公开(公告)号：US09074035B2

公开(公告)日：2015-07-07

申请号：US13813277

申请日：2011-07-26

申请人： Shojiro Kaita ,  Olivier Tardif ,  Yasuo Horikawa ,  Hideki Kitano

发明人： Shojiro Kaita ,  Olivier Tardif ,  Yasuo Horikawa ,  Hideki Kitano

IPC分类号： C08F36/00 ,  C08L9/00 ,  C08F236/04 ,  B60C1/00 ,  C08L47/00 ,  C08F210/02 ,  C08F236/06 ,  C08K3/00

CPC分类号： C08F236/04 ,  B60C1/00 ,  C08F210/02 ,  C08F236/06 ,  C08K3/013 ,  C08L47/00 ,  C08K3/0033 ,  C08L9/00 ,  C08F4/545 ,  C08F4/52

摘要： In a copolymer of a conjugated diene compound and a non-conjugated olefin, the conjugated diene unit has a cis-1,4 bond content of greater than 70.5% and the non-conjugated olefin is contained in an amount of 10 mol % or more.

摘要翻译： 在共轭二烯化合物和非共轭烯烃的共聚物中，共轭二烯单元的顺式-1,4键含量大于70.5％，非共轭烯烃的含量为10摩尔％以上 。

公开(公告)号：US20130210994A1

公开(公告)日：2013-08-15

申请号：US13813369

申请日：2011-07-27

申请人： Shojiro Kaita ,  Olivier Tardif ,  Yasuo Horikawa ,  Hideki Kitano

发明人： Shojiro Kaita ,  Olivier Tardif ,  Yasuo Horikawa ,  Hideki Kitano

IPC分类号： C08F236/06

CPC分类号： C08F236/06 ,  B60C1/00 ,  C08F210/02 ,  C08F236/04 ,  C08K3/013 ,  C08F4/52 ,  C08K3/0033 ,  C08L21/00 ,  C08F2500/03 ,  C08F2500/04 ,  C08F4/545

摘要： The present invention provides a copolymer of a conjugated diene compound and a non-conjugated olefin, in which the conjugated diene unit has cis-1,4 bonds and the non-conjugated olefin contains many ethylene structures. In a copolymer of a conjugated diene compound and an unconjugated olefin other than the conjugated diene compound, the conjugated diene unit has a cis-1,4 bond content of 50% or more and the unconjugated olefin is contained in an amount of 20 mol % or more.

摘要翻译： 本发明提供共轭二烯化合物和非共轭烯烃的共聚物，其中共轭二烯单元具有顺式-1,4键，非共轭烯烃含有许多乙烯结构。 在共轭二烯化合物和共轭二烯化合物以外的非共轭烯烃的共聚物中，共轭二烯单元的顺式-1,4键含量为50％以上，非共轭烯烃的含量为20摩尔％ 或者更多。

公开(公告)号：US20130186539A1

公开(公告)日：2013-07-25

申请号：US13877126

申请日：2010-11-30

申请人： Yuwa Takahashi ,  Shinji Tai ,  Masao Hikasa ,  Hideki Kitano ,  Tetsuo Amamoto ,  Takatsugu Tanaka

发明人： Yuwa Takahashi ,  Shinji Tai ,  Masao Hikasa ,  Hideki Kitano ,  Tetsuo Amamoto ,  Takatsugu Tanaka

IPC分类号： B60C1/00 ,  B32B27/30 ,  B32B27/28

CPC分类号： B60C1/0008 ,  B32B25/16 ,  B32B27/08 ,  B32B27/18 ,  B32B27/28 ,  B32B27/30 ,  B32B27/302 ,  B32B27/304 ,  B32B27/306 ,  B32B27/32 ,  B32B27/322 ,  B32B27/327 ,  B32B27/34 ,  B32B27/36 ,  B32B27/40 ,  B60C2005/145 ,  C08G18/0895 ,  C08G18/4238 ,  C08G18/4283 ,  C08G18/69 ,  C08G2380/00 ,  Y10T428/24967 ,  Y10T428/24975

