High-performance triple-crosslinked polymer and preparation method thereof

    公开(公告)号:US11566112B2

    公开(公告)日:2023-01-31

    申请号:US16853785

    申请日:2020-04-21

    Abstract: A high-performance triple-crosslinked polymer and a preparation method thereof are provided. The polymer is obtained by curing and cross-linking a monomer having two epoxy groups, a cross-linking monomer and a functional monomer. The polymer contains a cross-linking network formed by covalent bonds and two types of multi-level hydrogen bonds with different strengths. The interaction strength between the covalent bonds and the two types of hydrogen bonds decreases in a gradient. The dilemma of the strength-ductility tradeoff in a high-performance polymer is overcome by forming a triple-crosslinked network with covalent bonds and multi-level hydrogen bonds with different strengths in the polymer. The dynamic and hierarchical hydrogen bonds are broken and recombined timely and continuously to concurrently maintain the complete structure of the polymer network and enable the polymer network to quickly respond to the transmission and dissipation of the external environment.

    Vertical ground heat exchanger for reducing temperature in carbonaceous shale rock mass and preventing roadbed frost heave

    公开(公告)号:US11549222B2

    公开(公告)日:2023-01-10

    申请号:US17004013

    申请日:2020-08-27

    Inventor: Baolong Zhu Xin Li

    Abstract: A vertical ground heat exchanger for reducing the temperature in the carbonaceous shale rock mass and preventing roadbed frost heave includes a heating mechanism, a heat releasing component respectively connected to both ends of the heating mechanism and a refrigeration heat exchange mechanism. The refrigeration heat exchange mechanism is connected to the lower end of the heating mechanism through a heat transfer pipeline and communicates with the heat releasing component. The heat releasing component includes a double-layer heat exchange tube component, a gas-liquid separator and a branch tube, wherein the double-layer heat exchange tube component is respectively connected to the both ends of the heating mechanism, the gas-liquid separator is connected to the double-layer heat exchange tube component, and the branch tube is connected between the gas-liquid separator and the refrigeration heat exchange mechanism. The double-layer heat exchange tube component includes an upper bellows and a lower bellows.

    Method for electrochemical extraction of uranium from seawater using oxygen vacancy (OV)-containing metal oxide

    公开(公告)号:US11384444B2

    公开(公告)日:2022-07-12

    申请号:US17433613

    申请日:2020-12-11

    Abstract: A method for electrochemical extraction of uranium from seawater using an oxygen vacancy (OV)-containing metal oxide includes the following steps: adding glycerin to a solution of indium nitrate in isopropanol, transferring a resulting mixture to a reactor, and conducting reaction to obtain a spherical indium hydroxide solid; dissolving the solid in deionized water, transferring a resulting solution to the reactor, and conducting reaction to obtain a flaky indium hydroxide solid; calcining the solid to obtain calcined OV-containing In2O3-x; adding the In2O3-x to ethanol, and adding a membrane solution; coating a resulting solution uniformly on carbon paper, and naturally drying the carbon paper; clamping dried carbon paper with a gold electrode for being used as a working electrode for a three-electrode system; and adding simulated seawater to an electrolytic cell, placing the three-electrode system in the simulated seawater, and stirring the simulated seawater for electrolysis to extract uranium from the seawater.

    Method for comparative analysis on mechanical strength of polymer materials

    公开(公告)号:US10564099B2

    公开(公告)日:2020-02-18

    申请号:US15883973

    申请日:2018-01-30

    Abstract: A method for detecting or comparing mechanical strength of macro-molecular polymer materials. The detecting method has the steps of measuring the mechanical strength and the maximum value of the fluorescence absorption spectrum of each of the plurality of samples to form a curve relationship or function relationship between the maximum value of the fluorescence absorption spectrum and the mechanical strength; measuring the maximum value of the fluorescence absorption spectrum of the target material, and using the curve relationship or the function relationship to obtain the mechanical strength of the target material. The plurality of samples and the target material are both prepared from a macro-molecular polymer, and the macro-molecular polymer may be composed of disulfonate-difluorobenzophenone, hydroxyindole and difluorobenzophenone as monomers, and the sulfonate groups of the disulfonate-difluorobenzophenone have metal cations. An object of the method is to identify mechanical properties of polymer materials by fluorescence nondestructive detection.

