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    Complex of organic amine with a completely halogenated acetone and method of preparation
    81.
    发明授权
    Complex of organic amine with a completely halogenated acetone and method of preparation 失效
    有机胺与完全氢化的乙腈的复合物及其制备方法

    公开(公告)号：US3592805A

    公开(公告)日：1971-07-13

    申请号：US3592805D

    申请日：1969-02-17

    申请人： STAUFFER CHEMICAL CO

    发明人： SZABO KAROLY ,  FREIBERG ASHLEY H

    IPC分类号： A01N35/02 ,  C07D211/82 ,  C07D231/52 ,  C07D239/69 ,  C07D249/14 ,  C07D249/18 ,  C07D285/00 ,  C07D285/01 ,  C07D295/02 ,  C07D295/027 ,  A01N9/16 ,  A01N9/20 ,  A01N9/22

    CPC分类号： C07D285/01 ,  C07C243/00 ,  C07C255/00 ,  C07D211/82 ,  C07D231/52 ,  C07D239/69 ,  C07D249/14 ,  C07D249/18 ,  C07D295/027

    摘要： A CHEMICAL COMPLEX OF THE FOLLOWING FORMULA:

    (X-CF2-CO-CF2-X'')M.(NH(-R1)-R)N

    WHEREIN R1 AND R2 ARE HYDROGEN: AN ALKYL RADICAL OF FROM 1 TO 18 CARBON ATOMS; AN ALKYL RADICAL OF FROM 1 TO 18 CARBON ATOMS; AN ALKYNYL RADICAL OF FROM 1 TO 9 CARBON ATOMS; A NON-AROMATIC CARBOCYCLIC RADICAL OF FROM 5 TO 6 CARBON ATOMS; AN ARALKYL RADICAL WHEREIN THE ALKYL PORTION IS LOWER ALKYL AND THE ARYL PORTION IS A PHENYL OR NAPHTHYL RADICAL; PHENYL RADICAL; NAPHTHYL RADICAL; AN AMINO RADICAL; CYANO OR A HETEROCYCLIC RADICAL; AND WHEN TAKEN TOGETHER R1 AND R2 MAY FORM A HETEROCYCLIC RING SYSTEM; IT BEING PROVIDED THAT THE AFORESAID RADICALS MAY HAVE ATTACHED THERETO THE FUNCTIONAL MOIETY: HALOGEN, -CN, -SCN, -COOR, -SO2NR2, -SOR, -SO3R, -CONR2, - CONHR, - OH, -SH, -NR2, -NHR, -NH2, -OR, -SR, -OC(O)R, - CHO,

    -CO-, -CH(-O-R)2

    -NO2 AND -N=N, WHEREIN R CAN BE AN ORGANIC RADICAL OF THE TYPE ABOVE DEFINED FOR R1 AND R2; X AND X'' ARE FLUORINE OR CHLORINE, AND N AND M ARE INTEGERS OF FROM 1 TO 3 WITH THE PROVISO THAT N AND M ARE IDENTICAL WHEN EQUAL TO UNITY; AND A METHOD FOR PREPARING SAID CHEMICAL COMPLEX BY REACTING 1 TO 2 MOLES OF AN ORGANIC AMINE OF THE FORMULA

    R1-NH-R2

    WHEREIN R1 AND R2 HAVE THE VALUES AS ABOVE DESIGNATED, WITH 1 TO 2 MOLES OF A FULLY HALOGENATED ACETONE OF THE FORMULA

    X-CF2-CO-CF2-X''

    WHEREIN X AND X'' HAVE THE VALUES AS ABOVE DESIGNATED, AND ISOLATING THE SO-FORMED CHEMICAL COMPLEX AND THE USE OF SAID CHEMICAL COMPLEXES AS FUNGICIDES.