摘要:
Process of dyeing polyolefin textile fibers which comprises coating a polyolefin textile fiber or fabric with an adherent coating of an interpolymer comprising a non-rubbery interpolymer of a polyunsaturated hydrocarbon monomer and at least one monoolefin monomer having a single copolymerizable ethylenic group, said interpolymer having an essentially saturated carbon chain containing a substantial proportion of the total carbon atoms in the polymer molecule and containing sufficient ethylenically unsaturated groups in the polymer molecule to permit substantial curing of films thereof by oxidative mechanism, then contacting the coated fiber with an organic dye, preferably a dye selected from the group consisting of disperse dyes, cationic dyes, and premetallized dyes.
摘要:
A crystalline polymeric composition suitable for the manufacture of textile fibres comprises a crystalline alpha-olefin polymer which has been made using stereospecific catalysts, and an inorganic compound which has an affinity for disperse dyestuffs and is capable of bonding with alizarine dyestuffs to give water-insoluble compounds. The inorganic compound may contain Al, Cr, Fe, Cu, Sn, Pb, Zn, ti, V, Tl, Co, Ni, Mn, Mg, Sr, Ca, Ba, NH\sL4, Na, K, Rb, or Cs. Exemplified compounds are zinc hydroxide, sodium aluminate, calcium metaborate, zinc stearate, and aluminium stearate. The preferred polymer is isotactic polypropylene.
摘要:
The receptivity to dyes of fibres based on crystalline olefin polymers (e.g. polypropylene) and basic nitrogen-containing polymeric tinctorial modifiers, is improved by immersing the fibres in a solution of trimethylolpropane diallyl ether. Specified tinctorial modifiers are polymers of vinyl pyridines, condensation products of epichlorhydrin/piperazine/primary aliphatic amine, condensation products of dihalogenated hydrocarbon/diamine (optionally alkylated products), and basic polymers of epichlorohydrin. The fibres may contain solid dispersants for the tinctorial modifier, and listed are cetyl and stearyl alcohols, stearic and terephthalic acids, benzoin, furoin, vinyl stearate, stearic esters of glycerol, monoethanolamine stearate, N-diethanol lauramide, aliphatic amines, condensates of ethylene oxide with alcohols, amines or phenols, polystearamide, polyacrylic acid, styrene polymers and terpene polymers. The examples illustrate the spinning, stretching and dyeing of fibres according to the invention. Specifications 950,852 and 992,011 are referred to.