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81.
公开(公告)号:US5136097A
公开(公告)日:1992-08-04
申请号:US613641
申请日:1990-12-03
申请人: Michel Armand
发明人: Michel Armand
IPC分类号: C07C315/04 , C07C315/00 , C07C317/04
CPC分类号: C07C315/00
摘要: The invention relates to a process for the synthesis of sulfonylmethanes and derivatives thereof of the formula M[(RSO.sub.2).sub.2 CH].sub.m (I), in which M represents H, an alkali metal or alkaline earth metal or NR'.sub.4, R' and R are monovalent organic radicals and m represents the valence of M.The process comprises reacting an ionic carbide with a sulfonyl halide, hydrolyzing the product obtained, adding a compound M.sub.y Y.sub.m, in which Y represents an anion capable of reacting with the cation of the ionic carbide to the reaction medium before or after hydrolysis to give a compound which can be separated from compound (I), and y represents the valence of Y.
摘要翻译: PCT No.PCT / FR90 / 00241 Sec。 371日期1990年12月3日第 102(e)日期1990年12月3日PCT 1990年4月5日提交PCT公布。 WO90 / 12000 PCT出版物 1990年10月18日的日期。本发明涉及合成式M [(RSO 2)2 CH] m(I)的磺酰基甲烷及其衍生物的方法,其中M表示H,碱金属或碱土金属或 NR'4,R'和R是一价有机基团,m表示M的化合价。该方法包括使离子碳化物与磺酰卤反应,水解所得产物,加入化合物MyYm,其中Y表示能够 在水解之前或之后与离子碳化物的阳离子反应至反应介质,得到可与化合物(I)分离的化合物,y表示Y的化合价。
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公开(公告)号:US4818644A
公开(公告)日:1989-04-04
申请号:US115050
申请日:1987-10-30
申请人: Michel Armand
发明人: Michel Armand
IPC分类号: C09K3/00 , C07C45/00 , C07C49/167 , C07C67/00 , C07C313/00 , C07C317/04 , C07C317/24 , C08K5/04 , C08K5/41 , C08L71/02 , H01B1/12 , H01M6/16 , H01M6/18 , H01M10/40
摘要: Ionically conductive material composed of a salt represented by one of the following formulas: ##STR1## in a liquid or solid solvent. Application to electrochemistry.
摘要翻译: 由下式表示的盐构成的离子导电材料:
M [RFCOCRCOR'F]; M [RFCOCRSO2R'F]; M [RFSO 2 CRSO 2 R'F]在液体或固体溶剂中。 应用于电化学。 -
公开(公告)号:US09590245B2
公开(公告)日:2017-03-07
申请号:US13124725
申请日:2009-10-23
申请人: Jean-Marie Tarascon , Nadir Recham , Michel Armand
发明人: Jean-Marie Tarascon , Nadir Recham , Michel Armand
IPC分类号: H01M4/04 , C01B25/455 , C01B17/45 , C01B25/45 , H01M4/58 , C01B25/26 , C01B25/37 , C01B33/20 , C01G1/10 , C01G49/00 , C01G51/00 , C01G53/00 , H01M10/052
CPC分类号: H01M4/5825 , C01B25/26 , C01B25/37 , C01B25/45 , C01B25/455 , C01B33/20 , C01G1/10 , C01G49/009 , C01G51/006 , C01G53/006 , C01P2002/54 , C01P2002/72 , C01P2002/77 , C01P2002/88 , C01P2004/04 , C01P2006/40 , H01M4/582 , H01M10/052 , Y10T428/2982
摘要: The present arrangement provides compounds (I) AaMm(YO4)yZz(I) that are obtained from precursors of the constituent elements by a method having steps that can include dispersion of the precursors in a liquid support having one or more ionic liquids made up of a cation and an anion the electric charges of which balance out to give a suspension of the precursors in the liquid. The suspension is heated to a temperature of 25 to 380° C. and the ionic liquid and the inorganic oxide of formula (I) are separated from the reaction of the precursors.
摘要翻译: 本发明提供通过具有以下步骤的方法获得的化合物(I)AaMm(YO4)yZz(I):具有以下步骤的方法获得的化合物(A):AmM(YO4)yZz(I)),该方法可以包括前体在具有一种或多种离子液体的液体载体中的分散, 阳离子和阴离子,其电荷平衡以产生前体在液体中的悬浮液。 将悬浮液加热至25℃至380℃的温度,并将离子液体和式(I)的无机氧化物与前体的反应分离。
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公开(公告)号:US20160093889A1
公开(公告)日:2016-03-31
申请号:US14957377
申请日:2015-12-02
申请人: Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Christian Masquelier
发明人: Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Christian Masquelier
IPC分类号: H01M4/58 , H01M10/0525
CPC分类号: H01M4/136 , C01B25/45 , G02F1/155 , H01M4/049 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0525 , H01M2004/028 , H01M2300/0068 , Y10T29/49108
摘要: The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine or the rhombohedral NASICON structure and the polyanion (PO4)3− as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.
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85.
