利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

180 条记录 (耗时 0.031 秒)

    Fluorenyl catalyst compositions and olefin polymerization process
    81.
    发明授权
    Fluorenyl catalyst compositions and olefin polymerization process 有权
    芴基催化剂组合物和烯烃聚合方法

    公开(公告)号：US07514510B2

    公开(公告)日：2009-04-07

    申请号：US11459801

    申请日：2006-07-25

    申请人： Vladimir Marin ,  Abbas Razavi

    发明人： Vladimir Marin ,  Abbas Razavi

    IPC分类号： C08F4/76 ,  C08F4/64

    CPC分类号： C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/15 ,  C08F2500/20 ,  C08F210/16 ,  C08F2500/03 ,  C08F2500/12

    摘要： An olefin polymerization process comprising contacting one or more olefins and a catalyst component in a reaction zone under suitable reaction conditions to form a polyolefin, wherein the catalyst component is characterized by the formula: B(Cp)(Fl)MQ2 wherein M comprises a metal, Q comprises a halogen, an alkyl group or an aryl group or combinations thereof, Cp comprises a cyclopentadienyl group, Fl comprises a fluorenyl group, B is a bridging group that may be characterized by the general formula —YRH wherein Y comprises C or Si and R comprises an alkyl group, an aryl group, a poly-aryl group or combinations thereof.

    摘要翻译： 烯烃聚合方法包括在合适的反应条件下使反应区中的一种或多种烯烃和催化剂组分接触以形成聚烯烃，其中催化剂组分的特征在于下式： 公式“end =”lead“？> B（Cp）（F1）MQ2 <？in-line-formula description =”In-line Formulas“end =”tail“？>其中M包括金属，Q包括卤素， 烷基或芳基或其组合，Cp包含环戊二烯基，Fl包含芴基，B是可以由通式-YRH表征的桥连基团，其中Y包含C或Si，R包括烷基 ，芳基，聚芳基或其组合。

    Preparation and Use of Tetrasubstituted Fluorenyl Catalysts for Polymerization of Olefins
    83.
    发明申请
    Preparation and Use of Tetrasubstituted Fluorenyl Catalysts for Polymerization of Olefins 失效
    用于聚合烯烃的四取代的芴基催化剂的制备和应用

    公开(公告)号：US20080026935A1

    公开(公告)日：2008-01-31

    申请号：US11868033

    申请日：2007-10-05

    申请人： Vladimir Marin ,  Abbas Razavi

    发明人： Vladimir Marin ,  Abbas Razavi

    IPC分类号： B01J31/12

    CPC分类号： C07F7/00 ,  B01J31/2282 ,  B01J2231/122 ,  B01J2531/0263 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/20 ,  C08F2500/12 ,  C08F2500/04 ,  C08F2500/03

    摘要： Catalyst compositions and processes for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Such monomers include ethylene, C3+ alpha olefins and substituted vinyl compounds, such as styrene and vinyl chloride. The polymerization catalyst characterized by the formula B(FluL)MQn in which Flu is a fluorenyl group substituted at at least the 2,7- and 3,6-positions by hydrocarbyl groups, preferably relatively bulky hydrocarbyl groups. L is a substituted or unsubstituted cyclopentadienyl, indenyl or fluorenyl group or a heteroorgano group, XR, in which X is a heteroatom from Group 15 or 16 of the Periodic Table of Elements, such as nitrogen, R is an alkyl group, a cycloalkyl group or an aryl group and B is a structural bridge extending between the groups L and Flu, which imparts stereorigidity to the ligand structure, M is a Group 4 or Group 5 transition metal, such as titanium, zirconium or hafnium and Q is selected from the group consisting of chlorine, bromine, iodine, an alkyl group, an amino group, an aromatic group and mixtures thereof, with n being 1 or 2.

