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公开(公告)号：US06884904B2
公开(公告)日：2005-04-26
申请号：US09833278
申请日：2001-04-12
IPC分类号： C08G18/10 , C08G18/12 , C08G18/42 , C08G18/48 , C08G18/76 , C09J109/00 , C09J175/04 , C09J175/06 , C09J175/08 , C07C271/28
CPC分类号： C09J175/04 , C08G18/10 , C08G18/7671
摘要： An MDI/polypropylene polyether prepolymer composition consisting essentially of at least 80 wt % perfect prepolymers and less than 2 wt % free MDI monomer suitable for use in polyurethane adhesive compositions optionally also comprising a curative for isocyanate groups.
摘要翻译： 一种MDI /聚丙烯聚醚预聚物组合物，其基本上由至少80重量％的完美预聚物和小于2重量％的游离MDI单体组成，适用于聚氨酯粘合剂组合物，任选地还含有异氰酸酯基团的固化剂。
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2.发明授权Polyamide curing agents based on mixtures of polyethyleneamines and piperazine derivatives 失效聚酰胺固化剂基于聚乙烯胺和哌嗪衍生物的混合物
公开(公告)号：US6008313A
公开(公告)日：1999-12-28
申请号：US974284
申请日：1997-11-19
CPC分类号： C08L63/00 , C08G59/4014 , C08G59/44 , C08G59/54 , C08G69/34 , C08L77/08 , C09D163/00
摘要： Compositions of amine terminated polyamide resins useful for curing epoxy resins are disclosed comprising combinations of fatty mono-acids, dimer acids, polyethyleneamines, and piperazine ring containing polyamines having an N--H functionality of 2 or 3 per mole selected from the group consisting of piperazine, or N-aminoalkylpiperazine, where the alkyl chain is a C2 to C6 alkyl chain, wherein the ratio of equivalents of fatty mono-acid to dimer acid can range from about 0.001:1 to about 1:1, the ratio of moles of piperazine ring containing polyamine to polyethylene amine can range from about 0.1:1 to about 1:1, and the ratio of moles of polyamine to equivalents of acid can range from about 0.6:1 to about 1.2:1. Coating compositions comprising these polyamide resins are also disclosed.
摘要翻译： 公开了可用于固化环氧树脂的胺封端的聚酰胺树脂的组合物，其包含脂族单酸，二聚酸，聚乙烯胺和含哌嗪环的组合，所述多胺具有NH 2官能度为2或3，每摩尔选自哌嗪或 N-氨基烷基哌嗪，其中烷基链是C2-C6烷基链，其中脂肪酸单体酸与二聚酸的当量比可以在约0.001:1至约1:1的范围内，含有哌嗪环的摩尔数 聚胺与聚乙烯胺的比可以在约0.1:1至约1:1的范围内，并且多胺的摩尔数与酸的当量之比可以在约0.6:1至约1.2:1的范围内。 还公开了包含这些聚酰胺树脂的涂料组合物。
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3.发明授权Controlled structure polyurethane prepolymers for polyurethane structural adhesives 有权用于聚氨酯结构粘合剂的控制结构聚氨酯预聚物公开(公告)号：US06866743B2
公开(公告)日：2005-03-15
申请号：US09833453
申请日：2001-04-12
IPC分类号： C09J175/04 , C08G18/10 , C09J5/00 , C09J175/08
CPC分类号： C09J175/08 , C08G18/10 , C08G18/6688
摘要： A structural polyurethane adhesive composition comprising a polyurethane reaction product and a curative for isocyanate groups, characterized in that the polyurethane reaction product consists essentially of at least 80 wt % perfect prepolymers and less than 2 wt % free isocyanate monomer.
摘要翻译： 一种包含聚氨酯反应产物和异氰酸酯基团固化剂的结构聚氨酯粘合剂组合物，其特征在于聚氨酯反应产物基本上由至少80重量％的完美预聚物和少于2重量％的游离异氰酸酯单体组成。
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公开(公告)号：US6046282A
公开(公告)日：2000-04-04
申请号：US3492
申请日：1998-01-06
CPC分类号： C08G73/0213 , C08G59/54 , C08G73/02 , C08L63/00
摘要： Reactive diluents comprise the amide and/or imidazoline reaction products of low molecular weight carboxylic acids, such as acetic acid, and polyalkyleneamines, such as 2-aminoethylpiperazine (AEP) and triethylenetetramine (TETA). The reactive diluents are prepared by condensation reaction of the carboxylic acid and the polyalkyleneamine at elevated temperature generating a mixture of unreacted polyalkyleneamine, amides and/or imidazolines. The reactive diluent reaction products are used to reduce the viscosity of high viscosity polyamidoamines prepared from fatty dimer acids and polyethyleneamines. Also disclosed is an epoxy composition comprising the epoxy curative composition of a polyamidoamine curing agent reduced in viscosity by the addition of the reactive diluent reaction product and an epoxy resin, such as the diglycidyl ether of bisphenol A.
摘要翻译： 反应性稀释剂包括低分子量羧酸如乙酸和聚亚烷基胺如2-氨基乙基哌嗪（AEP）和三亚乙基四胺（TETA）的酰胺和/或咪唑啉反应产物。 反应性稀释剂通过羧酸和聚亚烷基胺在升高的温度下的缩合反应制备，产生未反应的聚亚烷基胺，酰胺和/或咪唑啉的混合物。 反应性稀释剂反应产物用于降低由脂肪二聚酸和聚乙烯胺制备的高粘度聚酰胺胺的粘度。 还公开了一种环氧组合物，其包含通过添加反应性稀释剂反应产物而降低粘度的聚酰胺胺固化剂的环氧固化剂组合物和环氧树脂，例如双酚A的二缩水甘油醚。
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