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公开(公告)号：US08748507B2
公开(公告)日：2014-06-10
申请号：US13145373
申请日：2010-01-21
申请人： Minoru Yada , Yuuki Kokufu , Yuu Takata , Hideo Hosaka , Kenichi Fujino
发明人： Minoru Yada , Yuuki Kokufu , Yuu Takata , Hideo Hosaka , Kenichi Fujino
CPC分类号： C08F287/00 , C08F293/005 , C09D4/06 , C09D11/101 , C09K3/10 , C09K2200/0617 , C09K2200/0625 , Y10T428/31913
摘要： It is an object of the present invention to provide an active energy ray curable resin composition exhibiting good adhesion to a polyolefin-based resin base material. More specifically, there is provided an active energy ray curable resin composition comprising: a block copolymer (C) that includes a polymer block (A) composed mainly of an olefin-based monomer unit and a polymer block (B) composed of a vinyl-based monomer unit having a carboxyl group, a carboxylic anhydride group, or a sulfonic acid group and/or a second vinyl-based monomer unit copolymerizable with the aforementioned vinyl-based monomer unit, the block copolymer (C) having a weight-average molecular weight from 5,000 to 100,000; and an active energy ray curable compound (D).
摘要翻译： 本发明的目的是提供对聚烯烃类树脂基材具有良好粘合性的活性能量射线固化性树脂组合物。 更具体地，提供了一种活性能量射线固化树脂组合物，其包含：嵌段共聚物（C），其包含主要由烯烃类单体单元组成的聚合物嵌段（A）和由乙烯基类单体组成的聚合物嵌段（B） 具有羧基的羧基单体单元，羧酸酐基或磺酸基和/或与上述乙烯基类单体单元共聚的第二乙烯基类单体单元，嵌段共聚物（C）具有重均分子量 重量从5,000到100,000; 和活性能量射线固化性化合物（D）。
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公开(公告)号：US20120141736A1
公开(公告)日：2012-06-07
申请号：US13262115
申请日：2010-03-28
IPC分类号： B32B3/00
CPC分类号： C09D7/65 , C09D7/69 , Y10T428/24355 , Y10T428/24372
摘要： An antiglare hard coat film is provided in which light transmittance is high without giving antiglare properties more than necessary, a haze value is low, transparency is excellent, image clarity is high, glare of an image is suppressed, whitishness (white blur) of the film is reduced, contrast deterioration is suppressed, and visibility of the display is improved as compared with prior-art antiglare films.This antiglare hard coat film is formed by providing an antiglare hard coat layer containing organic particulates and a resin on a transparent film. When an average value of height in an evaluation region on the surface of the antiglare hard coat film is set to zero (0), a maximum sectional height represented by a difference between a height maximum value in the evaluation region and a height minimum value in the evaluation region is 0.6 μm or less.