摘要： A multilayered structure having a layer A constituted with a resin composition containing a gas barrier resin, and a layer B being adjacent to the layer A and being constituted with a resin composition containing an elastomer. The total number of the layer A and the layer B is at least 7. The average thickness of the layer A in terms of a single layer is no less than 0.001 μm and no greater than 10 μm, and the average thickness of the layer B in terms of a single layer is no less than 0.001 μm and no greater than 40 μm. The multilayered structure is formed by irradiating with an active energy ray. Furthermore, an inner liner having the multilayered structure, and a pneumatic tire provided with the inner liner are provided.

摘要翻译： 具有由含有阻气性树脂的树脂组合物构成的层A和与层A相邻的层B并由含有弹性体的树脂组合物构成的多层结构体。 层A和层B的总数为7以上，层A的平均厚度为0.001μm以上且10μm以下，层B的平均厚度 单层为0.001μm以上且40μm以下。 通过用活性能量射线照射形成多层结构。 此外，提供具有多层结构的内衬和设置有内衬的充气轮胎。

公开(公告)号：US20050158500A1

公开(公告)日：2005-07-21

申请号：US10507320

申请日：2003-03-10

申请人： Hideki Kitano ,  Hidefumi Kotsubo ,  Takato Inamiya

发明人： Hideki Kitano ,  Hidefumi Kotsubo ,  Takato Inamiya

IPC分类号： G11B7/24 ,  G11B7/24038 ,  G11B7/256 ,  G11B7/26 ,  B32B9/00

CPC分类号： G11B7/24038 ,  G11B7/24 ,  G11B7/256 ,  G11B7/26 ,  Y10T428/14

摘要： A process for the preparation of an optical information recording medium comprises superposing two optical information recording substrates having an uneven surface of recorded pits and/or grooves on each other through a photo-curable adhesive sheet comprising a photo-curable composition which comprises a reactive polymer having a photopolymerizable functional group and Tg of not more than 20° C., the photo-curable adhesive sheet having a light transmittance of not less than 70% in a wavelength range of 380 to 420 nm, such that the two uneven surfaces face each other, depressing the substrates and sheet to form a laminate, and curing the laminate by light. A process for the preparation of an optical information recording medium comprises placing a photo-curable transfer sheet comprising a photo-curable composition which comprises a reactive polymer having a photopolymerizable functional group and Tg of not more than 20° C. on an optical information recording substrate having an uneven surface of recorded pits and/or grooves such that one side of the photo-curable transfer sheet is in contact with the uneven surface of the optical information recording substrate, depressing the sheet and substrate to form a laminate in which the one side of the photo-curable transfer sheet adheres closely to the uneven surface, and exposing the photo-curable transfer sheet of the laminate to ultraviolet rays to cure the transfer sheet. A photo-curable transfer sheet comprises a photo-curable composition which comprises a reactive polymer having a photopolymerizable functional group and which is capable of deforming by application of pressure, at least one side of the photo-curable transfer sheet having a surface roughness (Ra) of not more than 30 nm.

摘要翻译： 一种用于制备光学信息记录介质的方法包括通过包含光固化性组合物的光固化性粘合片将具有记录凹坑和/或凹槽的不平坦表面的两个光学信息记录基片重叠在一起，所述光固化性粘合片包含反应性聚合物 具有光聚合性官能团和Tg不超过20℃的光固化型粘合片，其光透射率在380〜420nm的波长范围内具有不小于70％的光透射率，使得两个不均匀表面面对每个 另一方面，压下基材和片材以形成层压体，并用光固化层压材料。 制备光学信息记录介质的方法包括将光可固化组合物的光固化性转印片材放置在光学信息记录介质上，所述光固化性组合物包含具有可光聚合官能团的反应性聚合物和Tg不超过20℃ 具有记录凹坑和/或凹槽的不平坦表面的基板，使得光固化转印片的一侧与光学信息记录基板的不平坦表面接触，按压片材和基底以形成层压体，其中一个 光固化性转印片的侧面紧贴于凹凸面，将层叠体的光固化性转印片露出紫外线，使转印片固化。 光固化性转印片包含光固化性组合物，其包含具有光聚合性官能团的反应性聚合物，其能够通过施加压力而变形，所述光固化性转印片的至少一面具有表面粗糙度（Ra ）不大于30nm。

