Dental materials having low polymerization shrinkage
    81.
    发明申请
    Dental materials having low polymerization shrinkage 审中-公开
    具有低聚合收缩率的牙科材料

    公开(公告)号:US20080058443A1

    公开(公告)日:2008-03-06

    申请号:US11897228

    申请日:2007-08-29

    IPC分类号: A61K6/08

    摘要: The present invention relates to dental materials composed of calix[n]arenes and also to the use thereof for cements, composites, adhesives and coating materials in the dental field. The materials include (a) 0.5 to 90% by weight of at least one polymerizable calix[n]arene according to formula (I), (b) 0.01 to 5% by weight of initiator, (c) 0 to 90% by weight of at least one additional monomer which can polymerize under cationic and/or radical conditions and/or which can polymerize by ring opening, (d) 0 to 85% by weight of filler, (e) 0.01 to 5% by weight of additive and (f) 0 to 70% by weight of solvent.

    摘要翻译: 本发明涉及由杯形[n]芳烃组成的牙科用材料,以及其在牙科领域中用于粘合剂,复合材料,粘合剂和涂层材料的用途。 这些材料包括:(a)0.5至90重量%的至少一种根据式(I)的可聚合杯[n]芳烃,(b)0.01至5重量%的引发剂,(c)0至90重量% 的至少一种可在阳离子和/或自由基条件下聚合的另外的单体和/或可以通过开环聚合,(d)0至85重量%的填料,(e)0.01至5重量%的添加剂和 (f)0〜70重量%的溶剂。

    PROCESS FOR PREPARING DENTAL MATERIALS HAVING LOW POLYMERIZATION SHRINKAGE
    83.
    发明申请
    PROCESS FOR PREPARING DENTAL MATERIALS HAVING LOW POLYMERIZATION SHRINKAGE 有权
    用于制备具有低聚合收缩的牙科材料的方法

    公开(公告)号:US20100311863A1

    公开(公告)日:2010-12-09

    申请号:US12859052

    申请日:2010-08-18

    IPC分类号: A61K6/08

    摘要: The present invention relates to dental materials composed of calix[n]arenes and also to the use thereof for cements, composites, adhesives and coating materials in the dental field. The materials include (a) 0.5 to 90% by weight of at least one polymerizable calix[n]arene according to formula (I), (b) 0.01 to 5% by weight of initiator, (c) 0 to 90% by weight of at least one additional monomer which can polymerize under cationic and/or radical conditions and/or which can polymerize by ring opening, (d) 0 to 85% by weight of filler, (e) 0.01 to 5% by weight of additive and (f) 0 to 70% by weight of solvent.

    摘要翻译: 本发明涉及由杯形[n]芳烃组成的牙科用材料,以及其在牙科领域中用于粘合剂,复合材料,粘合剂和涂层材料的用途。 这些材料包括:(a)0.5至90重量%的至少一种根据式(I)的可聚合杯[n]芳烃,(b)0.01至5重量%的引发剂,(c)0至90重量% 的至少一种可在阳离子和/或自由基条件下聚合的另外的单体和/或可以通过开环聚合,(d)0至85重量%的填料,(e)0.01至5重量%的添加剂和 (f)0〜70重量%的溶剂。

    Dental materials based on polysiloxanes
    85.
    发明授权
    Dental materials based on polysiloxanes 失效
    基于聚硅氧烷的牙科材料

    公开(公告)号:US06569917B1

    公开(公告)日:2003-05-27

    申请号:US09488489

    申请日:2000-01-20

    IPC分类号: A16F200

    摘要: The invention relates to dental materials which contain at least one polysiloxane based on one or several silanes according to formula (I) [(Wq—R6—Z)p—R3]mY—R2—SiXnR13−n  Formula (I) in which X stands for a halogen atom, a hydroxyl, alkoxy and/or acyloxy group; n is equal to 1 to 3, R1 stands for an alkyl, alkenyl, aryl, alkylaryl, arylalkyl group; R2 stands for an alkylene group; R3 stands for a p-time substituted, straight, branched or cyclic, saturated or unsaturated, aromatic or aliphatic organic radical with 2 to 40 carbon atoms and optionally 1 to 6 heteroatoms; R6 stands for a q-times substituted, straight, branched or cyclic organic radical with 1 to 20 carbon atoms or is absent; p is equal to 1 to 6; q is equal to 1 to 6; Y stands for —NR4—, N or —(C═O)—NH—; m is equal to 2 for Y═N and equal to 1 for Y═—NR4—, or —(C═O)—NH—; R4 stands for an alkyl or aryl group; Z stands for O, S, —(C═O)—O—, —(C═O)—NH—, —O—(C═O)—NH— or is absent; W stands for CH2═CR5—(C═O)—O—; and R5 stands for a hydrogen atom or an alkyl group and optionally one or several further hydrolytically condensable compounds of silicon, aluminium, zirconium, titanium, boron, tin, vanadium and/or phosphorus.

