公开(公告)号：US07404827B2

公开(公告)日：2008-07-29

申请号：US10567327

申请日：2004-08-04

申请人： Akira Ishikawa ,  Masahito Chiwaki ,  Motoko Fujii ,  Akira Fujiu

发明人： Akira Ishikawa ,  Masahito Chiwaki ,  Motoko Fujii ,  Akira Fujiu

IPC分类号： D06M10/00

CPC分类号： C11D1/72 ,  C11D3/3742 ,  D06M13/463 ,  D06M15/53 ,  D06M15/6436 ,  D06M15/647

摘要： The present invention relates to a fiber product treating agent composition containing (a) a nonionic surfactant containing 1 to 3 polyoxyalkylene groups having the number-average addition mol number of the oxyalkylene group of 50 to 200 and 1 to 3 hydrocarbon groups having 14 to 32 carbon atoms and having an HLB of 16 or more and a melting point of 30 to 80° C., and (b) an amino-modified silicone compound in a mass ratio of the component (a)/the component (b) of 4/1 to 1/4.

摘要翻译： 本发明涉及一种纤维制品处理剂组合物，其含有（a）含有1〜3个氧化烯基的加成摩尔数为50〜200，1〜3个碳原子数为14〜32的聚氧化烯的非离​​子表面活性剂 碳原子，HLB为16以上，熔点为30〜80℃，（b）成分（a）/成分（b）的质量比为4的氨基改性硅氧烷化合物 / 1至1/4。

公开(公告)号：US5395542A

公开(公告)日：1995-03-07

申请号：US93136

申请日：1993-07-19

申请人： Toshio Nozaki ,  Akira Fujiu ,  Yasushi Kajihara

发明人： Toshio Nozaki ,  Akira Fujiu ,  Yasushi Kajihara

IPC分类号： A61K8/00 ,  A61K8/55 ,  A61Q5/02 ,  A61Q19/10 ,  C07F9/11 ,  C11D1/34 ,  C11D1/37 ,  C11D7/36 ,  C11D3/36

CPC分类号： A61Q5/02 ,  A61K8/55 ,  A61Q19/10 ,  C11D1/345 ,  C11D1/37

摘要： A liquid detergent composition containing the following components (a) and (b) at a proportion of (a)/[(a)+(b)] of 0.4 -1:(a) phosphoric ester of the following formula (1) ##STR1## where R.sup.1 is a C.sub.8 -C.sub.12 linear hydrocarbon group, R.sup.4 is a C.sub.1 -C.sub.4 linear hydrocarbon group and X.sup.1 and X.sup.2 are, independently, a potassium atom or a hydrogen atom; and(b) phosphoric ester of the following formula (2): ##STR2## wherein R.sup.2 is a C.sub.11 -C.sub.15 linear hydrocarbon group and X.sup.3 and X.sup.4 are, independently, a potassium atom or a hydrogen atom.

摘要翻译： （a）/ [（a）+（b）]的比例为0.4:1的含有以下组分（a）和（b）的液体洗涤剂组合物：（a）下式（1）的磷酸酯 （1）其中R1是C8-C12直链烃基，R4是C1-C4直链烃基，X1和X2独立地是钾原子或氢原子; 和（b）下式（2）的磷酸酯：其中R2是C11-C15直链烃基，X3和X4独立地是钾原子或氢原子。

公开(公告)号：US20060277688A1

公开(公告)日：2006-12-14

申请号：US10567327

申请日：2004-08-04

申请人： Akira Ishikawa ,  Masahito Chiwaki ,  Motoko Fujji ,  Akira Fujiu

发明人： Akira Ishikawa ,  Masahito Chiwaki ,  Motoko Fujji ,  Akira Fujiu

IPC分类号： C11D3/00

CPC分类号： C11D1/72 ,  C11D3/3742 ,  D06M13/463 ,  D06M15/53 ,  D06M15/6436 ,  D06M15/647

摘要： The present invention relates to a fiber product treating agent composition containing (a) a nonionic surfactant containing 1 to 3 polyoxyalkylene groups having the number-average addition mol number of the oxyalkylene group of 50 to 200 and 1 to 3 hydrocarbon groups having 14 to 32 carbon atoms and having an HLB of 16 or more and a melting point of 30 to 80° C., and (b) an amino-modified silicone compound in a mass ratio of the component (a)/the component (b) of 4/1 to 1/4.