    摘要翻译： 催化剂组合物和用于聚合烯属不饱和单体以生产聚合物的方法，包括共聚物或均聚物。 这些单体包括乙烯，C 3+α-烯烃和取代的乙烯基化合物，例如苯乙烯和氯乙烯。 其中Flu是在至少2,7-和3,6位被烃基取代的芴基的式B（FluL）MQ N n的特征的聚合催化剂，优选相对庞大的烃基 团体 L是取代或未取代的环戊二烯基，茚基或芴基或杂有机基团XR，其中X是元素周期表第15或16族的杂原子，例如氮，R是烷基，环烷基 或芳基，B是在基团L和Flu之间延伸的结构桥，其赋予配体结构立体刚性，M是第4族或第5族过渡金属，例如钛，锆或铪，Q选自 由氯，溴，碘，烷基，氨基，芳族基团及其混合物组成的组，n为1或2。

    Ionic Liquids As Supports
    86.
    发明申请
    Ionic Liquids As Supports 审中-公开
    离子液体作为支撑物

    公开(公告)号：US20070213485A1

    公开(公告)日：2007-09-13

    申请号：US10573901

    申请日：2004-09-23

    申请人： Olivier Lavastre ,  Fabien Bonnette ,  Abbas Razavi

    发明人： Olivier Lavastre ,  Fabien Bonnette ,  Abbas Razavi

    IPC分类号： C08F4/44

    CPC分类号： B01J31/143 ,  B01J31/0284 ,  B01J31/1805 ,  B01J2231/12 ,  B01J2231/20 ,  B01J2531/824 ,  B01J2531/847 ,  C08F110/02 ,  C08F4/7006

    摘要： The present invention discloses a method for preparing a supported catalyst component comprising the steps of: a) providing a halogenated bisimine precursor component of formula (I); b) reacting the halogenated bisimine precursor with an ionic liquid precursor in a solvent to prepare an ionic liquid; c) reacting the ionic liquid prepared in step b) with a metallic complex of formula (II) L2MY2; wherein L is a labile ligand, M is a metal selected from Ni or Pd and Y is a halogen; d) retrieving a single site catalyst component dissolved in an ionic liquid. It also discloses an active catalyst system dissolved in an ionic liquid and its use in the polymerisation of olefins.

    摘要翻译： 本发明公开了一种制备载体催化剂组分的方法，包括以下步骤：a）提供式（I）的卤化双亚胺前体组分; b）使卤化双亚胺前体与离子液体前体在溶剂中反应以制备离子液体; c）将步骤b）中制备的离子液体与式（II）的二价金属络合物反应， 其中L是不稳定的配体，M是选自Ni或Pd的金属，Y是卤素; d）回收溶解在离子液体中的单一位点催化剂组分。 它还公开了溶解在离子液体中的活性催化剂体系及其在烯烃聚合中的用途。

    Group III bridged metallocene based on cyclopentadienyl-fluorenyl ligands
    87.
    发明授权
    Group III bridged metallocene based on cyclopentadienyl-fluorenyl ligands 失效
    基于环戊二烯基 - 芴基配体的III族桥连金属茂

    公开(公告)号：US07241849B2

    公开(公告)日：2007-07-10

    申请号：US10541644

    申请日：2004-01-06

    申请人： Jean-François Carpentier ,  Evgueni Kirillov ,  Abbas Razavi

    发明人： Jean-François Carpentier ,  Evgueni Kirillov ,  Abbas Razavi

    IPC分类号： C08F4/52

    CPC分类号： C08F4/52 ,  C07F17/00 ,  C08F10/00 ,  Y10S526/943

    摘要： The present invention discloses a metallocene catalyst component of formula (Flu-R″-Cp)M(η3-C3R′5)(ether)n (I) wherein Cp is a cyclopentadienyl, substituted or unsubstituted, Flu is a fluorenyl, substituted or unsubstitutted, R″ is a structural bridge between Cp and Flu imparting stereorigidity to the component, M is a metal Group III of the Periodic Table, each R′ is the same or different and is hydrogen or a hydrocarbyl having from 1 to 20 carbon atoms and n is 0, 1 or 2. It further discloses a process for preparing said catalyst component and its used in the controlled polymerisation of polar or non polar monomers.