    Method for recovering, regenerating and repairing polymer

    公开(公告)号:US10119005B1

    公开(公告)日:2018-11-06

    申请号:US15883795

    申请日:2018-01-30

    Abstract: A method for recovering, regenerating and repairing polymer. The method includes immersing a polymer in an acid solution so that hydrogen ions of the acid solution replace metal cations of the polymer to obtain an acid-treated polymer, and to realize the recovery of the polymers. Subsequently, the acid-treated polymer is immersed in an alkaline solution to obtain a base-treated polymer to realize the regeneration of the polymers. The polymer is composed of disulfonate-difluorobenzophenone, hydroxyindole and difluorobenzophenone as monomers, and sulfonate groups of the disulfonate-difluorobenzophenone have metal cations. The method replaces the metal cations with hydrogen ions to realize the recovery of the polymers and reduce environmental pollutions. The regeneration of polymers is realized by replacing the hydrogen ions with the metal cation, and resource recycling. Through the process of local repair, the service life of the product of polymers can be prolonged.

    Method for processing titanium extraction slag and carbon extracted and dechlorinated tailing

    公开(公告)号:US11905575B2

    公开(公告)日:2024-02-20

    申请号:US17529834

    申请日:2021-11-18

    CPC classification number: C22B7/04 C22B7/006 C22B34/1209 C22B34/1259

    Abstract: Provided are a method for processing titanium extraction slag and a carbon extraction and dechlorination tailing. The method comprises the following steps that a titanium extraction slag raw material is ground to obtain a treated material with a particle size being 0.3˜120 μm and d90≤90 μm; a first solvent and a treated material are mixed with a liquid-solid ratio of (3.5˜4.5): 1 L/kg, and a first capturing agent and a first foaming agent are added for mixing and then subjected to a primary flotation to obtain a floating product and a sinking product; and a second solvent is added into the floating product to adjust the liquid-solid ratio to (4˜5): 1 L/kg, a second capturing agent and a second foaming agent are added for mixing and then subjected to a secondary flotation to obtain a foam product; the foam product is filtered and dried to obtain a refined carbon, and the sinking product is filtered and dried to obtain the carbon extraction and dechlorination tailing, wherein the d90≤90 μm means that more than 90% of the powder in the treated material has a particle size of less than 90 μm. The method has the advantages that carbon in the titanium-extracted slag can be recycled, chlorine is removed, and the carbon extraction and dechlorination tailing can be used as a building material raw material.

    METHOD FOR PROCESSING TITANIUM EXTRACTION SLAG AND CARBON EXTRACTED AND DECHLORINATED TAILING

    公开(公告)号:US20220170132A1

    公开(公告)日:2022-06-02

    申请号:US17529834

    申请日:2021-11-18

    Abstract: Provided are a method for processing titanium extraction slag and a carbon extraction and dechlorination tailing. The method comprises the following steps that a titanium extraction slag raw material is ground to obtain a treated material with a particle size being 0.3˜120 μm and d90≤90 μm; a first solvent and a treated material are mixed with a liquid-solid ratio of (3.5˜4.5): 1 L/kg, and a first capturing agent and a first foaming agent are added for mixing and then subjected to a primary flotation to obtain a floating product and a sinking product; and a second solvent is added into the floating product to adjust the liquid-solid ratio to (4˜5): 1 L/kg, a second capturing agent and a second foaming agent are added for mixing and then subjected to a secondary flotation to obtain a foam product; the foam product is filtered and dried to obtain a refined carbon, and the sinking product is filtered and dried to obtain the carbon extraction and dechlorination tailing, wherein the d90≤90 μm means that more than 90% of the powder in the treated material has a particle size of less than 90 μm. The method has the advantages that carbon in the titanium-extracted slag can be recycled, chlorine is removed, and the carbon extraction and dechlorination tailing can be used as a building material raw material.

Patent Agency Ranking