摘要翻译： 本发明涉及一种纤维制品处理剂组合物，其含有（a）含有1〜3个氧化烯基的加成摩尔数为50〜200，1〜3个碳原子数为14〜32的聚氧化烯的非离​​子表面活性剂 碳原子，HLB为16以上，熔点为30〜80℃，（b）成分（a）/成分（b）的质量比为4的氨基改性硅氧烷化合物 / 1至1/4。

公开(公告)号：US06407054B2

公开(公告)日：2002-06-18

申请号：US09726577

申请日：2000-12-01

申请人： Takaya Sakai ,  Makio Tetsu ,  Makoto Kubo ,  Akira Fujiu

发明人： Takaya Sakai ,  Makio Tetsu ,  Makoto Kubo ,  Akira Fujiu

IPC分类号： C11D166

CPC分类号： A61Q5/02 ,  A61K8/42 ,  A61K8/44 ,  A61Q19/10 ,  C11D1/46 ,  C11D1/523 ,  C11D1/528 ,  C11D1/645 ,  C11D3/2065

摘要： There is provided a surfactant composition for detergents, which has its high detergency and foamability within a broad pH region even in the presence of solids. It has its excellent foamability, thickening property, water solubility and stability. The composition contains a component (a) represented by the following formula (I) and at least one component (b) represented by the formula (II) and (III), in the total amount of 0.1 to 80% by weight, at the ratio of (a)/(b) by weight of from 99.9/0.1 to 70/30. In the formula (I), R1CO— is a saturated or unsaturated acyl group which has 6 to 24 carbon atoms and which may have hydroxy group; R2 is a linear or branched alkyl group having 1 to 3 carbon atoms; and R3 is a linear or branched alkylene or alkenylene group having 1 to 6 carbon atoms. In the formula (II) and (III), R1CO—, R2 and R3 have the same meanings as above and R4CO— is a saturated or unsaturated acyl group which has 6 to 24 carbon atoms and which may have a hydroxy group. The composition may also contain a surfactant other than the above-mentioned components (a) and (b).

摘要翻译： 提供了用于洗涤剂的表面活性剂组合物，即使在固体存在下，其在宽pH范围内也具有高洗涤性和发泡性。 它具有优异的起泡性，增稠性，水溶性和稳定性。 组合物含有由下式（I）表示的组分（a）和由式（II）和（III）表示的至少一种组分（b），其总量为0.1-80重量％ （a）/（b）的比例为99.9 / 0.1〜70/30。在式（I）中，R 1 CO-为碳原子数6〜24的饱和或不饱和的酰基，可以具有羟基 ; R2是具有1至3个碳原子的直链或支链烷基; 在式（II）和（III）中，R 1 CO-，R 2和R 3具有与上述相同的含义，并且R 4 CO-是饱和或不饱和的酰基 具有6至24个碳原子并且可以具有羟基的基团。 组合物还可以含有除上述成分（a）和（b）以外的表面活性剂。

公开(公告)号：US06346259B1

公开(公告)日：2002-02-12

申请号：US09458992

申请日：1999-12-10

申请人： Hiroyuki Terasaki ,  Akira Fujiu ,  Kazuhisa Fukuhara ,  Yoshihisa Kitano

发明人： Hiroyuki Terasaki ,  Akira Fujiu ,  Kazuhisa Fukuhara ,  Yoshihisa Kitano

IPC分类号： A61K706

CPC分类号： A61Q5/00 ,  A61K8/44 ,  A61Q5/12 ,  C07C227/08 ,  C07C229/12

摘要： The present invention provides a method for the easy preparation of a mixture comprising betaine alkyl ester which gives good softness, smoothness and oily feeling to hair. Thus, according to the present invention, a specific monohalogen carboxylic acid alkyl-ester is made to react with a specific tertiary amine using a specific long-chain alcohol as a reaction solvent and, after a specific betaine alkyl ester is obtained, the excessive above-mentioned tertiary amine is removed whereupon a mixture comprising the said long-chain alcohol and the said betaine alkyl ester is obtained.

摘要翻译： 本发明提供了一种容易地制备包含甜菜碱烷基酯的混合物的方法，所述甜菜碱烷基酯对头发具有良好的柔软性，平滑性和油性感。 因此，根据本发明，使特定的单卤素羧酸烷基酯与特定的叔胺反应，使用特定的长链醇作为反应溶剂，并且在得到特定的甜菜碱烷基酯后，过量的 除去所述叔胺，由此获得包含所述长链醇和所述甜菜碱烷基酯的混合物。

公开(公告)号：US06407277B1

公开(公告)日：2002-06-18

申请号：US08849211

申请日：1997-06-09

申请人： Akira Matsunaga ,  Akira Fujiu ,  Shinji Tsuyutani ,  Toshio Nozaki ,  Masayuki Ueda

发明人： Akira Matsunaga ,  Akira Fujiu ,  Shinji Tsuyutani ,  Toshio Nozaki ,  Masayuki Ueda