公开(公告)号：US09815330B2

公开(公告)日：2017-11-14

申请号：US14123127

申请日：2012-05-30

申请人： Takuya Ogasawara ,  Hideyuki Chiashi ,  Hideki Kitano

发明人： Takuya Ogasawara ,  Hideyuki Chiashi ,  Hideki Kitano

IPC分类号： B60C1/00 ,  B60C5/14 ,  B29D30/06 ,  B29D30/30 ,  B29D30/20 ,  B32B25/16 ,  B32B27/30 ,  B32B7/12 ,  B32B25/08 ,  B32B25/12 ,  B32B25/14 ,  B32B27/38 ,  B32B1/00

CPC分类号： B60C5/14 ,  B29D30/0681 ,  B29D30/20 ,  B29D30/3007 ,  B29D2030/0682 ,  B32B1/00 ,  B32B7/12 ,  B32B25/08 ,  B32B25/12 ,  B32B25/14 ,  B32B25/16 ,  B32B27/306 ,  B32B27/38 ,  B32B2250/05 ,  B32B2307/54 ,  B60C1/0008 ,  B60C2005/145 ,  B60C2005/147 ,  Y10T428/269 ,  Y10T428/31511

摘要： The laminate according to the present invention includes a thermoplastic resin film-containing layer and a rubber layer, in which the rubber layer contains a modified diene polymer, and the rubber layer has a dynamic storage modulus E′ at −20° C. of 1.0×105 to 1.0×108 Pa. This laminate can improve the resistance to the fractures and the cracks of the inner liner.

公开(公告)号：US09266978B2

公开(公告)日：2016-02-23

申请号：US13813315

申请日：2011-07-22

申请人： Shojiro Kaita ,  Olivier Tardif ,  Hideki Kitano

发明人： Shojiro Kaita ,  Olivier Tardif ,  Hideki Kitano

IPC分类号： C08F4/54 ,  C08F4/72 ,  C08F236/04 ,  C08F210/02 ,  C08F236/06

CPC分类号： C08F4/72 ,  C08F210/02 ,  C08F236/04 ,  C08F236/06 ,  C08F4/545 ,  C08F2500/04

摘要： Disclosed is a method of manufacturing a copolymer of a conjugated diene compound and an olefin other than the conjugated diene compound, where a conjugated diene compound and an olefin other than the conjugated diene compound is copolymerized in the presence of a polymerization catalyst composition containing components: (A) a rare earth element compound or a reactant of the rare earth element compound and a Lewis base; and (B) at least one selected from a group consisting of an ionic compound (B-1) composed of a non-coordinating anion and a cation, an aluminoxane (B-2), and at least one kind of halogen compound (B-3) selected from among a Lewis acid, a complex compound of a metal halide and a Lewis base, and an organic compound containing active halogen (when containing at least one of (B-1) and (B-3), the polymerization catalyst composition further contains component (C): an organometallic compound).