摘要翻译： 提供一种防眩光硬涂膜，其中透光率高，而不会产生大于所需的防眩性，雾度值低，透明度优异，图像清晰度高，图像眩光抑制，白色模糊（白色模糊） 与现有技术的防眩膜相比，降低了对比度变差，显示器的可见度提高。 该防眩光硬涂膜通过在透明膜上设置含有有机颗粒和树脂的防眩光硬涂层而形成。 当防眩硬涂膜表面的评价区域的高度的平均值设定为零（0）时，由评价区域的高度最大值与高度最小值之间的差表示的最大截面高度 评价区域为0.6μm以下。
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3.发明申请PROCESS FOR PRODUCING MODIFIED PROPYLENE POLYMER, MODIFIED PROPYLENE POLYMER OBTAINED BY THE PRODUCTION PROCESS, AND COMPOSITION CONTAINING THE MODIFIED PROPYLENE POLYMER 审中-公开生产改性丙烯聚合物，由生产过程获得的改性丙烯聚合物的方法，以及含有改性丙烯聚合物的组合物公开(公告)号：US20090137721A1
公开(公告)日：2009-05-28
申请号：US12162534
申请日：2007-01-19
申请人： Kenichi FUJINO
发明人： Kenichi FUJINO
IPC分类号： C08F255/00 , C08L51/00
CPC分类号： C09D5/002 , C08F110/06 , C08F210/06 , C08F255/02 , C09D11/108 , C08F222/06 , C08F2500/15 , C08F2500/17 , C08F2500/03
摘要： Provided is a process for producing a modified propylene polymer which includes using a radical initiator and an organic acid to modify a propylene homopolymer satisfying the following (a) to (h): (a) mmmm is 40 to 50 mol %; (b) [rrrr/(1−mmmm)]≦0.05; (c) rmrm is 2.5 mol % or more; (d) mm×rr/(mr)2≦2.0; (e) Mw/Mn is 2.5 or lower; (f) Mw is 50,000 to 200,000; (g) [η] is 1.5 dL/g; and (h) Tm is 65 to 85° C. Also provided are: a modified propylene polymer obtained by the production process; and a composition, a surface treatment agent for a polyolefin resin, and a primer each containing the modified propylene polymer.
摘要翻译： 本发明提供一种改性丙烯聚合物的制造方法，其包括使用自由基引发剂和有机酸改性满足下述（a）〜（h）的丙烯均聚物：（a）mmmm为40〜50摩尔％ （b）[rrrr /（1-mmmm）] <= 0.05; （c）rmrm为2.5摩尔％以上; （d）mmxrr /（mr）2 <= 2.0; （e）Mw / Mn为2.5以下; （f）Mw为50,000〜200,000; （g）η为1.5dL / g; （h）Tm为65〜85℃。另外，通过制造方法得到改性丙烯类聚合物。 以及组合物，聚烯烃树脂的表面处理剂和各自含有改性丙烯聚合物的底漆。
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4.发明申请公开(公告)号：US20100029836A1
公开(公告)日：2010-02-04
申请号：US12519169
申请日：2007-12-13
IPC分类号： C08L33/10
CPC分类号： C08J3/07 , C08J2323/02 , C08J2333/08 , C08J2333/10 , C08L23/02 , C08L23/025 , C08L33/08 , C08L33/10 , C08L51/06 , C08L2314/02 , C08L2666/06 , C09D133/08 , C09D133/10 , C09J133/08 , C09J133/10
摘要： It is an object of the present invention to provide a polyolefin resin dispersion composition in which the dispersed resin is stable to water or a hydrophilic substance, and which has an adhesive property to nonpolar substrates, in particular poorly adhesive polyolefin-based substrates whose surface has not been treated, is excellent in a coating property, exhibits an excellent adhesive property through drying and press bonding with heat at a temperature in a wide range regardless of whether the temperature is low or high, is excellent in water resistance and gasohol resistance and is less tacky. That is, the present invention provides the dispersed resin composition containing (a) a polyolefin resin, (b) a (meth)acrylic acid homopolymer or copolymer having a side chain comprising an esterified alkyl group, (c) a basic substance and (d) water or a hydrophilic substance, and a process for producing the same.