IPC分类号： C07F909

CPC分类号： C07F9/11 ,  C07F9/09

摘要： An organic hydroxyl compound is reacted with a phosphorylating agent comprising phosphorus pentaoxide and at least one compound selected from the group consisting of water, phosphoric acid and polyphosphoric acid and having a value represented by formula (I) of from 0.5 to 1.0, under such a condition that the ratio as defined by formula (II) has a value in the range of from 2.8 to 3.2; or alternatively, an organic hydroxyl compound is reacted with the above phosphorylating agent under such a condition that the ratio as defined by formula (II) has a value in the range of from exceeding 3.2 up to 6.4 and then phosphorus pentaoxide is added to the reaction product in such an amount that the ratio as defined by formula (II) has a value in the range of from 2.8 to 3.2 with respect to the total feeds of the starting materials to conduct further reaction. Said process enables the preparation of a phosphoric ester mixture which is excellent in hue and odor, is reduced in the amount of orthophosphoric acid formed as a by-product and contains a phosphoric monoester useful as the component of detergent in an increased amount.

摘要翻译： 使有机羟基化合物与包含五氧化二磷和至少一种选自水，磷酸和多磷酸的化合物的磷酸化剂与式（I）表示的值为0.5至1.0的磷酸化剂反应， 条件是由式（II）定义的比例的值在2.8至3.2的范围内; 或者将有机羟基化合物与上述磷酸化剂反应，使得式（II）定义的比例在超过3.2至6.4的范围内，然后向反应中加入五氧化二磷 产物的量使得由式（II）定义的比例相对于进料进一步反应的起始原料的总进料的值在2.8至3.2的范围内。 所述方法能够制备色调和气味优异的磷酸酯混合物，作为副产物形成的正磷酸的量减少，并且含有可用作增加量的洗涤剂组分的磷酸单酯。

公开(公告)号：US6034261A

公开(公告)日：2000-03-07

申请号：US245843

申请日：1999-02-08

申请人： Akira Matsunaga ,  Akira Fujiu ,  Shinji Tsuyutani ,  Toshio Nozaki ,  Masayuki Ueda

发明人： Akira Matsunaga ,  Akira Fujiu ,  Shinji Tsuyutani ,  Toshio Nozaki ,  Masayuki Ueda

IPC分类号： C07F9/09 ,  C07F9/11

CPC分类号： C07F9/11 ,  C07F9/09

摘要： An organic hydroxyl compound is reacted with a phosphorylating agent comprising phosphorus pentaoxide and at least one compound selected from the group consisting of water, phosphoric acid and polyphosphoric acid and having a value represented by formula (I) of from 0.5 to 1.0, under such a condition that the ratio as defined by formula (II) has a value in the range of from 2.8 to 3.2; or alternatively, an organic hydroxyl compound is reacted with the above phosphorylating agent under such a condition that the ratio as defined by formula (II) has a value in the range of from exceeding 3.2 up to 6.4 and then phosphorus pentaoxide is added to the reaction product in such an amount that the ratio as defined by formula (II) has a value in the range of from 2.8 to 3.2 with respect to the total feeds of the starting materials to conduct further reaction: ##EQU1## The above process produces a phosphoric ester mixture that is excellent in hue and odor, is reduced in the amount of orthophosphoric acid and contains a phosphoric monoester useful as a component of a detergent.

摘要翻译： 使有机羟基化合物与包含五氧化二磷和至少一种选自水，磷酸和多磷酸的化合物的磷酸化剂与式（I）表示的值为0.5至1.0的磷酸化剂反应， 条件是由式（II）定义的比例的值在2.8至3.2的范围内; 或者将有机羟基化合物与上述磷酸化剂反应，使得式（II）定义的比例在超过3.2至6.4的范围内，然后向反应中加入五氧化二磷 产物的量使得由式（II）定义的比例相对于进料进一步反应的起始原料的总进料，其值在2.8至3.2的范围内。上述方法产生磷酸酯混合物，其中 具有优异的色调和气味，正磷酸的量减少，并含有可用作洗涤剂组分的磷酸单酯。

公开(公告)号：US5219562A

公开(公告)日：1993-06-15

申请号：US709820

申请日：1991-06-04

申请人： Akira Fujiu ,  Naohisa Kure ,  Yoshiko Ogura

发明人： Akira Fujiu ,  Naohisa Kure ,  Yoshiko Ogura

IPC分类号： A61K8/00 ,  A61K8/46 ,  A61Q5/00 ,  A61Q5/04 ,  C07C323/12

CPC分类号： A61Q5/04 ,  A61K8/46 ,  C07C323/12

摘要： A hair treating composition comprising one or more thioglyceryl ethers provides effective wave formation, with a minimized mercapto smell and minimized irritation to the skin.