公开(公告)号：US20050182211A1

公开(公告)日：2005-08-18

申请号：US10779939

申请日：2004-02-17

Applicant: Sandor Nagy ,  Barbara Tsuie

Inventor： Sandor Nagy ,  Barbara Tsuie

IPC: C08F4/659 ,  C08F10/00 ,  C08F4/44 ,  B01J31/00 ,  C07F15/02

CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F2410/03 ,  C08F4/659 ,  C08F4/7006 ,  C08F4/7081

Abstract: Catalyst systems and methods for olefin polymerization are disclosed. The polymerizations are performed in the presence of a clathrochelate which comprises a transition metla ion and an encapsulating macropolycyclic ligand. At least one of the capping atoms of the macropolycyclic ligand is a Group 3-10 transition metla or a Group 13 atom. When a capping atom is a Group 3-10 transition metal, the clathrochelate can be used with an activator to polymerize olefins. When a capping atom is a Group 13 atom, the clathrachelate can be used as an activator for an olefin polumerization. Clathrochelates allow polyolefin markers to fine tune catalyst reactivity and polyolefin properties.

Abstract translation: 公开了用于烯烃聚合的催化剂体系和方法。 聚合反应在包含过渡金属离子和包封大环多重配体的笼形螯合物存在下进行。 大环配体的至少一个封端原子是3-10族过渡元或13族原子。 当封端原子是3-10族过渡金属时，可以使用活化剂来使烯螯合物与烯烃聚合。 当封端原子是第13族原子时，可以使用该杂环化合物作为烯烃聚合的活化剂。 氯酸铜螯合物允许聚烯烃标记物微调催化剂反应性和聚烯烃性能。

公开(公告)号：US20080249266A1

公开(公告)日：2008-10-09

申请号：US11996139

申请日：2006-07-17

Applicant: Louis Boulanger ,  Olivier Lavastre ,  Sabine Sirol ,  Abbas Razavi

Inventor： Louis Boulanger ,  Olivier Lavastre ,  Sabine Sirol ,  Abbas Razavi

IPC: C08F4/22 ,  C07F11/00 ,  B01J31/18

CPC classification number: C07C251/38 ,  B01J31/14 ,  B01J31/143 ,  B01J31/1805 ,  B01J2231/12 ,  B01J2231/20 ,  B01J2531/0258 ,  B01J2531/60 ,  B01J2531/62 ,  B01J2531/70 ,  B01J2531/80 ,  B01J2531/84 ,  C07D213/38 ,  C07D307/52 ,  C07F15/025 ,  C07F15/045 ,  C07F15/065 ,  C08F10/00 ,  C08F110/02 ,  C08F4/69224 ,  C08F4/7042 ,  C08F4/7081

Abstract: The present invention discloses active oligomerisation and polymerisation catalyst systems based on dioxime ligands.

Abstract translation: 本发明公开了基于二肟配体的活性低聚和聚合催化剂体系。

公开(公告)号：US07371803B2

公开(公告)日：2008-05-13

申请号：US11602897

申请日：2006-11-21

Applicant: Gregory Adam Solan ,  Christopher James Davies

Inventor： Gregory Adam Solan ,  Christopher James Davies

IPC: C08F4/70 ,  C08F4/80

CPC classification number: C07C2/32 ,  B01J31/143 ,  B01J31/146 ,  B01J31/1805 ,  B01J31/1815 ,  B01J2231/122 ,  B01J2231/20 ,  B01J2531/0258 ,  B01J2531/16 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07C2531/26 ,  C07F13/005 ,  C07F15/025 ,  C07F15/045 ,  C07F15/065 ,  C08F10/00 ,  C08F110/02 ,  C07C11/02 ,  C08F2500/02 ,  C08F4/60089 ,  C08F4/7042 ,  C08F4/50 ,  C08F4/7081

Abstract: This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.

