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公开(公告)号：US06235671B1
公开(公告)日：2001-05-22
申请号：US09292039
申请日：1999-04-14
Applicant: Ian McKay , Alison Ciupa , P. Scott Chisholm
Inventor： Ian McKay , Alison Ciupa , P. Scott Chisholm
IPC: B01J3100
CPC classification number: B01J31/143 , B01J23/007 , B01J31/1805 , B01J31/2295 , B01J31/26 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F10/00 , C08F210/16 , C08F4/65916 , C08F4/6592 , C08F210/08 , C08F2500/03
Abstract: A heterogeneous catalyst for olefin polymerization is prepared by spray drying a mixture of a metallocene catalyst, a cocatalyst and a hydrotalcite. It Preferred hydrotalcites are magnesium-aluminum hydroxy carbonates. The catalysts are very active for ethylene polymerization. The hydrotalcite used in this invention are generally defined by the formula: (Mg1−x Alx(OH)2)n+An−x/n·m H2O wherein X is from 0 to 0.5, m is from 0 to 20 and An− is an anion having a charge of n. Preferred hydrotalcites are those in which the anion A is a carbonate and which have been dried of adsorbed water.
Abstract translation: 通过喷雾干燥茂金属催化剂，助催化剂和水滑石的混合物来制备用于烯烃聚合的非均相催化剂。 优选的水滑石是羟基碳酸镁铝。 催化剂对于乙烯聚合是非常有活性的。 本发明中使用的水滑石通常由下式定义：其中X为0至0.5，m为0至20，An-为负电荷为n的阴离子。 优选的水滑石是阴离子A是碳酸盐并且已被吸附的水干燥的那些。
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公开(公告)号：US6013745A
公开(公告)日：2000-01-11
申请号：US905650
申请日：1997-08-04
Applicant: Ian McKay , Alison Ciupa , Arpad F. Somogyvari , Beth Lorraine Creed , Alan Rodney Sanger , David John Law , Ronald George Cavell
Inventor： Ian McKay , Alison Ciupa , Arpad F. Somogyvari , Beth Lorraine Creed , Alan Rodney Sanger , David John Law , Ronald George Cavell
CPC classification number: C08F10/00 , C08F110/02 , C08F210/16
Abstract: The present invention relates to the polymerization of one or more alpha olefins in the presence of a transition metal catalyst having either a heterobifunctional ligand, having a phosphorus and a nitrogen atom, or a bis-phosphinimine ligand having two nitrogen atoms, in the presence of an activator.
Abstract translation: 本发明涉及一种或多种α-烯烃的聚合反应，所述α-烯烃在具有磷和氮原子的异双官能配体或具有两个氮原子的双膦基亚胺配体的过渡金属催化剂的存在下， 激活剂。
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公开(公告)号：US06486273B1
公开(公告)日：2002-11-26
申请号：US09835985
申请日：2001-04-16
Applicant: Ian McKay , Alison Ciupa , Barbara Christine Hall
Inventor： Ian McKay , Alison Ciupa , Barbara Christine Hall
IPC: C08F406
CPC classification number: C08F10/00 , C08F4/65912 , C08F4/65916 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/04 , Y10S526/901 , Y10S526/943 , C08F4/65904 , C08F4/6592 , C08F2500/03 , C08F2500/04 , C08F2500/12 , C08F210/14
Abstract: A supported catalyst for the polymerization of olefins, especially ethylene, has at least two catalyst components having different propagation and/or termination constants. Each catalyst component must have at least one phosphinimine ligand. The polymer produced according to this invention has a broad molecular weight distribution. Catalysts according to this invention have a very surprising and desirable hydrogen response.
Abstract translation: 用于烯烃，特别是乙烯聚合的负载催化剂具有至少两种具有不同传播和/或终止常数的催化剂组分。 每个催化剂组分必须具有至少一个膦亚胺配体。 根据本发明生产的聚合物具有宽的分子量分布。 根据本发明的催化剂具有非常令人惊奇和期望的氢响应。
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公开(公告)号：US06235672B1
公开(公告)日：2001-05-22
申请号：US09616491
申请日：2000-07-14
Applicant: Ian McKay , Alison Ciupa , Barbara Christine Hall
Inventor： Ian McKay , Alison Ciupa , Barbara Christine Hall
IPC: B01J3118
CPC classification number: C08F10/00 , C08F4/65912 , C08F4/65916 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/04 , Y10S526/901 , Y10S526/943 , C08F4/65904 , C08F4/6592 , C08F2500/03 , C08F2500/04 , C08F2500/12 , C08F210/14
Abstract: A supported catalyst for the polymerization of olefins, especially ethylene, has at least two catalyst components having different propagation and/or termination constants. Each catalyst component must have at least one phosphinimine ligand. The polymer produced according to this invention has a broad molecular weight distribution. Catalysts according to this invention have a very surprising and desirable hydrogen response.
Abstract translation: 用于烯烃，特别是乙烯聚合的负载催化剂具有至少两种具有不同传播和/或终止常数的催化剂组分。 每个催化剂组分必须具有至少一个膦亚胺配体。 根据本发明生产的聚合物具有宽的分子量分布。 根据本发明的催化剂具有非常令人惊奇和期望的氢响应。
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