摘要翻译： 公开了共轭二烯化合物与共轭二烯化合物以外的烯烃的共聚物的制造方法，其中共轭二烯化合物和除共轭二烯化合物以外的烯烃在含有组分的聚合催化剂组合物的存在下共聚： （A）稀土元素化合物或稀土元素化合物的反应物和路易斯碱; 和（B）选自由非配位阴离子构成的离子性化合物（B-1）和阳离子，铝氧烷（B-2）和至少一种卤素化合物（B）的组中的至少一种 -3），选自路易斯酸，金属卤化物的络合物和路易斯碱，以及含有活性卤素的有机化合物（当含有（B-1）和（B-3）中的至少一种时，聚合 催化剂组合物还含有组分（C）：有机金属化合物）。

公开(公告)号：US08846819B2

公开(公告)日：2014-09-30

申请号：US13142770

申请日：2009-12-29

申请人： Yaohong Chen ,  Mindaugas Rackaitis ,  Xiaorong Wang ,  Hideki Kitano

发明人： Yaohong Chen ,  Mindaugas Rackaitis ,  Xiaorong Wang ,  Hideki Kitano

IPC分类号： C08F287/00 ,  C08L9/06 ,  B60C1/00

CPC分类号： C08G81/025 ,  B60C1/0016 ,  C08F287/00 ,  C08G77/442 ,  C08K3/04 ,  C08K3/36 ,  C08K5/548 ,  C08L9/06 ,  C08L51/00 ,  Y10S525/902 ,  Y10S977/773 ,  Y10T428/2989

摘要： A method is provided for synthesizing a core-shell nanoparticle that includes the following steps: providing a polymeric seed (in a solvent) that includes a mono-vinyl monomer cross-linked with a cross-linking agent to form the core of the nanoparticle, the core has an average diameter of from about nanometers to about 10,000 nanometers, and the core has polymer chains with living ends; adding a stabilizer to stabilize the seed and prevent the seed from precipitating out of solution; and grafting a shell species onto the living ends of the core to form the shell of the nanoparticle. A core-first synthesized nanoparticle, along with a rubber composition and tire product are also provided.

摘要翻译： 提供了一种用于合成核 - 壳纳米颗粒的方法，其包括以下步骤：提供聚合物种子（在溶剂中），其包括与交联剂交联以形成纳米颗粒的核心的单乙烯基单体， 芯具有约纳米至约10,000纳米的平均直径，并且芯具有带有端部的聚合物链; 添加稳定剂以稳定种子并防止种子从溶液中沉淀出来; 并将壳物种接枝到芯的活的末端以形成纳米颗粒的壳。 还提供了核心优先合成的纳米颗粒，以及橡胶组合物和轮胎产品。

公开(公告)号：US08722191B2

公开(公告)日：2014-05-13

申请号：US12281242

申请日：2007-02-27

申请人： Hideki Kitano ,  Haruyuki Hatano

发明人： Hideki Kitano ,  Haruyuki Hatano

IPC分类号： B32B27/38 ,  B32B5/14 ,  C08G59/40 ,  H05K1/03

CPC分类号： H05K1/0373 ,  B32B5/26 ,  B32B2260/023 ,  B32B2260/046 ,  B32B2262/101 ,  B32B2307/536 ,  B32B2307/734 ,  B32B2457/08 ,  C08J5/24 ,  H05K2201/0209 ,  H05K2201/068 ,  Y10T428/31511 ,  Y10T428/31515

摘要： There is provided an intermediate layer material including a curing type resin composition and a fiber base material, to be used to form an intermediate layer of a composite laminate, wherein a cured material obtained by curing the intermediate layer material at a temperature of 180° C. has such properties as (i) a planar linear expansion coefficient (α1) equal to or lower than 20 ppm/° C., in a range equal to or higher than 25° C. and equal to or lower than a glass transition temperature (Tg); and (ii) a Barcol hardness equal to or more than 40 and equal to or less than 65, at 25° C.

