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81.发明申请Hairy Polymeric Nanoparticles With First And Second Shell Block Polymer Arms 有权具有第一和第二壳块聚合物臂的多毛聚合物纳米颗粒公开(公告)号：US20110213066A1
公开(公告)日：2011-09-01
申请号：US12754367
申请日：2010-04-05
申请人： Xiaorong Wang , Hideki Kitano , James H. Pawlow , Christopher G. Robertson , Yaohong Chen , Yuan-Yong Yan
发明人： Xiaorong Wang , Hideki Kitano , James H. Pawlow , Christopher G. Robertson , Yaohong Chen , Yuan-Yong Yan
IPC分类号： C08F271/02 , C08F279/02 , C08L53/02 , B82B1/00
CPC分类号： C08F279/02 , C08F297/046 , C08L9/06 , C08L21/00 , C08L2205/03 , C08L2207/53 , C08L7/00 , C08L9/00 , C08L53/00 , C08L53/02
摘要： Compositions and methods are included for preparing a hairy polymeric nanoparticle including first and second shell block polymer arms are at least partially phase-separated and surround a polymeric core. One type of polymeric arm can have a greater polarity than the other type(s) of polymeric arms. A rubber composition including the hairy nanoparticles is also provided.
摘要翻译： 包括用于制备毛发聚合物纳米颗粒的组合物和方法，包括第一和第二壳嵌段聚合物臂至少部分地相分离并且围绕聚合物芯。 一种类型的聚合物臂可以具有比其它类型的聚合物臂更大的极性。 还提供了包含毛状纳米颗粒的橡胶组合物。
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公开(公告)号：US20110172369A1
公开(公告)日：2011-07-14
申请号：US12935863
申请日：2009-03-30
申请人： Yuan-Yong Yan , Steven Luo , Mark T. Arigo
发明人： Yuan-Yong Yan , Steven Luo , Mark T. Arigo
摘要： A macromolecule includes at least one polymer chain with at least one functionality. The polymer can include unsaturated mer units and can be provided via anionic and pseudo-living polymerization techniques. In either technique, the functionality can include at least one 5- or 6-membered ring which includes a secondary amine group and at least one additional heteroatom; in the latter technique, the functionality can include a hydrazone radical. Such polymers can be used to provide compositions that also include particulate fillers, such compositions being useful for the production of vulcanizates.
摘要翻译： 大分子包括至少一个具有至少一个官能团的聚合物链。 聚合物可以包括不饱和聚合单元，并且可以通过阴离子和假活性聚合技术提供。 在任一技术中，官能团可以包括至少一个5-或6-元环，其包括仲胺基团和至少一个另外的杂原子; 在后一种技术中，官能团可以包括腙基团。 这样的聚合物可用于提供还包括颗粒填料的组合物，这种组合物可用于生产硫化橡胶。
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公开(公告)号：US07767755B2
公开(公告)日：2010-08-03
申请号：US11734298
申请日：2007-04-12
申请人： Yuan-Yong Yan
发明人： Yuan-Yong Yan
CPC分类号： C08L15/00 , C08C19/44 , C08K3/013 , C08L19/006 , C08L2666/08
摘要： A composition that includes functionalized polymers and particulate filler is provided. The composition includes at least three components: (1) a polymer that includes a first type of functionality such as a functional group including a primary or secondary amine functionality, (2) a polymer that includes a second type of functionality such as an alkoxysilane or other silica interacting functionality, and (3) at least two types of particulate filler. One of the functionalized polymers can be made in the presence of the other.
摘要翻译： 提供了包含官能化聚合物和颗粒填料的组合物。 组合物包括至少三种组分：（1）包含第一类官能团的聚合物，例如包括伯胺或仲胺官能团的官能团，（2）包含第二类官能团的聚合物，例如烷氧基硅烷或 其他二氧化硅相互作用功能，和（3）至少两种类型的颗粒填料。 官能化聚合物之一可以在其它聚合物的存在下制备。
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公开(公告)号：US20090105408A1
公开(公告)日：2009-04-23
申请号：US12254284
申请日：2008-10-20
申请人： Yuan-Yong Yan
发明人： Yuan-Yong Yan
IPC分类号： C08G18/04 , C08G61/12 , C08G77/18 , C08L23/32 , C08L23/36 , C08L43/04 , C08L39/00 , C08K3/04 , C08K3/36 , C08L41/00
CPC分类号： C08C19/44 , C08C19/30 , C08L19/006
摘要： A functionalized polymer includes a polymer chain and a terminal group linked to the chain through a functionality that contains one or more urethane groups. The functionalized polymer can be provided by reacting a nucleophile with a polymer having terminal iso(thio)cyanate functionality which, in turn, can be provided by reacting a terminally active polymer with a polyiso(thio)cyanate. Even polymers that contain substantial amounts of styrene mer can be used in the described process.