Abstract translation: 本发明涉及由下式表示的过渡金属催化剂化合物：LMX 2或（LMX 2）2 N，其中每个M独立地为基团 7至11个金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）键合到M上 原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C < 并且中心氮原子键合到三个不同的碳原子或两个不同的碳原子和一个氢原子上; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。

公开(公告)号：US07189791B2

公开(公告)日：2007-03-13

申请号：US10855585

申请日：2004-05-27

Applicant: Gregory Adam Solan ,  Christopher James Davies

Inventor： Gregory Adam Solan ,  Christopher James Davies

IPC: C08F4/695 ,  C08F4/70 ,  B01J31/12 ,  B01J31/14 ,  C07F13/00 ,  C07F15/00 ,  C07F15/04

CPC classification number: C07C2/32 ,  B01J31/143 ,  B01J31/146 ,  B01J31/1805 ,  B01J31/1815 ,  B01J2231/122 ,  B01J2231/20 ,  B01J2531/0258 ,  B01J2531/16 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07C2531/26 ,  C07F13/005 ,  C07F15/025 ,  C07F15/045 ,  C07F15/065 ,  C08F10/00 ,  C08F110/02 ,  C07C11/02 ,  C08F2500/02 ,  C08F4/60089 ,  C08F4/7042 ,  C08F4/50 ,  C08F4/7081

Abstract: This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3–C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3–C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.

Abstract translation: 本发明涉及由下式表示的过渡金属催化剂化合物：LMX 2或（LMX 2）2 N，其中每个M独立地为基团 7至11个金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）与M键合 原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C < 并且中心氮原子键合到三个不同的碳原子或两个不同的碳原子和一个氢原子上; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。

公开(公告)号：US09458266B2

公开(公告)日：2016-10-04

申请号：US14780150

申请日：2014-03-27

Applicant: Saudi Basic Industries Corporation

Inventor： Peter Neuteboom ,  Jan Nicolaas Eddy Duchateau ,  Diego Mauricio Castaneda Zuniga

IPC: C08F4/70 ,  C08F110/02 ,  C08F2/42 ,  C08F2/40 ,  C08F2/38 ,  C08F2/02

CPC classification number: C08F110/02 ,  C08F2/02 ,  C08F2/38 ,  C08F2/40 ,  C08F2/42 ,  C08F4/7081 ,  C08F4/04 ,  C08F2500/07 ,  C08F4/34 ,  C08F2/34 ,  C08F10/02 ,  C08F2/00 ,  C08F210/02 ,  C08F220/14 ,  C08F2500/01

Abstract: The invention relates to a high pressure polymerisation process for the preparation of the polyethylene wherein the polymerisation process takes place in the presence of a cobalt containing complex. The cobalt containing complex may be a complex according to Formula (I): Formula (I) wherein y1, y2, y3 and y4 may, independently of one another be the same or different, H, (C1C20) alkyl, (C5-C20) cycloalkyl, (C6-C10) aryl radical, phenyl or hydroxy-phenyl.

公开(公告)号：US08058372B2

公开(公告)日：2011-11-15

申请号：US12099940

申请日：2008-04-09

Applicant: Gregory Adam Solan ,  Christopher James Davies

Inventor： Gregory Adam Solan ,  Christopher James Davies

IPC: C08F4/72 ,  C08F4/64 ,  B01J31/22 ,  C07C2/32

CPC classification number: C07C2/32 ,  B01J31/143 ,  B01J31/146 ,  B01J31/1805 ,  B01J31/1815 ,  B01J2231/122 ,  B01J2231/20 ,  B01J2531/0258 ,  B01J2531/16 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07C2531/26 ,  C07F13/005 ,  C07F15/025 ,  C07F15/045 ,  C07F15/065 ,  C08F10/00 ,  C08F110/02 ,  C07C11/02 ,  C08F2500/02 ,  C08F4/60089 ,  C08F4/7042 ,  C08F4/50 ,  C08F4/7081

Abstract: This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.

Abstract translation: 本发明涉及由下式表示的过渡金属催化剂化合物：LMX2或（LMX2）2，其中每个M独立地是7-11族金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）键合到M上 原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C 3 -C 50烃基，并且中心氮原子键合到三个不同的碳原子或 两个不同的碳原子和一个氢原子; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。

公开(公告)号：US06670298B1

公开(公告)日：2003-12-30

申请号：US09337612

申请日：1999-06-21

Applicant: W. Henry Weinberg ,  Eric McFarland ,  Isy Goldwasser ,  Thomas Boussie ,  Howard Turner ,  Johannes A. M. Van Beek ,  Vince Murphy ,  Timothy Powers

Inventor： W. Henry Weinberg ,  Eric McFarland ,  Isy Goldwasser ,  Thomas Boussie ,  Howard Turner ,  Johannes A. M. Van Beek ,  Vince Murphy ,  Timothy Powers