摘要翻译： 提供了包含固化型树脂组合物和纤维基材的中间层材料，用于形成复合层压体的中间层，其中通过在180℃的温度下固化中间层材料而获得的固化材料 具有（i）等于或低于20ppm /℃的平面线性膨胀系数（α1）等于或高于25℃并且等于或低于玻璃化转变温度 （Tg）; 和（ii）在25℃下等于或大于40且等于或小于65的巴氏硬度

公开(公告)号：US20140099490A1

公开(公告)日：2014-04-10

申请号：US14122331

申请日：2012-05-31

申请人： Hideki Kitano ,  Tetsuo Amamoto ,  Takatsugu Tanaka ,  Nahoto Hayashi ,  Masao Hikasa ,  Yusuke Tanaka

发明人： Hideki Kitano ,  Tetsuo Amamoto ,  Takatsugu Tanaka ,  Nahoto Hayashi ,  Masao Hikasa ,  Yusuke Tanaka

IPC分类号： B32B7/02 ,  B32B27/08

CPC分类号： B32B7/02 ,  B32B25/08 ,  B32B27/08 ,  B32B27/306 ,  B32B2250/05 ,  B32B2250/24 ,  B32B2307/552 ,  B32B2307/7242 ,  B32B2605/08 ,  B60C1/0008 ,  B60C5/14 ,  B60C2005/145 ,  Y10T428/2495 ,  Y10T428/24975 ,  Y10T428/31573

摘要： To provide a multilayer structure having high gas barrier property and crack resistance as well as excellent fatigue resistance, an inner liner for a pneumatic tire using such a multilayer structure, and a pneumatic tire comprising the inner liner. According to the present invention, in a multilayer structure 1 including a barrier layer 2 and an elastomer layer 3, a proportion of a thickness of the elastomer layer 3 in the multilayer structure ((U1+U2+ . . . +Un)/T) is 60% or more.

摘要翻译： 为了提供具有高阻气性和抗裂性以及优异的耐疲劳性的多层结构，使用这种多层结构的充气轮胎的内衬和包含内衬的充气轮胎。 根据本发明，在包括阻挡层2和弹性体层3的多层结构体1中，多层结构（（U1 + U2 + ... + Un）/ T）中的弹性体层3的厚度的比例， 是60％以上。

公开(公告)号：US20110236686A1

公开(公告)日：2011-09-29

申请号：US12979719

申请日：2010-12-28

申请人： Hideki Kitano ,  Yaohong Chen

发明人： Hideki Kitano ,  Yaohong Chen

IPC分类号： B32B5/16 ,  C08F2/06 ,  C08F8/00 ,  C08F2/38 ,  B82Y99/00 ,  B82B3/00

CPC分类号： C08F299/02 ,  B01J13/18 ,  C08F2/06 ,  C08F8/00 ,  C08F212/08 ,  C08F257/02 ,  C08F2800/20 ,  C08F2810/20 ,  Y10T428/2982 ,  C08F212/36

摘要： A method is provided for making nanoparticles, including the steps of: combining a hydrocarbon solvent and an aprotic, polar co-solvent, a mono-vinyl aromatic monomer, polymerization initiator, a solution stabilizer, and a first charge of a cross-linking agent. Subsequently, a second charge of cross-linking agent is added. The nanoparticles have an average diameter of 5 nanometers to about 10,000 nanometers. Spherical nanoparticles are also provided that include a cross-linking agent comprising 30% to 60% by weight of the combined weight of a mono-vinyl aromatic species and the cross-linking agent. The spherical nanoparticles also meet the following equation: 0.90≦(D1/D2)≦1.1 wherein D1 is a first diameter of a nanoparticle and D2 is a second diameter of the nanoparticle, and D1 and D2 intersect at right angles.

摘要翻译： 提供了制备纳米颗粒的方法，包括以下步骤：将烃溶剂与非质子极性共溶剂，单乙烯基芳族单体，聚合引发剂，溶液稳定剂和交联剂的第一电荷 。 随后，加入第二次交联剂。 纳米颗粒具有5纳米至约10,000纳米的平均直径。 还提供了球形纳米颗粒，其包括含有单乙烯基芳族物质和交联剂的组合重量的30重量％至60重量％的交联剂。 球形纳米粒子还满足以下等式：0.90＆nlE;（D1 / D2）＆nlE; 1.1其中D1是纳米颗粒的第一直径，D2是纳米颗粒的第二直径，D1和D2以直角相交。