a metallic salt;L represents a chemical bond or a group having a valency of (k+m); andl, k and m each represents an integer of 1 or more.

公开(公告)号：US4970307A

公开(公告)日：1990-11-13

申请号：US84789

申请日：1987-08-13

申请人： Keiji Takeda ,  Jiro Tsukahara ,  Kozo Sato

发明人： Keiji Takeda ,  Jiro Tsukahara ,  Kozo Sato

IPC分类号： G03C1/61

CPC分类号： G03C1/615

摘要： A process for formation of a base from a base precursor, which comprises decomposing the base precursor in the presence of a catalyst. The base precursor has the following formula (I) or (II):(R.sup.1 --C.tbd.C--CO.sub.2 H).sub.x .multidot.B (I)R.sup.2 (--C.tbd.C--CO.sub.2 H).sub.2 .multidot.B.sub.y (II)wherein R.sup.1 is a monovalent group selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an aralkyl group, an acyl group, an alkoxycarbonyl group, carbamoyl, --CO.sub.2 M (M is an alkali metal) and --CO.sub.2 H.B, each of which may have one or more substituent groups; R.sup.2 is a divalent group selected from the group consisting of an alkylene group, an arylene group and a divalent heterocyclic group, each of which may have one or more substituent groups; B is an organic base; x is 1 when B is a monoacidic base, and x is 2 when B is a diacidic base; and y is 2 when B is a monoacidic base, and y is 1 when B is a diacidic base. The catalyst is selected from the group consisting of silver, a silver compound, copper and a copper compound. A light-sensitive material containing the base precursor and the catalyst is also disclosed.

摘要翻译： 从碱性前体形成碱的方法，其包括在催化剂存在下分解碱前体。 碱前体具有下式（I）或（II）：（R1-C3B2C-CO2H）xxB（I）R2（-C3BcC-CO2H）2xBy（Ⅱ）其中R1是选自 由氢，烷基，环烷基，烯基，炔基，芳基，杂环基，芳烷基，酰基，烷氧基羰基，氨基甲酰基，-CO 2 M（M是碱 金属）和-CO 2 H B，其各自可以具有一个或多个取代基; R2是选自亚烷基，亚芳基和二价杂环基的二价基团，每个可以具有一个或多个取代基; B是有机碱; 当B是一元酸碱时x是1，当B是二酸基时x是2; 并且当B是一元酸碱时y是2，当B是二酸基时y是1。 催化剂选自银，银化合物，铜和铜化合物。 还公开了含有碱前体和催化剂的感光材料。

公开(公告)号：US4927897A

公开(公告)日：1990-05-22

申请号：US214062

申请日：1988-07-01

申请人： Ken Kawata ,  Kozo Sato ,  Masayoshi Tsuboi

发明人： Ken Kawata ,  Kozo Sato ,  Masayoshi Tsuboi

IPC分类号： C08F38/00 ,  C23C18/20 ,  C23C18/30 ,  H05K3/18

CPC分类号： C23C18/20 ,  C08F38/00 ,  C23C18/30 ,  H05K3/181

摘要： A metal-containing organic polymer produced by the step of polymerizing a compound represented by formula (I):(R--C.tbd.C.sub.lk S).sub.m (I)whereinS represents a hydrogen atom, a hydroxy group, an amino group, a mercapto group, a polyoxyether group, a polyaminoether group, a polythioether group, a sulfino group or a salt thereof, a sulfo group or a salt thereof, a carboxyl group or a salt thereof or a polymerizable group;R represents a metallic atom, a hydrogen atom, or a group --COOM wherein M represents a hydrogen atom or a metallic atom;provided that when R represents a carboxyl group or a hydrogen atom, said compound represented by formula (I) is polymerized in the presence of a metallic salt;L represents a chemical bond or a group having a valency of (k+m); andl, k and m each represents an integer of 1 or more.

摘要翻译： 通过使由式（I）表示的化合物：（RC 3BOND ClkS）m（I）聚合的步骤制备的含金属的有机聚合物，其中S表示氢原子，羟基，氨基，巯基， 聚氧醚基，聚氨基醚基，聚硫醚基，亚磺酰基或其盐，磺基或其盐，羧基或其盐或可聚合基团; R表示金属原子，氢原子或-COOM基团，其中M表示氢原子或金属原子; 条件是当R表示羧基或氢原子时，由式（I）表示的所述化合物在金属盐的存在下聚合; L表示化学键或价数为（k + m）的基团。 并且l，k和m各自表示1以上的整数。

公开(公告)号：US4877720A

公开(公告)日：1989-10-31

申请号：US188583

申请日：1988-04-29

申请人： Kozo Sato ,  Shigeru Ohno ,  Sumito Yamada

发明人： Kozo Sato ,  Shigeru Ohno ,  Sumito Yamada

IPC分类号： G03C7/26 ,  C07D231/20 ,  C07D231/56 ,  C08F8/00 ,  C08F246/00 ,  G03C1/04 ,  G03C1/06 ,  G03C7/305 ,  G03C8/56

CPC分类号： G03C7/30541 ,  G03C1/04 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/16

摘要： A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, at least one layer of the silver halide photographic material comprising at least one compound represented by formula (I):PWR--Time--.sub.t --POL (I)wherein PWR represents a group capable of releasing (Time--.sub.t POL upon reduction; Time represents a divalent organic group capable of releasing POL via a subsequent reaction after (Time--.sub.t POL is released from PWR; t is 0 or 1; and POL represents a polymer group.The compound represented by formula (I) is a useful functional polymer whose properties are drastically changed upon reduction and reveal photographically useful function.

摘要翻译： 包含其上具有至少一个卤化银乳剂层的载体的卤化银照相材料，至少一层卤化银照相材料包含至少一种由式（I）表示的化合物：PWR-Time-t-POL（I） 其中PWR表示能够释放的时间（时间tPOL在还原时;时间表示在时间tPOL从PWR释放之后经由随后的反应释放POL的二价有机基团; t表示0或1;并且POL表示聚合物 由式（I）表示的化合物是一种有用的官能聚合物，其性能在还原时显着变化并显示出相关的有用功能。

公开(公告)号：US4830957A

公开(公告)日：1989-05-16

申请号：US105167

申请日：1987-10-07

申请人： Kozo Sato ,  Masashi Takeuchi ,  Takeshi Shibata

发明人： Kozo Sato ,  Masashi Takeuchi ,  Takeshi Shibata

IPC分类号： G03C7/00 ,  C09B29/33 ,  G03C8/10 ,  G03C8/12

CPC分类号： G03C8/10 ,  C09B29/337

摘要： A color light-sensitive material is disclosed. The material is comprised of a support having provided thereon at least one image-forming compound represented by formula (I)(Dye--X).sub.q Y (I)wherein X, Y, q, and Dye are as defined herein. The light-sensitive material shows excellent yellow dye-transferring properties and provides a yellow dye having excellent light fastness.