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1.发明申请公开(公告)号：US20080004386A1
公开(公告)日：2008-01-03
申请号：US11900686
申请日：2007-09-13
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
摘要翻译： 提供用于阴离子聚合单体的引发剂，以在聚合物上提供功能性头基。 还提供了具有衍生自含硫阴离子引发剂的功能性头基团和任选地作为由使用功能性终止试剂，偶联剂或连接剂引起的附加官能团的聚合物。 提出了一种阴离子聚合单体的方法，包括使单体与含硫阴离子引发剂聚合的步骤，以在聚合物上提供功能性头基。 还描述了包含功能聚合物和填料的弹性体化合物。 还提供了由含有可硫化弹性体化合物的轮胎成分导致的滚动阻力降低的轮胎。
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公开(公告)号：US20060030657A1
公开(公告)日：2006-02-09
申请号：US10533408
申请日：2003-10-30
IPC分类号： C08K3/34 , C07F5/02 , C07D327/04 , C07D277/04 , C07F7/02
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
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公开(公告)号：US20080004385A1
公开(公告)日：2008-01-03
申请号：US11900664
申请日：2007-09-13
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
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4.发明申请公开(公告)号：US20070083023A1
公开(公告)日：2007-04-12
申请号：US11607690
申请日：2006-12-02
IPC分类号： C08F136/00
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
摘要翻译： 提供用于阴离子聚合单体的引发剂，以在聚合物上提供功能性头基。 还提供了具有衍生自含硫阴离子引发剂的功能性头基团和任选地作为由使用功能性终止试剂，偶联剂或连接剂引起的附加官能团的聚合物。 提出了一种阴离子聚合单体的方法，包括使单体与含硫阴离子引发剂聚合的步骤，以在聚合物上提供功能性头基。 还描述了包含功能聚合物和填料的弹性体化合物。 还提供了由含有可硫化弹性体化合物的轮胎成分导致的滚动阻力降低的轮胎。
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公开(公告)号：US20070037956A1
公开(公告)日：2007-02-15
申请号：US11502228
申请日：2006-08-10
申请人： Terrence Hogan , David Lawson , Yuan-Yong Yan
发明人： Terrence Hogan , David Lawson , Yuan-Yong Yan
IPC分类号： C08G8/02
CPC分类号： C08F290/06 , C08C19/44 , C08F8/30 , C08F8/34 , C08F257/02 , C08F279/02 , C08L15/00 , C08L51/003 , C08L51/04 , C08L2666/02
摘要： A functionalized polymer includes a polymer chain and, bonded thereto, a functional group having the general formula —NQOR1 where R1 is a hydrogen atom or —CH2Z where Z is a hydrogen atom or a substituted or unsubstituted aryl, alkyl, alkenyl, alkenaryl, aralkenyl, alkaryl, or aralkyl group and where Q is a moiety connected to the nitrogen atom of the functional group through a C, N, O, or S atom. The material can be the reaction product of a living polymer and a compound that includes nitroso functionality. The functional group can interact with particulate filler such as, e.g., carbon black.
摘要翻译： 官能化聚合物包括聚合物链，并且与其键合，具有通式-NQOR 1的官能团，其中R 1是氢原子或-CH 2 Z其中Z是氢原子或取代或未取代的芳基，烷基，烯基，烯芳基，芳烯基，烷芳基或芳烷基，其中Q是通过C与官能团的氮原子连接的部分， N，O或S原子。 该材料可以是活性聚合物和包括亚硝基官能团的化合物的反应产物。 官能团可以与颗粒填料例如炭黑相互作用。
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6.发明授权公开(公告)号：US07943696B2
公开(公告)日：2011-05-17
申请号：US12559588
申请日：2009-09-15
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： A vulcanized rubber composition comprising the vulcanization product of a functional polymer, where the functional polymer is defined by the formula where R is selected from C1 to C6 trialkyl-silyl groups, C1 to C20 alkyl groups, C4 to C20 cycloalkyl groups, C6 to C20 aryl groups, thienyl, furyl, and pyridyl groups; and R may optionally have attached thereto any of the following functional groups: C1 to C10 alkyl groups, C6 to C20 aryl groups, C2 to C10 alkenyl groups, C3 to C10 non-terminal alkynyl groups, ethers, tert-amines, oxazolines, thiazolines, phosphines, sulfides, silyls, and mixtures thereof; where R1 is selected from C2 to C8 alkylene groups, where X is NR, and where π is a polymer chain.
