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    Production of two esters using homogeneous catalyst
    84.
    发明授权
    Production of two esters using homogeneous catalyst 有权
    使用均相催化剂生产两种酯

    公开(公告)号：US09493395B2

    公开(公告)日：2016-11-15

    申请号：US14680595

    申请日：2015-04-07

    Applicant: Eastman Chemical Company

    Inventor： Mesfin Ejerssa Janka ,  Robert Thomas Hembre ,  Stephanie Rollins Testerman

    IPC: C07C67/00 ,  C07C67/44

    CPC classification number: C07C67/44 ,  C07C67/39 ,  C07C69/14

    Abstract: Disclosed is a process for preparing two esters by reacting an aldehyde with an alcohol in the presence of a ruthenium complex compound as a catalyst. The process is particularly useful for preparing ethyl acetate and n-butyl acetate, isobutyl acetate, or 2-ethylhexyl acetate in high yield by coupling acetaldehyde with n-butanol, i-butanol, or 2-ethylhexanol.

    Abstract translation: 公开了一种通过在钌络合物化合物作为催化剂存在下使醛与醇反应来制备两种酯的方法。 通过将乙醛与正丁醇，异丁醇或2-乙基己醇偶联，可以高产率制备乙酸乙酯和乙酸正丁酯，乙酸异丁酯或乙酸2-乙基己酯。

    PRODUCTION OF TWO ESTERS USING HOMOGENEOUS CATALYST
    85.
    发明申请
    PRODUCTION OF TWO ESTERS USING HOMOGENEOUS CATALYST 有权
    使用均质催化剂生产两个酯

    公开(公告)号：US20160297741A1

    公开(公告)日：2016-10-13

    申请号：US14680595

    申请日：2015-04-07

    Applicant: Eastman Chemical Company

    Inventor： Mesfin Ejerssa Janka ,  Robert Thomas Hembre ,  Stephanie Rollins Testerman

    IPC: C07C67/44

    CPC classification number: C07C67/44 ,  C07C67/39 ,  C07C69/14

    Abstract: Disclosed is a process for preparing two esters by reacting an aldehyde with an alcohol in the presence of a ruthenium complex compound as a catalyst. The process is particularly useful for preparing ethyl acetate and n-butyl acetate, isobutyl acetate, or 2-ethylhexyl acetate in high yield by coupling acetaldehyde with n-butanol, i-butanol, or 2-ethylhexanol.

    Abstract translation: 公开了一种通过在钌络合物化合物作为催化剂存在下使醛与醇反应来制备两种酯的方法。 通过将乙醛与正丁醇，异丁醇或2-乙基己醇偶联，可以高产率制备乙酸乙酯和乙酸正丁酯，乙酸异丁酯或乙酸2-乙基己酯。

    Oxidation process to produce a purified carboxylic acid product via solvent displacement and post oxidation
    87.
    发明授权
    Oxidation process to produce a purified carboxylic acid product via solvent displacement and post oxidation 有权
    氧化工艺，通过溶剂置换和后氧化生产纯化的羧酸产物

    公开(公告)号：US09266850B2

    公开(公告)日：2016-02-23

    申请号：US14692416

    申请日：2015-04-21

    Applicant: Eastman Chemical Company

    Inventor： Mesfin Ejerssa Janka ,  Kenny Randolph Parker ,  Paula Moody ,  Ashfaq Shahanawaz Shaikh ,  Lee Reynolds Partin ,  Bradford Russell Bowers ,  Michael Charles Morrow

    IPC: C07D307/68 ,  C07D307/60

    CPC classification number: C07D307/68 ,  C07D307/60

    Abstract: Disclosed is a process to produce a dry purified carboxylic acid product comprising furan-2,5-dicarboxylic acid (FDCA). The process comprises oxidizing at least one oxidizable compound selected from the following group: 5-(hydroxymethyl)furfural (5-HMF), 5-HMF esters (5-R(CO)OCH2-furfural where R is alkyl, cycloalkyl, or aryl), 5-HMF ethers (5-R′OCH2-furfural where R′ is alkyl, cycloalkyl, or aryl), 5-alkyl furfurals (5-R″-furfural where R″ is alkyl, cycloalkyl, or aryl), mixed feedstocks of 5-HMF and 5-HMF esters, mixed feedstocks of 5-HMF and 5-HMF ethers, and mixed feedstocks of 5-HMF and 5-alkyl furfurals to generate a crude carboxylic acid slurry comprising FDCA.