摘要翻译： 本发明的目的是提供一种聚烯烃树脂分散体组合物，其中分散的树脂对水或亲水物质是稳定的，并且对非极性基材具有粘合性，特别是表面具有粘合性的聚烯烃类基材 未经处理，涂布性优异，无论温度低还是高，在宽范围的温度下通过干燥和加热粘合而具有优异的粘合性，耐水性和耐汽油醇性优异，为 少发粘 也就是说，本发明提供了包含（a）聚烯烃树脂的分散树脂组合物，（b）具有侧链的（甲基）丙烯酸均聚物或共聚物，其包含酯化的烷基，（c）碱性物质和（d ）水或亲水性物质，及其制造方法。
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公开(公告)号：US08758877B2
公开(公告)日：2014-06-24
申请号：US13262115
申请日：2010-03-28
IPC分类号： B32B3/00
CPC分类号： C09D7/65 , C09D7/69 , Y10T428/24355 , Y10T428/24372
摘要： An antiglare hard coat film is provided in which light transmittance is high without giving antiglare properties more than necessary, a haze value is low, transparency is excellent, image clarity is high, glare of an image is suppressed, whitishness (white blur) of the film is reduced, contrast deterioration is suppressed, and visibility of the display is improved as compared with prior-art antiglare films.This antiglare hard coat film is formed by providing an antiglare hard coat layer containing organic particulates and a resin on a transparent film. When an average value of height in an evaluation region on the surface of the antiglare hard coat film is set to zero (0), a maximum sectional height represented by a difference between a height maximum value in the evaluation region and a height minimum value in the evaluation region is 0.6 μm or less.
摘要翻译： 提供一种防眩光硬涂膜，其中透光率高，而不会产生大于所需的防眩性，雾度值低，透明度优异，图像清晰度高，图像眩光抑制，白色模糊（白色模糊） 与现有技术的防眩膜相比，降低了对比度变差，显示器的可见度提高。 该防眩光硬涂膜通过在透明膜上设置含有有机颗粒和树脂的防眩光硬涂层而形成。 当防眩硬涂膜表面的评价区域的高度的平均值设定为零（0）时，由评价区域的高度最大值与高度最小值之间的差表示的最大截面高度 评价区域为0.6μm以下。
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6.发明授权公开(公告)号：US08519046B2
公开(公告)日：2013-08-27
申请号：US12519169
申请日：2007-12-13
CPC分类号： C08J3/07 , C08J2323/02 , C08J2333/08 , C08J2333/10 , C08L23/02 , C08L23/025 , C08L33/08 , C08L33/10 , C08L51/06 , C08L2314/02 , C08L2666/06 , C09D133/08 , C09D133/10 , C09J133/08 , C09J133/10
摘要： It is an object of the present invention to provide a polyolefin resin dispersion composition in which the dispersed resin is stable to water or a hydrophilic substance, and which has an adhesive property to nonpolar substrates, in particular poorly adhesive polyolefin-based substrates whose surface has not been treated, is excellent in a coating property, exhibits an excellent adhesive property through drying and press bonding with heat at a temperature in a wide range regardless of whether the temperature is low or high, is excellent in water resistance and gasohol resistance and is less tacky. That is, the present invention provides the dispersed resin composition containing (a) a polyolefin resin, (b) a (meth)acrylic acid homopolymer or copolymer having a side chain comprising an esterified alkyl group, (c) a basic substance and (d) water or a hydrophilic substance, and a process for producing the same.
摘要翻译： 本发明的目的是提供一种聚烯烃树脂分散体组合物，其中分散的树脂对水或亲水物质是稳定的，并且对非极性基材具有粘合性，特别是表面具有粘合性的聚烯烃类基材 未经处理，涂布性优异，无论温度低还是高，在宽范围的温度下通过干燥和加热粘合而具有优异的粘合性，耐水性和耐汽油醇性优异，为 少发粘 也就是说，本发明提供了包含（a）聚烯烃树脂的分散树脂组合物，（b）具有侧链的（甲基）丙烯酸均聚物或共聚物，其包含酯化的烷基，（c）碱性物质和（d ）水或亲水性物质，及其制造方法。
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7.发明申请公开(公告)号：US20070224435A1
公开(公告)日：2007-09-27
申请号：US11597916
申请日：2005-05-31
申请人： Eiji Nishijima , Koji Masumoto , Takayuki Hirose , Naosuke Komoto , Hironori Muramoto , Kensho Okayama
发明人： Eiji Nishijima , Koji Masumoto , Takayuki Hirose , Naosuke Komoto , Hironori Muramoto , Kensho Okayama
IPC分类号： C08F8/20 , C08F8/46 , C08L23/28 , C09D11/00 , C09D123/28
CPC分类号： C08F8/20 , C08F255/023 , C08L23/10 , C08L51/06 , C09D11/102 , C09D11/106 , C09D123/28 , C09D151/06 , C09J123/28 , C09J151/06 , Y10T428/3154 , Y10T428/31855 , C08F220/06
摘要： A novel binder resin which attains good adhesion to various substrates such as polyolefin resins, vinyl chloride resins, polycarbonate resins, polyethylene terephthalate resins, acrylonitrile/butadiene/styrene resins, and nylon resins even by low-temperature baking and has excellent solubility in solvent. Namely, a chlorinated propylene random copolymer produced by subjecting a propylene random copolymer which is obtained by copolymerizing propylene with other alpha-olefins by using a metallocene catalyst as the polymerization catalyst and which has a melting point (Tm) of less than 115° C. as determined with a differential scanning calorimeter (DSC) to thermally kneaded preferably at a temperature ranging from the melting point of the copolymer to 350° C. and chlorination successively.