摘要翻译： 一种硫化橡胶组合物，其包含功能性聚合物的硫化产物，其中所述官能聚合物由下式定义：其中R选自C1至C6三烷基 - 甲硅烷基，C1至C20烷基，C4至C20环烷基，C6至C20 芳基，噻吩基，呋喃基和吡啶基; 并且R可以任选地具有连接到下列官能团之一：C 1至C 10烷基，C 6至C 20芳基，C 2至C 10烯基，C 3至C 10非端炔基，醚，叔胺，恶唑啉，噻唑啉 ，膦，硫化物，甲硅烷基及其混合物; 其中R1选自C2至C8亚烷基，其中X为NR，其中＆pgr; 是一种聚合物链。
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7.发明申请公开(公告)号：US20100041797A1
公开(公告)日：2010-02-18
申请号：US12559588
申请日：2009-09-15
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： A vulcanized rubber composition comprising the vulcanization product of a functional polymer, where the functional polymer is defined by the formula where R is selected from C1 to C6 trialkyl-silyl groups, C1 to C20 alkyl groups, C4 to C20 cycloalkyl groups, C6 to C20 aryl groups, thienyl, furyl, and pyridyl groups; and R may optionally have attached thereto any of the following functional groups: C1 to C10 alkyl groups, C6 to C20 aryl groups, C2 to C10 alkenyl groups, C3 to C10 non-terminal alkynyl groups, ethers, tert-amines, oxazolines, thiazolines, phosphines, sulfides, silyls, and mixtures thereof; where R1 is selected from C2 to C8 alkylene groups, where X is NR, and where π is a polymer chain.
摘要翻译： 一种硫化橡胶组合物，其包含功能性聚合物的硫化产物，其中所述官能聚合物由下式定义：其中R选自C1至C6三烷基 - 甲硅烷基，C1至C20烷基，C4至C20环烷基，C6至C20 芳基，噻吩基，呋喃基和吡啶基; 并且R可以任选地具有连接到下列官能团之一：C 1至C 10烷基，C 6至C 20芳基，C 2至C 10烯基，C 3至C 10非端炔基，醚，叔胺，恶唑啉，噻唑啉 ，膦，硫化物，甲硅烷基及其混合物; 其中R1选自C2至C8亚烷基，其中X为NR，其中＆pgr; 是一种聚合物链。
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8.发明授权公开(公告)号：US07612144B2
公开(公告)日：2009-11-03
申请号：US11900686
申请日：2007-09-13
IPC分类号： C08L47/00 , C08F236/00 , C08F236/10 , C08F36/06 , C08C19/20 , B60C1/00 , C08L25/00 , B60C11/00
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
摘要翻译： 提供用于阴离子聚合单体的引发剂，以在聚合物上提供功能性头基。 还提供了具有衍生自含硫阴离子引发剂的功能性头基团和任选地作为由使用功能性终止试剂，偶联剂或连接剂引起的附加官能团的聚合物。 提出了一种阴离子聚合单体的方法，包括使单体与含硫阴离子引发剂聚合的步骤，以在聚合物上提供功能性头基。 还描述了包含功能聚合物和填料的弹性体化合物。 还提供了由含有可硫化弹性体化合物的轮胎成分导致的滚动阻力降低的轮胎。
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公开(公告)号：US07153919B2
公开(公告)日：2006-12-26
申请号：US10533408
申请日：2003-10-30
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
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公开(公告)号：US07462677B2
公开(公告)日：2008-12-09
申请号：US11900664
申请日：2007-09-13
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
摘要翻译： 提供用于阴离子聚合单体的引发剂，以在聚合物上提供功能性头基。 还提供了具有衍生自含硫阴离子引发剂的功能性头基团和任选地作为由使用功能性终止试剂，偶联剂或连接剂引起的附加官能团的聚合物。 提出了一种阴离子聚合单体的方法，包括使单体与含硫阴离子引发剂聚合的步骤，以在聚合物上提供功能性头基。 还描述了包含功能聚合物和填料的弹性体化合物。 还提供了由含有可硫化弹性体化合物的轮胎成分导致的滚动阻力降低的轮胎。
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