    摘要翻译： 本发明公开了一种式（Flu-R“-C Cp）M（η3 -OR 3 R 5）5的茂金属催化剂组分， ）（醚）其中Cp是环戊二烯基，取代或未取代的，Flu是芴基，取代或未取代的R“是Cp和Flu赋予组分立体刚性之间的结构桥 M是元素周期表的金属III族，各R'相同或不同，为氢或碳原子数为1〜20的烃基，n为0,1或2.进一步公开了制备所述 催化剂组分及其用于极性或非极性单体的受控聚合。

    Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
    88.
    发明申请
    Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins 审中-公开
    催化剂组分，其制备方法及其作为烯烃聚合中催化剂组分的用途

    公开(公告)号：US20070093623A1

    公开(公告)日：2007-04-26

    申请号：US11638169

    申请日：2006-12-13

    申请人： Abbas Razavi ,  Vladimir Marin ,  Margarito Lopez

    发明人： Abbas Razavi ,  Vladimir Marin ,  Margarito Lopez

    IPC分类号： C08F4/44

    CPC分类号： B01J31/1815 ,  B01J2231/122 ,  B01J2531/842 ,  C07F15/025 ,  C08F10/00 ,  C08F110/02 ,  C08F2500/12 ,  C08F2500/04 ,  C08F2500/20 ,  C08F2500/19 ,  C08F2500/17 ,  C08F4/60089 ,  C08F4/7042

    摘要： Catalyst compositions having Cs symmetry and processes utilizing Cs symmetric catalyst components for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Monomers, which are polymerized or copolymerized include ethylene, C3+ alpha olefins and substituted vinyl compounds, such as styrene and vinyl chloride. The catalyst component is characterized by the formula: wherein M is a Group 4-11 transition metal, n is an integer of from 1-3, Q is halogen or a C1-C2 alkyl group, PY is a pyridinyl group, R′ and R″ are each C1-C20 hydrocarbyl group, A1 is a mononuclear aromatic group, and A2 is a polynuclear aromatic group, such as a terphenyl group. The catalyst component is used with an activating co-catalyst component such as an alumoxane. Also disclosed is a process for the preparation of a pyridinyl-linked bis-amino ligand suitable for use in forming the catalyst component.

    摘要翻译： 具有Cs对称性的催化剂组合物和利用Cs对称催化剂组分用于烯键式不饱和单体聚合以产生聚合物（包括共聚物或均聚物）的方法。 聚合或共聚的单体包括乙烯，C 3 +α烯烃和取代的乙烯基化合物，例如苯乙烯和氯乙烯。 催化剂组分的特征在于下式：其中M是4-11族过渡金属，n是1-3的整数，Q是卤素或C 1 -C 2 烷基，PY是吡啶基，R'和R“各自为C 1 -C 20烃基，A 1， SUB>是单核芳族基团，并且A 2是多核芳族基团，例如三联苯基。 催化剂组分与活化助催化剂组分如铝氧烷一起使用。 还公开了制备适于用于形成催化剂组分的吡啶基连接的双 - 氨基配体的方法。

    Random olefin copolymers
    89.
    发明申请
    Random olefin copolymers 审中-公开
    无规烯烃共聚物

    公开(公告)号：US20070060726A1

    公开(公告)日：2007-03-15

    申请号：US10562719

    申请日：2004-06-28

    申请人： Abbas Razavi

    发明人： Abbas Razavi

    IPC分类号： C08F4/44

    CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/65927 ,  C08F210/06 ,  C08F2500/06