IPC: B01J3100

CPC classification number: G01N21/6402 ,  B01J19/0046 ,  B01J2219/00315 ,  B01J2219/00317 ,  B01J2219/00364 ,  B01J2219/00378 ,  B01J2219/0043 ,  B01J2219/00443 ,  B01J2219/00497 ,  B01J2219/005 ,  B01J2219/00511 ,  B01J2219/00515 ,  B01J2219/0052 ,  B01J2219/00527 ,  B01J2219/00536 ,  B01J2219/00583 ,  B01J2219/00585 ,  B01J2219/0059 ,  B01J2219/00596 ,  B01J2219/00605 ,  B01J2219/0061 ,  B01J2219/00612 ,  B01J2219/00621 ,  B01J2219/00637 ,  B01J2219/00644 ,  B01J2219/00659 ,  B01J2219/00675 ,  B01J2219/00689 ,  B01J2219/00702 ,  B01J2219/00722 ,  B01J2219/00738 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/0075 ,  B01J2219/00754 ,  B82Y30/00 ,  C07F15/0066 ,  C07F15/045 ,  C08F10/00 ,  C40B30/08 ,  C40B40/14 ,  C40B40/18 ,  C40B50/14 ,  C40B60/14 ,  G01J4/00 ,  G01N29/036 ,  G01N29/2425 ,  G01N29/348 ,  G01N29/4427 ,  G01N2291/02818 ,  G01N2291/0423 ,  G01N2291/106 ,  C08F4/7006 ,  C08F4/7081

Abstract: The present invention relates, inter alia, to methodologies for the synthesis, screening and characterization of organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention provide for the combinatorial synthesis, screening and characterization of libraries of supported and unsupported organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention can be applied to the preparation and screening of large numbers of organometallic compounds which can be used not only as catalysts (e.g., homogeneous catalysts), but also as additives and therapeutic agents.

Abstract translation: 本发明尤其涉及有机金属化合物和催化剂（例如均相催化剂）的合成，筛选和表征的方法。 本发明的方法提供了负载和未负载的有机金属化合物和催化剂（例如均相催化剂）的文库的组合合成，筛选和表征。 本发明的方法可用于大量有机金属化合物的制备和筛选，所述有机金属化合物不仅可用作催化剂（例如均相催化剂），而且可用作添加剂和治疗剂。

公开(公告)号：US20030100119A1

公开(公告)日：2003-05-29

申请号：US10269362

申请日：2002-10-11

Applicant: Symyx Technologies, Inc.

Inventor： W. Henry Weinberg ,  Eric McFarland ,  Isy Goldwasser ,  Thomas Boussie ,  Howard Turner ,  Johannes A.M. Van Beek ,  Vince Murphy ,  Tim Powers

IPC: G01N001/10

CPC classification number: G01N29/348 ,  B01J19/0046 ,  B01J2219/00317 ,  B01J2219/00364 ,  B01J2219/00378 ,  B01J2219/0043 ,  B01J2219/00443 ,  B01J2219/00497 ,  B01J2219/005 ,  B01J2219/00511 ,  B01J2219/00515 ,  B01J2219/0052 ,  B01J2219/00527 ,  B01J2219/00536 ,  B01J2219/00585 ,  B01J2219/0059 ,  B01J2219/00596 ,  B01J2219/00605 ,  B01J2219/0061 ,  B01J2219/00612 ,  B01J2219/00621 ,  B01J2219/00637 ,  B01J2219/00644 ,  B01J2219/00659 ,  B01J2219/00689 ,  B01J2219/00702 ,  B01J2219/00738 ,  B01J2219/00745 ,  B01J2219/0075 ,  B01J2219/00754 ,  C07F15/0066 ,  C07F15/045 ,  C08F10/00 ,  C08F110/02 ,  C40B40/18 ,  C40B60/14 ,  G01N29/0681 ,  G01N29/2418 ,  G01N2291/106 ,  Y10T436/2575 ,  C08F4/7006 ,  C08F4/027 ,  C08F2500/03 ,  C08F4/7081

Abstract: The present invention relates, inter alia, to methodologies for the synthesis, screening and characterization of organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention provide for the combinatorial synthesis, screening and characterization of libraries of supported and unsupported organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention can be applied to the preparation and screening of large numbers of organometallic compounds which can be used not only as catalysts (e.g., homogeneous catalysts), but also as additives and therapeutic agents.

