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    Reactive triazinyl dyestuffs
    2.
    发明授权
    Reactive triazinyl dyestuffs 失效
    活性三嗪染料

    公开(公告)号：US3956300A

    公开(公告)日：1976-05-11

    申请号：US495122

    申请日：1974-08-05

    申请人： Peter William Austin ,  Alan Thomas Costello ,  Allen Crabtree

    发明人： Peter William Austin ,  Alan Thomas Costello ,  Allen Crabtree

    IPC分类号： C09B11/00 ,  C09B11/28 ,  C09B62/002 ,  C09B62/44 ,  C07D251/50 ,  C07D251/44

    CPC分类号： C09B62/0025 ,  C09B62/4401

    摘要： Dyestuffs of the formula: ##SPC1##In whichR.sup.1 is H, benzyl, sulphobenzyl or an alkyl group of 1-4 carbon atoms which may be substituted by OH, CN, OSO.sub.3 H, CO.sub.2 H, halogen, SO.sub.3 H or NHQ, Q representing a cellulose-reactive group,R.sup.2 is H, or an alkyl group of 1-4 carbon atoms which may be substituted by OH, CN, OSO.sub.3 H, CO.sub.2 H, halogen or SO.sub.3 H, orNr.sup.1 r.sup.2 is the N-linked radical of a nitrogen-containing heterocyclic compound containing 5 or 6 atoms in the heterocyclic ring,R.sup.3 is H or an alkyl group of 1-4 carbon atoms which may be substituted by OH,R.sup.4 is benzyl which may be substituted by SO.sub.3 H or NHQ, an alkyl group of 1 to 4 carbon atoms which may be substituted by OH, SO.sub.3 H or NHQ or a phenyl radical which may be substituted by SO.sub.3 H, CO.sub.2 H, halogen, alkyl or alkoxy of 1 to 4 carbon atoms or NHQ, and the benzene ring A may be further substituted by an alkyl or alkoxy group of 1-4 carbon atoms, halogen, NO.sub.2 or NHQ, and wherein NR.sup.1 R.sup.2 and NR.sup.3 R.sup.4 are different and the dyestuff as a whole contains 1 or 2 cellulose-reactive groups and at least one further SO.sub.3 H group.The dyestuffs are particularly suitable for dyeing cellulose textile materials in the presence of alkalies to give bright reddish or violet shades having good fastness to washing. The light fastness of the new dyes is much better than could have been expected from the known fastness of basic xanthene dyes applied to cellulose with the aid of mordants.

    摘要翻译： 染料的配方：

    Disperse monoazo dyestuffs containing a thiophene residue
    3.
    发明授权
    Disperse monoazo dyestuffs containing a thiophene residue 失效
    分散含有噻吩残留物的单偶氮染料

    公开(公告)号：US4079050A

    公开(公告)日：1978-03-14

    申请号：US654170

    申请日：1976-02-02

    申请人： David Boyd Baird ,  Alan Thomas Costello ,  Brian Ribbons Fishwick ,  Robert David McClelland ,  Peter Smith

    发明人： David Boyd Baird ,  Alan Thomas Costello ,  Brian Ribbons Fishwick ,  Robert David McClelland ,  Peter Smith

    IPC分类号： C07D333/38 ,  C07D333/44 ,  C09B29/00 ,  C09B29/06 ,  C09B29/08 ,  C09B29/26

    CPC分类号： C07D333/38 ,  C07D333/44 ,  C09B29/00 ,  C09B29/06 ,  C09B29/0807

    摘要： The water-insoluble monoazo dyestuffs, free from sulphonic acid and carboxylic acid groups, which are of the formula: ##STR1## wherein Y is hydrogen, lower alkyl, optionally substituted phenyl or nitro; Z is nitro, cyano, optionally substituted phenyl, optionally substituted lower alkoxycarbonyl or carbonamido; T is hydrogen, optionally substituted lower alkyl or optionally substituted lower alkoxy;W is an acylamino group of the formula: ##STR2## wherein X.sup.1 is hydrogen or lower alkyl, X.sup.2 is hydrogen or an optionally substituted hydrocarbon or heterocyclic radical, and A is a direct link or --0-- or ##STR3## and R.sup.1 and R.sup.2 each independently represent a hydrogen atom or an optionally substituted alkyl radical or R.sup.1 and R.sup.2 together form with the nitrogen atom N a 5- or 6-membered nitrogen-containing heterocyclic ring, a process for the manufacture of the said dyestuffs by diazotization and coupling, and the use of the said dyestuffs for coloring synthetic textile materials, in particular aromatic polyester textile materials which they color in violet to green shades possessing excellent fastness to light, to wet treatments and to dry heat treatments.

    摘要翻译： 不溶于磺酸和羧酸基的水不溶性单偶氮染料，其具有下式：其中Y为氢，低级烷基，任选取代的苯基或硝基; Z是硝基，氰基，任选取代的苯基，任选取代的低级烷氧基羰基或碳酰氨基; T是氢，任选取代的低级烷基或任选取代的低级烷氧基; W是下式的酰氨基，其中X 1是氢或低级烷基，X 2是氢或任选取代的烃或杂环基，A是直链或-O-或R 1和R 2 各自独立地表示氢原子或任选取代的烷基，或者R 1和R 2与氮原子一起一起形成5-或6-元含氮杂环，通过重氮化和偶联制备所述染料的方法， 以及所述染料用于着色合成纺织材料，特别是紫色的芳族聚酯纺织材料，具有优异的耐光牢度的绿色色调，湿法处理和干热处理。