摘要翻译： 即使通过低温烘烤也能够对各种基材例如聚烯烃树脂，氯乙烯树脂，聚碳酸酯树脂，聚对苯二甲酸乙二醇酯树脂，丙烯腈/丁二烯/苯乙烯树脂和尼龙树脂具有良好的粘附性并且在溶剂中具有优异的溶解性的新型粘结剂树脂。 即，通过使用茂金属催化剂作为聚合催化剂并且熔点（Tm）小于115℃的丙烯与其它α-烯烃共聚得到的丙烯无规共聚物制备的氯化丙烯无规共聚物。 如用差示扫描量热计（DSC）测定的，优选在从共聚物的熔点至350℃的温度下进行热捏合，并依次进行氯化。
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公开(公告)号：US20110274941A1
公开(公告)日：2011-11-10
申请号：US13145373
申请日：2010-01-21
申请人： Minoru Yada , Yuuki Kokufu , Yuu Takata , Hideo Hosaka , Kenichi Fujino
发明人： Minoru Yada , Yuuki Kokufu , Yuu Takata , Hideo Hosaka , Kenichi Fujino
CPC分类号： C08F287/00 , C08F293/005 , C09D4/06 , C09D11/101 , C09K3/10 , C09K2200/0617 , C09K2200/0625 , Y10T428/31913
摘要： It is an object of the present invention to provide an active energy ray curable resin composition exhibiting good adhesion to a polyolefin-based resin base material. More specifically, there is provided an active energy ray curable resin composition comprising: a block copolymer (C) that includes a polymer block (A) composed mainly of an olefin-based monomer unit and a polymer block (B) composed of a vinyl-based monomer unit having a carboxyl group, a carboxylic anhydride group, or a sulfonic acid group and/or a second vinyl-based monomer unit copolymerizable with the aforementioned vinyl-based monomer unit, the block copolymer (C) having a weight-average molecular weight from 5,000 to 100,000; and an active energy ray curable compound (D).
