摘要:
Disclosed is an active material for a secondary battery, the active material containing aggregates, each including a plurality of single particles, or a mixture of the aggregates with non-aggregated single particles, the active material including a first region having a relatively high content of an additional element (X) and a second region having a relatively low content of the additional element (X), wherein the first region is at least one region of a grain boundary formed whereby the surfaces of the single particles constituting the aggregate contact one another and a void (pore or gap) between the single particles, and/or a surface region of each single particle, wherein the additional element (X) includes at least one selected from the group consisting of Zr, Ti, Al, W, B, P, Mn, Ni, Mg, Cr, Ca, V, Sr, Y, F, Zn, Ga, Sn, Ru, Ce, La, and Si.
摘要:
Disclosed are a cathode active material for a lithium secondary battery including a core containing lithium composite metal oxide, and a coating layer disposed on the core, containing a mixture of lithium oxide, tungsten oxide, boron oxide and phosphorus oxide, and having an amorphous phase, and a lithium secondary battery including the same.
摘要:
There are provided a cathode active material for a lithium secondary battery, a method of preparing the same, and a lithium secondary battery containing the same. The cathode active material for a lithium secondary battery includes: a compound reversibly intercalating and deintercalating lithium; and a coating layer positioned on at least a portion of a surface of the compound, wherein the coating layer is a composite coating layer containing Li3PO4 and further containing a lithium metal oxide, a metal oxide, and/or a combination thereof, the lithium metal oxide or the metal oxide containing Zr.
摘要:
The present invention relates to a nickel-based composite oxide for a lithium secondary battery, and a lithium secondary battery including the same, and provides a nickel-based composite oxide for a lithium secondary battery, which comprises: a core part; and at least one tunnel connected from the inside of the core part to the outside thereof, wherein the tunnel has a diameter of 100 nm or larger, and the composite oxide further comprises coating layers located inside the tunnel and outside the core part.
摘要:
The positive active material according to one embodiment of the present invention includes a composite metal oxide of the following Formula 1, and a compound being capable of intercalating and deintercalating lithium having the composite metal oxide coated on the surface thereof. M1-xAlO2 [Chemical Formula 1] Wherein, in the above Formula 1, M is selected from the group consisting of an alkali metal, an alkaline-earth metal, and combinations thereof, and 0.03≦x≦0.95. The composite metal oxide increases impregnation of an electrolyte, improves lithium mobility, and decreases internal resistance of a rechargeable lithium battery, and thereby improves discharge capacity and cycle-life characteristics.
摘要:
The positive active material according to one embodiment of the present invention includes a composite metal oxide of the following Formula 1, and a compound being capable of intercalating and deintercalating lithium having the composite metal oxide coated on the surface thereof. M1-xAlO2 [Chemical Formula 1] Wherein, in the above Formula 1, M is selected from the group consisting of an alkali metal, an alkaline-earth metal, and combinations thereof, and 0.03≦x≦0.95. The composite metal oxide increases impregnation of an electrolyte, improves lithium mobility, and decreases internal resistance of a rechargeable lithium battery, and thereby improves discharge capacity and cycle-life characteristics.
摘要翻译:根据本发明的一个实施方案的正极活性物质包括下式1的复合金属氧化物和能够在其表面上涂覆复合金属氧化物的锂的嵌入和脱嵌化合物。 <?in-line-formula description =“In-line Formulas”end =“lead”?> M 1-x A 2 O 2化学式1 < -line-formula description =“In-line Formulas”end =“tail”?>其中,在上述式1中,M选自碱金属,碱土金属及其组合,以及 0.03 <= x <= 0.95。 复合金属氧化物增加电解质的浸渍,提高锂的迁移率,降低可再充电锂电池的内阻,从而提高放电容量和循环寿命特性。
摘要:
Disclosed is a cathode active material for a lithium secondary battery including a core containing lithium composite metal oxide, and a coating layer disposed on the core and including an amorphous phase, wherein the amorphous phase contains lithium oxide and boron oxide in a form of mixture.
摘要:
Disclosed is a cathode active material for lithium secondary batteries containing lithium transition metal composite oxide in the form of primary particles having a one-body structure, the cathode active material having a ratio (R/L) of a right area (R) to a left area (L) in a particle size distribution (PSD) graph of less than 1.1, based on a maximum point of a main peak in the particle size distribution (PSD) graph, in which an X-axis represents a particle size (μm) and a Y-axis represents a relative particle amount (%).
摘要:
There are provided a cathode active material for a lithium secondary battery, a method of preparing the same, and a lithium secondary battery containing the same. The cathode active material for a lithium secondary battery includes: a core made of a compound reversibly intercalating and deintercalating lithium; and a coating layer positioned on at least a portion of a surface of the compound, wherein the coating layer is a composite coating layer containing Li3PO4 and LiF, and further containing a lithium metal compound, a metal oxide, a metal fluoride compound, and/or a combination thereof, and the core is doped with fluorine.
摘要:
A method for preparing a cathode active material for a lithium secondary battery is provided. The preparing method includes: adding a phosphorus compound to a transition metal oxide dispersion liquid to prepare a coating liquid; drying the coating liquid to prepare a powder including phosphorus oxide coated on the surface of the transition metal oxide; and dry-mixing the powder coated with the phosphorus oxide with a lithium intercalation compound, and then firing the mixture to form a solid solution compound of L1-M1-M2-P—O (where M1 is a transition metal derived from transition metal oxide, and M2 is a metal derived from lithium intercalation compound) on the surface of the lithium intercalation compound. The method for preparing a cathode active material for a lithium secondary battery simplifies the conventional preparing process to save process cost, and it provides comparable electrochemical characteristics to a cathode active material obtained from a wet process.