Abstract translation: 本发明尤其涉及有机金属化合物和催化剂（例如均相催化剂）的合成，筛选和表征的方法。 本发明的方法提供了负载和未负载的有机金属化合物和催化剂（例如均相催化剂）的文库的组合合成，筛选和表征。 本发明的方法可用于大量有机金属化合物的制备和筛选，所述有机金属化合物不仅可用作催化剂（例如均相催化剂），而且可用作添加剂和治疗剂。

公开(公告)号：US06197984B1

公开(公告)日：2001-03-06

申请号：US09305942

申请日：1999-05-06

Applicant: Kiryll Lvovich Makovetsky ,  Eugeny Shmerovich Finkelshtein ,  Viktor Ivanovich Bykov ,  Andrey Khristoforovich Bagdasaryan ,  Larry Funderburk Rhodes

Inventor： Kiryll Lvovich Makovetsky ,  Eugeny Shmerovich Finkelshtein ,  Viktor Ivanovich Bykov ,  Andrey Khristoforovich Bagdasaryan ,  Larry Funderburk Rhodes

IPC: C07F1504

CPC classification number: C08F232/08 ,  C07F15/04 ,  C07F15/045 ,  C08F10/00 ,  C08F210/02 ,  C08F2410/03 ,  C08F4/80 ,  C08F4/26 ,  C08F232/00 ,  C08F2500/03 ,  C08F4/7081 ,  C08F4/7014

Abstract: A method of preparing amorphous copolymers of ethylene and at least one norbornene (NB)-type comonomer is disclosed. These polymers may be random or alternating depending on the choice of catalyst and/or the relative ratio of the monomers used. This method comprises polymerizing said monomers in a diluent or in bulk in the presence of a neutral nickel catalyst which may be represented by the formula wherein Y may be a saturated or unsaturated hydrocarbyl chain, X may be oxygen or sulfur, E may be phosphorus, arsenic, antimony, oxygen or nitrogen, R and R′ independently each is hydrogen or a hydrocarbyl group, L is a ligand containing a heteroatom P, N or O or L and R together with L may form part of a chelating structure in which case L is an ethylenic double bond.

Abstract translation: 公开了制备乙烯和至少一种降冰片烯（NB）型共聚单体的无定形共聚物的方法。 这些聚合物可以是随机的或交替的，这取决于催化剂的选择和/或所用单体的相对比例。 该方法包括在中性镍催化剂的存在下在稀释剂或本体中聚合所述单体，所述中性镍催化剂可以由式（Ⅳ）代表，Y可以是饱和或不饱和的烃基链，X可以是氧或硫，E可以是磷，砷 ，锑，氧或氮，R和R'各自独立地是氢或烃基，L是含有杂原子P，N或O或L的配体，R和L一起可以形成螯合结构的一部分，其中L 是乙烯双键。

公开(公告)号：US20160039953A1

公开(公告)日：2016-02-11

申请号：US14780150

申请日：2014-03-27

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Peter NEUTEBOOM ,  Jan Nicolaas Eddy DUCHATEAU ,  Diego Mauricio CASTANEDA ZUNIGA

IPC: C08F110/02

CPC classification number: C08F110/02 ,  C08F2/02 ,  C08F2/38 ,  C08F2/40 ,  C08F2/42 ,  C08F4/7081 ,  C08F4/04 ,  C08F2500/07 ,  C08F4/34 ,  C08F2/34 ,  C08F10/02 ,  C08F2/00 ,  C08F210/02 ,  C08F220/14 ,  C08F2500/01

Abstract: The invention relates to a high pressure polymerisation process for the preparation of the polyethylene wherein the polymerisation process takes place in the presence of a cobalt containing complex. The cobalt containing complex may be a complex according to Formula (I): Formula (I) wherein y1, y2, y3 and y4 may, independently of one another be the same or different, H, (C1C20) alkyl, (C5-C20) cycloalkyl, (C6-C10) aryl radical, phenyl or hydroxy-phenyl.

Abstract translation: 本发明涉及用于制备聚乙烯的高压聚合方法，其中聚合方法在含钴复合物存在下进行。 含钴络合物可以是根据式（I）的络合物：式（I）其中y1，y2，y3和y4可以彼此独立地相同或不同，H，（C1C20）烷基，（C5-C20 ）环烷基，（C 6 -C 10）芳基，苯基或羟基 - 苯基。