    Abstract translation: 公开了一种生产包含呋喃-2,5-二羧酸（FDCA）的干燥纯化羧酸产物的方法。 该方法包括氧化至少一种选自以下组的可氧化化合物：5-（羟甲基）糠醛（5-HMF），5-HMF酯（5-R（CO）OCH 2 - 糠醛，其中R是烷基，环烷基或芳基 ），5-HMF醚（5-R'OCH 2 - 糠醛，其中R'是烷基，环烷基或芳基），5-烷基糠醛（5-R“ - 糠醛，其中R”是烷基，环烷基或芳基），混合 5-HMF和5-HMF酯的原料，5-HMF和5-HMF醚的混合原料以及5-HMF和5-烷基糠醛的混合原料以产生包含FDCA的粗制羧酸浆料。

    Oxidation process to produce a crude dry carboxylic acid product
    88.
    发明授权
    Oxidation process to produce a crude dry carboxylic acid product 有权
    氧化过程产生粗制的干燥羧酸产物

    公开(公告)号：US09206149B2

    公开(公告)日：2015-12-08

    申请号：US14282360

    申请日：2014-05-20

    Applicant: EASTMAN CHEMICAL COMPANY

    Inventor： Mesfin Ejerssa Janka ,  Kenny Randolph Parker ,  Ashfaq Shahanawaz Shaikh ,  Lee Reynolds Partin

    IPC: C07D307/34 ,  C07D307/68 ,  C07D307/48

    CPC classification number: C07D307/68 ,  C07D307/48

    Abstract: Disclosed is a process to produce a dry purified carboxylic acid product comprising furan-2,5-dicarboxylic acid (FDCA). The process comprises oxidizing at least one oxidizable compound selected from the following group: 5-(hydroxymethyl)furfural (5-HMF), 5-HMF esters (5-R(CO)OCH2-furfural where R=alkyl, cycloalkyl and aryl), 5-HMF ethers (5-R′OCH2-furfural, where R′=alkyl, cycloalkyl and aryl), 5-alkyl furfurals (5-R″-furfural, where R″=alkyl, cycloalkyl and aryl), mixed feed-stocks of 5-HMF and 5-HMF esters and mixed feed-stocks of 5-HMF and 5-HMF ethers and mixed feed-stocks of 5-HMF and 5-alkyl furfurals to generate a crude carboxylic acid slurry comprising FDCA, cooling a crude carboxylic acid slurry in cooling zone to form a cooled slurry stream. The cooled slurry stream is routed to a solid-liquid separation zone to generate a crude wet cake stream comprising FDCA that is dried in a drying zone to generate a dry carboxylic acid product stream comprising crude FDCA (cFDCA).

    Abstract translation: 公开了一种生产包含呋喃-2,5-二羧酸（FDCA）的干燥纯化羧酸产物的方法。 该方法包括氧化至少一种选自以下组的可氧化化合物：5-（羟甲基）糠醛（5-HMF），5-HMF酯（5-R（CO）OCH 2 - 糠醛，其中R =烷基，环烷基和芳基） ，5-HMF醚（5-R'OCH 2 - 糠醛，其中R'=烷基，环烷基和芳基），5-烷基糠醛（5-R“ - 糠醛，其中R”=烷基，环烷基和芳基），混合进料 5-HMF和5-HMF酯的原料和5-HMF和5-HMF醚的混合原料和5-HMF和5-烷基糠醛的混合原料以产生包含FDCA的粗制羧酸浆料，冷却 在冷却区中的粗羧酸浆料以形成冷却的浆料流。 将冷却的浆料流送至固液分离区，以产生包含FDCA的粗湿饼流，其在干燥区中干燥以产生包含粗FDCA（cFDCA）的干燥羧酸产物流。

    Process for purifying crude furan 2,5-dicarboxylic acid using hydrogenation
    89.
    发明授权
    Process for purifying crude furan 2,5-dicarboxylic acid using hydrogenation 有权
    使用氢化纯化粗呋喃2,5-二羧酸的方法

    公开(公告)号：US09156806B2

    公开(公告)日：2015-10-13

    申请号：US14259754

    申请日：2014-04-23

    Applicant: Eastman Chemical Company

    Inventor： Ashfaq Schahanawaz Shaikh ,  Kenny Randolph Parker ,  Mesfin Ejerssa Janka ,  Lee Reynolds Partin

    IPC: A61K31/341 ,  C07D307/34 ,  C07D307/68

    CPC classification number: C07D307/68

    Abstract: A process to produce a dry purified furan-2,5-dicarboxylic acid (FDCA) is described. After oxidation of 5-(hydroxymethyl)furfural (5-HMF), a crude FDCA stream is produced that is fed to a crystallization zone followed by a solid-liquid displacement zone to form a low impurity slurry stream. The solids in the low impurity slurry stream are dissolved in a dissolution zone to produce a hydrogenation feed that is hydrogenated in a hydrogenation reactor to generate a hydrogenated FDCA composition. The hydrogenated FDCA composition is routed to a crystallization zone to form a crystallized produce stream that is separated from liquid in a solid-liquid separation zone to generate a purified wet cake stream containing FDCA that can be dried in a drying zone to generate a dry purified FDCA product stream.

    Abstract translation: 描述了制备干净的呋喃-2,5-二羧酸（FDCA）的方法。 在5-（羟甲基）糠醛（5-HMF）氧化之后，产生粗制FDCA流，将其送入结晶区，随后进行固 - 液置换区以形成低杂质浆料流。 将低杂质浆料流中的固体溶解在溶解区中以产生在氢化反应器中氢化以产生氢化FDCA组合物的氢化进料。 将氢化的FDCA组合物送至结晶区以形成在固液分离区中与液体分离的结晶产物流，以产生含有FDCA的纯化湿饼流，其可以在干燥区中干燥以产生干净的 FDCA产品流。

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