    摘要： Provided is a method for the production of an olefin co-polymer, which method comprises co-polymerising two or more olefin monomers in the presence of a metallocene catalyst, wherein the metallocene catalyst comprises a metallocene having the following formula: R″(CpRm)(FluR′n)MQ2 wherein Cp comprises a cyclopentadienyl ring; Flu comprises a fluorenyl ring; R″ comprises a structural bridge imparting stereorigidity to the component; each R is the same or different and is an organic group; m is an integer of from 1-4; each R′ is the same or different and is an organic group; n is an integer of from 0-8; M is a metal atom from group IVB of the Periodic Table or is vanadium; and each Q is a hydrocarbon having from 1-20 carbon atoms or is a halogen.

    摘要翻译： 提供了一种生产烯烃共聚物的方法，该方法包括在茂金属催化剂存在下共聚两种或多种烯烃单体，其中茂金属催化剂包含具有下式的茂金属：R“'（CpR 其中Cp包含环戊二烯基环;（3）其中Cp包含环戊二烯基环; 流感包含芴环; R“包括赋予组分立体刚性的结构桥; 每个R相同或不同，为有机基团; m为1-4的整数; 每个R'相同或不同，为有机基团; n为0-8的整数; M是元素周期表IVB族的金属原子，或是钒; 并且每个Q是具有1-20个碳原子的烃或是卤素。

    Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins
    90.
    发明申请
    Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins 失效
    四取代芴基催化剂烯烃聚合的制备与应用

    公开(公告)号：US20070043183A1

    公开(公告)日：2007-02-22

    申请号：US11205934

    申请日：2005-08-17

    申请人： Vladimir Marin ,  Abbas Razavi

    发明人： Vladimir Marin ,  Abbas Razavi

    IPC分类号： C08F4/44 ,  B01J31/00 ,  C08F110/06

    CPC分类号： C07F7/00 ,  B01J31/2282 ,  B01J2231/122 ,  B01J2531/0263 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/20 ,  C08F2500/12 ,  C08F2500/04 ,  C08F2500/03

    摘要： Catalyst compositions and processes for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Such monomers include ethylene, C3+ alpha olefins and substituted vinyl compounds, such as styrene and vinyl chloride. The polymerization catalyst characterized by the formula B(FluL)MQn in which Flu is a fluorenyl group substituted at at least the 2,7- and 3,6-positions by hydrocarbyl groups, preferably relatively bulky hydrocarbyl groups. L is a substituted or unsubstituted cyclopentadienyl, indenyl or fluorenyl group or a heteroorgano group, XR, in which X is a heteroatom from Group 15 or 16 of the Periodic Table of Elements, such as nitrogen, R is an alkyl group, a cycloalkyl group or an aryl group and B is a structural bridge extending between the groups L and Flu, which imparts stereorigidity to the ligand structure, M is a Group 4 or Group 5 transition metal, such as titanium, zirconium or hafnium and Q is selected from the group consisting of chlorine, bromine, iodine, an alkyl group, an amino group, an aromatic group and mixtures thereof, with n being 1 or 2.

    摘要翻译： 催化剂组合物和用于聚合烯属不饱和单体以生产聚合物的方法，包括共聚物或均聚物。 这些单体包括乙烯，C 3+α-烯烃和取代的乙烯基化合物，例如苯乙烯和氯乙烯。 其中Flu是在至少2,7-和3,6位被烃基取代的芴基的式B（FluL）MQ N n的特征的聚合催化剂，优选相对庞大的烃基 团体 L是取代或未取代的环戊二烯基，茚基或芴基或杂有机基团XR，其中X是元素周期表第15或16族的杂原子，例如氮，R是烷基，环烷基 或芳基，B是在基团L和Flu之间延伸的结构桥，其赋予配体结构立体刚性，M是第4族或第5族过渡金属，例如钛，锆或铪，Q选自 由氯，溴，碘，烷基，氨基，芳族基团及其混合物组成的组，n为1或2。