摘要翻译： 本发明的目的是提供对聚烯烃类树脂基材具有良好粘合性的活性能量射线固化性树脂组合物。 更具体地，提供了一种活性能量射线固化树脂组合物，其包含：嵌段共聚物（C），其包含主要由烯烃类单体单元组成的聚合物嵌段（A）和由乙烯基类单体组成的聚合物嵌段（B） 具有羧基的羧基单体单元，羧酸酐基或磺酸基和/或与上述乙烯基类单体单元共聚的第二乙烯基类单体单元，嵌段共聚物（C）具有重均分子量 重量从5,000到100,000; 和活性能量射线固化性化合物（D）。
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公开(公告)号：US20100004383A1
公开(公告)日：2010-01-07
申请号：US12375032
申请日：2007-07-18
IPC分类号： C08L23/12 , C08F210/00 , C08F210/06 , C08L23/00
CPC分类号： C08L23/0815 , C08F8/00 , C08F255/00 , C08F255/02 , C08F299/00 , C08L23/10 , C08L51/06 , C08L2205/02 , C08L2666/02 , C08L2666/04 , C09J151/06 , C09J155/005 , C08F10/00 , C08L2666/24 , C08L2666/06
摘要： It is an object of the present invention to provide a modified polyolefin resin adhesive agent which is excellent in adhesiveness to a nonpolar substrate, particularly a poorly adhesive polyolefin substrate to which no surface treatment has been given and to a polar substrate, develops the excellent adhesiveness by drying or thermal compression bonding at relatively low temperature, and exhibits a low tack. That is, the present invention provides the modified polyolefin resin obtained by modifying a polyolefin resin with (A) a polarity imparting agent which is at least one selected from chlorine, unsaturated carboxylic acid, derivatives and anhydrides of unsaturated carboxylic acid and radical polymerizable monomers; and (B) an ethylene-α-olefin copolymer having an unsaturated bond at one end, and use of said modified polyolefin resin as an aqueous resin composition or an organic solvent resin composition.
摘要翻译： 本发明的目的是提供一种与非极性基材，特别是不进行表面处理的粘合性差的聚烯烃基材和极性基材粘合性优异的改性聚烯烃树脂粘合剂，具有优异的粘合性 通过在相对低的温度下进行干燥或热压接，并且具有低的粘性。 也就是说，本发明提供了通过（A）极性赋予剂（其为选自氯，不饱和羧酸，不饱和羧酸的衍生物和酸酐以及可自由基聚合的单体）中的至少一种来改性聚烯烃树脂而获得的改性聚烯烃树脂; 和（B）在一端具有不饱和键的乙烯-α-烯烃共聚物，使用所述改性聚烯烃树脂作为水性树脂组合物或有机溶剂树脂组合物。
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公开(公告)号：US08236900B2
公开(公告)日：2012-08-07
申请号：US12375032
申请日：2007-07-18
CPC分类号： C08L23/0815 , C08F8/00 , C08F255/00 , C08F255/02 , C08F299/00 , C08L23/10 , C08L51/06 , C08L2205/02 , C08L2666/02 , C08L2666/04 , C09J151/06 , C09J155/005 , C08F10/00 , C08L2666/24 , C08L2666/06
摘要： It is an object of the present invention to provide a modified polyolefin resin adhesive agent which is excellent in adhesiveness to a nonpolar substrate, particularly a poorly adhesive polyolefin substrate to which no surface treatment has been given and to a polar substrate, develops the excellent adhesiveness by drying or thermal compression bonding at relatively low temperature, and exhibits a low tack. That is, the present invention provides the modified polyolefin resin obtained by modifying a polyolefin resin with (A) a polarity imparting agent which is at least one selected from chlorine, unsaturated carboxylic acid, derivatives and anhydrides of unsaturated carboxylic acid and radical polymerizable monomers; and (B) an ethylene-α-olefin copolymer having an unsaturated bond at one end, and use of said modified polyolefin resin as an aqueous resin composition or an organic solvent resin composition.
摘要翻译： 本发明的目的是提供一种与非极性基材，特别是不进行表面处理的粘合性差的聚烯烃基材和极性基材粘合性优异的改性聚烯烃树脂粘合剂，具有优异的粘合性 通过在相对低的温度下进行干燥或热压接，并且具有低的粘性。 也就是说，本发明提供了通过（A）极性赋予剂（其为选自氯，不饱和羧酸，不饱和羧酸的衍生物和酸酐和自由基聚合性单体）中的至少一种来改性聚烯烃树脂而获得的改性聚烯烃树脂; 和（B）一端具有不饱和键的乙烯-α-烯烃共聚物，使用所述改性聚烯烃树脂作为水性树脂组合物或有机溶剂树脂组合物。
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