公开(公告)号:US20140291572A1
公开(公告)日:2014-10-02
申请号:US13697573
申请日:2011-05-11
申请人: Jean-Marie Tarascon , Mohamed Ati , Michel Armand , Nadir Recham
发明人: Jean-Marie Tarascon , Mohamed Ati , Michel Armand , Nadir Recham
CPC分类号: C01D15/06 , C01D5/00 , C01G49/009 , C01G49/14 , C01G51/006 , C01G51/10 , C01G53/006 , C01G53/10 , C01P2002/54 , C01P2002/72 , C01P2002/85 , C01P2002/88 , C01P2004/03 , C01P2006/40 , H01M4/5825
摘要: The invention relates to a method for preparing an alkali metal and transition metal fluorosulfate that is useful as an electrode material in an electrochemical battery that operates by alkali ion exchange. The method includes a first step that involves: preparing a mixture of precursors of elements making up fluorosulfate, placing said mixture in contact with a solid polymer at ambient temperature, subjecting the reaction medium to a heat treatment that aims to melt the polymer, and subsequently reacting the precursors with one another. Said polymer is one that is solid at ambient temperature, has a melting point lower than the reaction temperature of the precursors, is stable at least up to the reaction temperature of the precursors, and is soluble in a nonpolar aprotic organic solvent.
摘要翻译: 本发明涉及一种制备碱金属和过渡金属氟硫酸盐的方法,其可用作通过碱离子交换操作的电化学电池中的电极材料。 该方法包括第一步骤,其包括:制备构成氟硫酸盐的元素的前体的混合物,将所述混合物与环境温度下的固体聚合物接触,使反应介质经受热处理,其目的是熔化聚合物,随后 使前体彼此反应。 所述聚合物是在环境温度下为固体的聚合物,其熔点低于前体的反应温度,至少稳定至前体的反应温度,并且可溶于非极性非质子有机溶剂。
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公开(公告)号:US20130029223A1
公开(公告)日:2013-01-31
申请号:US13645341
申请日:2012-10-04
申请人: Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Christian Masquelier
发明人: Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Christian Masquelier
CPC分类号: H01M4/136 , C01B25/45 , G02F1/155 , H01M4/049 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0525 , H01M2004/028 , H01M2300/0068 , Y10T29/49108
摘要: The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine or the rhombohedral NASICON structure and the polyanion (PO4)3− as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.
摘要翻译: 本发明涉及用作碱离子二次(可再充电)电池,特别是锂离子电池中的电极的材料。 本发明提供具有有序橄榄石或菱方NASICON结构的过渡金属化合物,聚阴离子(PO4)3-作为至少一种用作碱性离子可再充电电池的电极材料的组分。
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公开(公告)号:US07955733B2
公开(公告)日:2011-06-07
申请号:US12859865
申请日:2010-08-20
申请人: Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Christian Masquelier
发明人: Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Christian Masquelier
CPC分类号: H01M4/136 , C01B25/45 , G02F1/155 , H01M4/049 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0525 , H01M2004/028 , H01M2300/0068 , Y10T29/49108
摘要: The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivineor the rhombohedral NASICON structure and the polyanion (PO4)3− as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.
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公开(公告)号:US20110017959A1
公开(公告)日:2011-01-27
申请号:US12877811
申请日:2010-09-08
申请人: Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Chirstian Masquelier
发明人: Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Chirstian Masquelier
CPC分类号: H01M4/136 , C01B25/45 , G02F1/155 , H01M4/049 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0525 , H01M2004/028 , H01M2300/0068 , Y10T29/49108
摘要: The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine, a modified olivine, or the rhombohedral NASICON structure and the polyanion (PO4)3− as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.
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89.
公开(公告)号:US20110006270A1
公开(公告)日:2011-01-13
申请号:US12877744
申请日:2010-09-08
申请人: Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Christian Masquelier
发明人: Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Christian Masquelier
CPC分类号: H01M4/136 , C01B25/45 , G02F1/155 , H01M4/049 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0525 , H01M2004/028 , H01M2300/0068 , Y10T29/49108
摘要: The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine, a modified olivine, or the rhombohedral NASICON structure and the polyanion (PO4)3− as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.
摘要翻译: 本发明涉及用作碱离子二次(可再充电)电池,特别是锂离子电池中的电极的材料。 本发明提供了具有有序橄榄石,改性橄榄石或菱方NASICON结构的过渡金属化合物,聚阴离子(PO4)3-作为至少一种用作碱性离子可再充电电池的电极材料的组分。
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公开(公告)号:US20090151779A1
公开(公告)日:2009-06-18
申请号:US12225525
申请日:2007-03-29
申请人: Amer Hammami , Benoit Marsan , Michel Armand , Gregory Hersant
发明人: Amer Hammami , Benoit Marsan , Michel Armand , Gregory Hersant
CPC分类号: H01M14/005 , H01G9/2004 , H01G9/2018 , H01M4/60 , H01M8/188 , Y02E10/542 , Y02E60/528
摘要: There is provided a composition comprising a first compound chosen from compounds of formulas (I) and (III) and a second compound chosen from compounds of formulas (II) and (IV): A-S−M+ (III) A-S—S-A (IV) Various chemical entities can be used for R1 to R4, A, M, and Z. This composition can be particularly useful as a redox couple.
摘要翻译: 提供了包含选自式(I)和(III)的化合物的第一化合物和选自式(II)和(IV)的化合物的第二化合物)的组合物:<?in-line-formula description =“In- 线公式“end =”lead“?> AS-M +(III)<?in-line-formula description =”In-line Formulas“end =”tail“?> <?in-line-formula description =”In- 线公式“end =”lead“?> ASSA(IV)<?in-line-formula description =”In-line Formulas“end =”tail“?>各种化学实体可用于R1至R4,A,M 和Z。该组合物可以特别用作氧化还原对。
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