摘要:
2-Cycloalkyl-pyrimidin-5-yl-(thiono)(thiol)-phosphoric-(phosphonic) acid esters and ester-amides of the formula ##STR1## in which R is alkyl,R.sup.1 is alkyl, alkoxy, alkylthio, alkylamino or phenylR.sup.2 is hydrogen or alkyl,R.sup.3 is cycloalkyl, andX is oxygen or sulphur which possess insecticidal, acaricidal and nematicidal properties.
摘要:
Benzyl esters of the formula ##STR1## in which n is 1,2,3,4, or 5,R.sup.2 is hydrogen, C.sub.1-4 -alkyl, cyano or ethynyl,R.sup.3 is the radical of a carboxylic acid customary in pyrethroids or pyrethroid-like compounds, andat least one R.sup.1 is fluoroalkoxy or fluoroalkylmercapto, or two together are fluoromethylene- or fluoroethylene-dioxy, and the others, if present, are hydrogen or various radicals,which possess arthropodicidal properties. Various alcohols, amines, aldehydes, halides, and the like, corresponding to the alcohol moieties of the esters are also synthesized.
摘要:
2,2-Dimethyl-3-(2'-perfluoroalkyl-2'-perhaloalkyl-vinyl)-cyclopropane of the formula ##STR1## in which R is --COOR.sup.2, --COOH, --CO--Halogen, --CN or --CO--CH.sub.3,R.sup.1 is fluorine or CF.sub.3,R.sup.3 is fluorine, chlorine, bromine or R.sup.1 CF.sub.2 --, andR.sup.2 is the radical of an alcoholwhich possess arthropodicidal properties. These compounds can be produced by adding a compound of the formula ##STR2## to an olefin of the formula ##STR3## to produce a compound of the formula ##STR4## and dehydrohalogenating said compound. This compound may be hydrolyzed, saponified or esterified, depending upon the particular derivative desired.
摘要:
N-Methyl-N-(sulphonic acid amide-N'-sulphenyl)-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1 to 4 carbon atoms in each alkyl radical, phenyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trihalogenomethyl substituent,R.sup.2 is alkyl with 2 to 8 carbon atoms, cycloalkyl, phenyl or cycloalkyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trifluoromethyl substituent, andR.sup.3 is phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl; phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl substituted at least once by trihalogenomethyl, halogen, nitro, cyano, cycloalkyl, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto, alkynylmercapto or dialkylamino, each with up to 4 carbon atoms per aliphatic moiety, or an oxime radical of the formula ##STR2## R.sup.4 and R.sup.5 each independently is cyano or alkyl, alkoxy, alkylthio, alkoxycarbonyl, dialkylcarbamoyl or dialkoxyphosphoryl with up to 4 carbon atoms per alkyl moiety, orR.sup.4 and R.sup.5, conjointly with the adjacent carbon atom, form an optionally methyl- or phenyl-substituted dithiolane, dithiane, oxathiolane or oxathiane ring.
摘要:
O-alkyl-O-[6-substituted-thio-pyridazin-3-yl]-(thiono) (thiol)-phosphoric (phosphonic) acid esters of the formula ##STR1## in which R represents alkyl,R.sup.1 represents alkyl, alkylthio or alkylamino,R.sup.2 represents alkyl, alkenyl, alkynyl or phenyl which can optionally be monosubstituted or polysubstituted, andX represents oxygen or sulphur.Which possess insecticidal and acaricidal properties.
摘要:
Sulfonic acid-N'-methylamido-N'-sulfenyl-N-methyl-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1-4 carbon atoms in each alkyl group, phenyl substituted in the o- or m-position by halogen or by alkyl with 1-4 carbon atoms, or phenyl substituted in the o-, m- or p-position by NO.sub.2, CF.sub.3 or CN, andR.sup.2 is phenyl, naphthyl, benzodioxolanyl or indanyl; phenyl, naphthyl, benzodioxolanyl or indanyl substituted by trihalogenomethyl, halogen, nitro, cyano, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto or dialkylamino wherein each hydrocarbon portion has 1-4 carbon atoms; cycloalkyl of 5-7 carbon atoms, or ##STR2## in which R.sup.3 and R.sup.4 each independently is cyano or alkyl, alkoxy, alkylthio or alkoxycarbonyl with 1-4 carbon atoms in each alkyl group, or R.sup.3 and R.sup.4 together form a ring, or, provided that R.sup.1 is a NO.sub.2 -substituted phenyl, R.sup.2 may be dihydrobenzofuranyl or dihydrobenzofuranyl substituted by alkyl of 1-4 cabon atoms,Which possess insecticidal, acaricidal, nematicidal, fungicidal and herbicidal properties.
摘要:
Pyrimidine (4,6)diyl-bis-(thiono)(thiol)-phosphoric (phosphonic) acid esters of the formula ##STR1## in which R is alkyl with 1 to 6 carbon atoms,R.sub.1 is alkyl, alkoxy or alkylmercapto each with 1 to 6 carbon atoms or phenyl,R.sub.2 is alkyl, alkoxy or alkylmercapto each with 1 to 5 carbon atoms, hydrogen or phenyl,R.sub.3 is hydrogen, alkyl with 1 to 4 carbon atoms or halogen, andX is oxygen or sulfur,Which possess insecticidal and acaricidal properties.
摘要:
O-Alkyl-S-[2-(1',1',2'-trifluoro-2'-chloroethylmercapto)-ethyl](thiono)(di)thiolphosphoric (phosphonic) acid esters and ester-amides of the formula ##STR1## in which R is alkyl with 1 to 6 carbon atoms,R' is alkyl, alkoxy, alkylmercapto or alkylamino with 1 to 6 carbon atoms in each alkyl moiety, amino or phenyl, andX is oxygen or sulfur,Which possess arthropodicidal and nematicidal properties.
摘要:
O-Alkyl-O-pyrimidin(2)yl-thionophosphonic acid esters of the formula ##STR1## in which R is alkyl with 1 to 6 carbon atoms,R' is alkyl with 1 to 6 carbon atoms or phenyl,R" and R.sup.IV each independently is hydrogen or alkyl with 1 to 4 carbon atoms, andR'" is halogen or hydrogen.Which possess insecticidal, acaricidal and nematocidal properties.
摘要:
S-(alkoxycarbonyl)-alkyl-thiophosphoric acid ester amides of the general formula ##EQU1## in which R, R' and R" each independently is alkyl of 1 to 10 carbon atoms or lower alkenyl,Y is hydrogen or lower alkyl,Y' is hydrogen, lower alkyl or --CH.sub.2 --CO--OR", andX is oxygen or sulfur,Which possess insecticidal and acaricidal properties.