    摘要翻译: 本发明涉及含有至少一种基于一种或几种根据式(I)的硅烷的聚硅氧烷的牙科材料,其中X代表卤素原子,羟基,烷氧基和/或酰氧基; n等于1至3,R1代表烷基,烯基,芳基,烷基芳基,芳基烷基; R2表示亚烷基; R3表示具有2至40个碳原子和任选1至6个杂原子的p时间取代的,直链,支链或环状饱和或不饱和的芳族或脂族有机基团; R6代表具有1至20个碳原子的q次取代的,直链,支链或环状的有机基团或不存在; p等于1至6; q等于1至6; Y代表-NR4-,N或 - (C = O)-NH-; 对于Y = N,m等于2,Y = -NR4-等于1,或 - (C = O)-NH-; R4代表烷基或芳基; Z代表O,S, - (C = O)-O-, - (C = O)-NH-,-O-(C = O)-NH-或不存在; W代表CH 2 = CR 5 - (C = O)-O-; R5代表氢原子或烷基,以及任选的一种或几种其它可水解缩合的硅,铝,锆,钛,硼,锡,钒和/或磷的化合物。

    Dental materials with unusual fluorine distribution
    88.
    发明授权
    Dental materials with unusual fluorine distribution 有权
    具有不寻常氟分布的牙科材料

    公开(公告)号:US07595354B2

    公开(公告)日:2009-09-29

    申请号:US11338034

    申请日:2006-01-24

    摘要: A composition comprising (A) at least one fluorinated vinylcyclopropane according to Formula (I) wherein R1 is H or —CO—O—(CH2CH2)p—R7; R2 is H or forms together with R6 a —CH2—C(R9)(R10)—CH2— residue; R3 is H; R4 is H or forms together with R5—CH2—C(R9)(R10)—CH2— residue; R5 is H, —CO—O—R8, —CO—O—(CH2CH2)p—R7 or forms together with R4—CH2—C(R9)(R10)—CH2— residue; R6 is H, —CO—O—R8, —CO—O—(CH2CH2)p—R7 or forms together with R2 a —CH2—C(R9)(R10)—CH2— residue; R7 is perfluorinated C2-C20 aliphatic or alicyclic group; R8 is H, phenyl, benzyl, or a linear or branched C1-C12 aliphatic or alicyclic group; R9 is a H, benzoyl, acetyl or a C1-C5-alkyl group; R10H or a —CO—O—R8; p is 1, 2, 3, or 4, provided that the compound of Formula (I) comprises at least one —CO—O—(CH2CH2)p—R7 residue; (B) at least one non-fluorinated vinylcyclopropane derivative; (C) a bisphenol-A-ether di(meth)acrylate according to Formula (II) wherein R18 is H or CH3, R19 is CH3 or CF3, Y is a C2-C5-alkylen residue which can be substituted by an OH group or is preferably unsubstituted.

    摘要翻译: 一种组合物,其包含(A)至少一种根据式(I)的氟化乙烯基环丙烷,其中R 1是H或-CO-O-(CH 2 CH 2)p -R 7; R2是H或与R6一起形成-CH 2 -C(R 9)(R 10)-CH 2 - 残基; R3为H; R4是H或与R5-CH2-C(R9)(R10)-CH2-残基一起形成; R5是H,-CO-O-R8,-CO-O-(CH2CH2)p-R7或与R4-CH2-C(R9)(R10)-CH2-残基一起形成; R6是H,-CO-O-R8,-CO-O-(CH2CH2)p-R7或与R2一起形成-CH2-C(R9)(R10)-CH2-残基; R7是全氟化C 2 -C 20脂族或脂环基; R8是H,苯基,苄基或直链或支链C 1 -C 12脂族或脂环基; R9是H,苯甲酰基,乙酰基或C1-C5-烷基; R10H或-CO-O-R8; p为1,2,3或4,条件是式(I)化合物包含至少一个-CO-O-(CH 2 CH 2)p-R 7残基; (B)至少一种非氟化乙烯基环丙烷衍生物; (C)式(II)的双酚A - 醚二(甲基)丙烯酸酯,其中R18为H或CH3,R19为CH3或CF3,Y为可被OH基取代的C2-C5-亚烷基基团 或优选未被取代。

    Dental materials based on multicyclic allyl sulphides
    89.
    发明授权
    Dental materials based on multicyclic allyl sulphides 有权
    基于多环烯丙基硫化物的牙科材料

    公开(公告)号:US07501457B2

    公开(公告)日:2009-03-10

    申请号:US11482164

    申请日:2006-07-07

    IPC分类号: A61K6/083 C08F28/06

    摘要: Dental materials and associated methods are described based on multicyclic allyl sulphides with general Formula (I): in which R1 is H or a C1-C10 alkyl radical; R2 is H or a C1-C10 alkyl radical; R3 is absent or is a C1-C20 alkylene radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C6-C12 radical, a C6-C14 arylene or C7-C20 alkylene arylene radical; R4 is an n-times substituted aliphatic C2 to C20 hydrocarbon radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, an aromatic C6-C14 radical, an aliphatic-aromatic C7-C20 radical or a heterocyclic radical which can contain 4 to 20 carbon atoms and 1 to 6 heteroatoms which are selected from N, O, P and/or S atoms, or which is formed exclusively by these heteroatoms; R5 is absent or is a C1-C10 alkylene radical; X is absent or is O, S, —O—CO— or —O—CO—NH—; Y is absent or is O, S, —O—CO— or —O—CO—NH—; m is 0 or 1 and n is an integer from 3 to 6.

    摘要翻译: 基于具有通式(I)的多环烯丙基硫化物描述牙科材料和相关方法:其中R1是H或C1-C10烷基; R2是H或C1-C10烷基; R3不存在或是可被O或S间隔的C 1 -C 20亚烷基,脂环族C 4 -C 12基,双环C 6 -C 12基,C 6 -C 14亚芳基或C 7 -C 20亚烷基亚芳基; R4是可被O或S间隔的n次取代的脂族C 2 -C 20烃基,脂环族C 4 -C 12基团,芳族C 6 -C 14基团,脂族 - 芳族C 7 -C 20基团或杂环基团,其可以 含有4至20个碳原子和1至6个选自N,O,P和/或S原子的杂原子,或仅由这些杂原子形成的杂原子; R5不存在或是C1-C10亚烷基; X不存在或为O,S,-O-CO-或-O-CO-NH-; Y不存在或为O,S,-O-CO-或-O-CO-NH-; m为0或1,n为3至6的整数。