摘要翻译： 官能化聚合物包括聚合物链和通过包含一个或多个氨基甲酸酯基的官能团与链连接的端基。 官能化聚合物可以通过使亲核试剂与具有末端异（硫代）氰酸酯官能团的聚合物反应来提供，其又可以通过使末端活性聚合物与多异（硫代）氰酸酯反应来提供。 即使是含有大量苯乙烯聚合物的聚合物也可用于所述方法中。
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公开(公告)号：US07462677B2
公开(公告)日：2008-12-09
申请号：US11900664
申请日：2007-09-13
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
摘要翻译： 提供用于阴离子聚合单体的引发剂，以在聚合物上提供功能性头基。 还提供了具有衍生自含硫阴离子引发剂的功能性头基团和任选地作为由使用功能性终止试剂，偶联剂或连接剂引起的附加官能团的聚合物。 提出了一种阴离子聚合单体的方法，包括使单体与含硫阴离子引发剂聚合的步骤，以在聚合物上提供功能性头基。 还描述了包含功能聚合物和填料的弹性体化合物。 还提供了由含有可硫化弹性体化合物的轮胎成分导致的滚动阻力降低的轮胎。
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公开(公告)号：US20080154020A1
公开(公告)日：2008-06-26
申请号：US11961189
申请日：2007-12-20
申请人： Yuan-Yong Yan , Steven Luo
发明人： Yuan-Yong Yan , Steven Luo
IPC分类号： C08G73/00
摘要： A functionalized polymer includes a directly bonded moiety, which can be located at a terminus of the polymer, defined by the formula —CR1R2NH-Q-M where M is (N═CR1R2) or N-(QN═CR1R2)2 each Q independently is a substituted or unsubstituted, cyclic or acyclic C1-C40 alkyl, aryl, or alkaryl radical, and each R1 and R2 independently is a hydrogen atom or a substituted or unsubstituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, allyl, aralkyl, alkaryl, or alkynyl group. The polymer can be provided by introducing a polyimine compound into a system that includes carbanionic (living) polymer. Such polymers can be used in the production of compositions that include particulate fillers.
摘要翻译： 官能化聚合物包括直接键合的部分，其可以位于聚合物的末端，由式-CR 1 2 O 2 NH-QM定义，其中M为（ N-CR 1 R 2 2）或N - （QN-CR 1 R 2）2 每个Q独立地是取代或未取代的环状或无环C 1 -C 40烷基，芳基或烷芳基，每个R 1 独立地是氢原子或取代或未取代的烷基，烯基，环烷基，环烯基，芳基，烯丙基，芳烷基，烷芳基或炔基。 聚合物可以通过将聚亚胺化合物引入到包含聚阴离子（活性）聚合物的体系中来提供。 这种聚合物可用于生产包括颗粒填料的组合物。
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公开(公告)号：US07319123B2
公开(公告)日：2008-01-15
申请号：US11607690
申请日：2006-12-02
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
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公开(公告)号：US20080004385A1
公开(公告)日：2008-01-03
申请号：US11900664
申请日：2007-09-13
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
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公开(公告)号：US20070293622A1
公开(公告)日：2007-12-20
申请号：US11734298
申请日：2007-04-12
申请人： Yuan-Yong Yan
发明人： Yuan-Yong Yan
CPC分类号： C08L15/00 , C08C19/44 , C08K3/013 , C08L19/006 , C08L2666/08
摘要： A composition that includes functionalized polymers and particulate filler is provided. The composition includes at least three components: (1) a polymer that includes a first type of functionality such as a functional group including a primary or secondary amine functionality, (2) a polymer that includes a second type of functionality such as an alkoxysilane or other silica interacting functionality, and (3) at least two types of particulate filler. One of the functionalized polymers can be made in the presence of the other.
摘要翻译： 提供了包含官能化聚合物和颗粒填料的组合物。 组合物包括至少三种组分：（1）包含第一类官能团的聚合物，例如包括伯胺或仲胺官能团的官能团，（2）包含第二类官能团的聚合物，例如烷氧基硅烷或 其他二氧化硅相互作用功能，和（3）至少两种类型的颗粒填料。 官能化聚合物之一可以在其它聚合物的存在下制备。
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90.发明申请公开(公告)号：US20070149649A1
公开(公告)日：2007-06-28
申请号：US11641514
申请日：2006-12-19
IPC分类号： C09D151/00
CPC分类号： C08F297/04 , B82Y30/00 , C08F257/02 , C08F285/00 , C08K2201/011 , C08L21/00 , C08L53/02 , C09D153/02 , C08L2666/24 , C08L2666/02
摘要： The present invention provides polymeric nanoparticles comprising triblock and optionally diblock copolymer chains. The architecture of the polymeric nanoparticles may be controlled, resulting in nanoparticles having non-spherical shapes. The present invention also provides a method of preparing the polymeric nanoparticles and a rubber article such as a tire manufactured from a formulation comprising the polymer nanoparticles.
摘要翻译： 本发明提供了包含三嵌段和任选的二嵌段共聚物链的聚合物纳米颗粒。 可以控制聚合物纳米颗粒的结构，导致具有非球形形状的纳米颗粒。 本发明还提供了制备聚合物纳米颗粒的方法和由包含聚合物纳米颗粒的制剂制成的橡胶制品，例如轮胎。
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