摘要:
[Problem to be Solved]A Ni-based alloy product consisting of, by mass percent, C: 0.03 to 0.10%, Si: 0.05 to 1.0%, Mn: 0.1 to 1.5%, Sol.Al: 0.0005 to 0.04%, Fe: 20 to 30%, Cr: not less than 21.0% and less than 25.0%, W: exceeding 6.0% and not more than 9.0%, Ti: 0.05 to 0.2%, Nb: 0.05 to 0.35%, and B: 0.0005 to 0.006%, the balance being Ni and impurities, the impurities being P: 0.03% or less, S: 0.01% or less, N: less than 0.010%, Mo: less than 0.5%, and Co: 0.8% or less, wherein a value of effective B (Beff) defined by the formula, Beff (%)=B−(11/14)×N+(11/48)×Ti, is 0.0050 to 0.0300%, and the rupture elongation in a tensile test at 700° C. and at a strain rate of 10−6/sec is 20% or more. This alloy may contain one or more kinds of Cu, Ta, Zr, Mg, Ca, REM, and Pd.
摘要:
A high strength, ductile, and tough Ni-base heat resistant alloy comprises by mass percent, C: 0.1% or less, Si: 1% or less, Mn: 1% or less, Cr: not less than 15% to less than 28%, Fe: 15% or less, W: more than 5% to not more than 20%, Al: more than 0.5% to not more than 2%, Ti: more than 0.5% to not more than 2%, Nd: 0.001 to 0.1% and B: 0.0005 to 0.01%, with the balance being Ni and impurities. Impurity contents of P, S, Sn, Pb, Sb, Zn and As are P: 0.03% or less, S: 0.01% or less, Sn: 0.020% or less, Pb: 0.010% or less, Sb: 0.005% or less, Zn: 0.005% or less and As: 0.005% or less, and formulas of [0.015≦Nd+13.4×B≦0.13], [Sn+Pb≦0.025] and [Sb+Zn +As≦0.010] are met.
摘要:
A Ni-base heat resistant alloy, which comprises by mass percent, C: 0.1% or less, Si: 1% or less, Mn: 1% or less, Cr: not less than 15% to less than 28%, Fe: 15% or less, W: more than 5% to not more than 20%, Al: more than 0.5% to not more than 2%, Ti: more than 0.5% to not more than 2%, Nd: 0.001 to 0.1% and B: 0.0005 to 0.01%, with the balance being Ni and impurities, in which the contents of P, S, Sn, Pb, Sb, Zn and As among the impurities are P: 0.03% or less, S: 0.01% or less, Sn: 0.020% or less, Pb: 0.010% or less, Sb: 0.005% or less, Zn: 0.005% or less and As: 0.005% or less, and further satisfies the formulas of [0.015≦Nd+13.4×B≦0.13], [Sn+Pb≦0.025] and [Sb+Zn+As≦0.010] is an alloy in which much higher strength than the conventional Ni-base heat resistant alloy can be achieved, the ductility and toughness after a long period of use at a high temperature are remarkably improved, and moreover the zero ductility temperature and the hot workability are also further improved. This alloy can be suitably used as a pipe material, a thick plate material for a heat resistant pressure member, a bar material, a forging, and the like for a boiler for power generation, a plant for chemical industry, and the like. This alloy may contain a specific amount of one or more elements selected from Mo, Co, Nb, V, Zr, Hf, Mg, Ca, La, Ce, Ta and Re.
摘要:
After an inner wall tube, made of steel or alloy containing not less than 2% of Cr, whose outer surface thereof is machined and/or ground to a thickness of 0.1 mm or more including the scale layer, is inserted into an outer wall tube, made of ferritic steel containing not less than 2% of Cr, in which an oxide scale layer containing Cr and having a thickness of 10 to 30 μm is formed in the inner surface thereof , cold working at an outside diameter reduction rate of 5 to 30% is performed. Similarly cold worked after an inner wall tube having an oxide scale layer on the outer surface thereof, is inserted into an outer wall tube whose inner surface is machined and ground. A double-walled tube made has a uniform gap and an excellent thermal conductivity, and is suitable as materials for SG tubes of future FBR.
摘要:
A Ni-based heat resistant alloy as pipe, plate, rod, forgings and the like consists of C≦0.15%, Si≦2%, Mn≦3%, P≦0.03%, S≦0.01%, Cr: 15% or more and less than 28%, Mo: 3 to 15%, Co: more than 5% and not more than 25%, Al: 0.2 to 2%, Ti: 0.2% to 3%, Nd: fn to 0.08%, and O≦0.4Nd, further containing, as necessary, at least one kind of Nb, W, B, Zr, Hf, Mg, Ca, Y, La, Ce, Ta, Re and Fe of specific amounts, the balance being Ni and impurities, wherein, fn=1.7×10−5d+0.05{(Al/26.98)+(Ti/47.88)+(Nb/92.91)}. In the formula, d denotes an average grain size (μm), and each element symbol denotes the content (mass %) of that element. If the alloy contains W, Mo+(W/2)≦15% holds. The alloy has improved ductility after long-term use at high temperatures, and cracking due to welding can be avoided.
摘要:
To provide an austenitic stainless steel which has an excellent high-temperature corrosion thermal fatigue cracking resistance.An austenitic stainless steel containing, by mass %, Cr: 15.0 to 23.0%, and Ni: 6.0 to 20.0%, wherein a near-surface portion is covered with a worked layer with high energy density having an average thickness of 5 to 30 μm.
摘要:
[Problem to be Solved]A Ni-based alloy product consisting of, by mass percent, C: 0.03 to 0.10%, Si: 0.05 to 1.0%, Mn: 0.1 to 1.5%, Sol.Al: 0.0005 to 0.04%, Fe: 20 to 30%, Cr: not less than 21.0% and less than 25.0%, W: exceeding 6.0% and not more than 9.0%, Ti: 0.05 to 0.2%, Nb: 0.05 to 0.35%, and B: 0.0005 to 0.006%, the balance being Ni and impurities, the impurities being P: 0.03% or less, S: 0.01% or less, N: less than 0.010%, Mo: less than 0.5%, and Co: 0.8% or less, wherein a value of effective B (Beff) defined by the formula, Beff (%)=B−(11/14)×N+(11/48)×Ti, is 0.0050 to 0.0300%, and the rupture elongation in a tensile test at 700° C. and at a strain rate of 10−6/sec is 20% or more. This alloy may contain one or more kinds of Cu, Ta, Zr, Mg, Ca, REM, and Pd.
摘要:
The present invention provides an austenitic stainless steel tube with a uniform fine grained structure of regular grains, which is not changed to a coarse structure and the steam oxidation resistance is maintained even if the tube is subjected to a high temperature reheating during welding and high temperature bending working. The austenitic stainless steel tube consists of, by mass %, C: 0.03–0.12%, Si: 0.1–0.9%, Mn: 0.1–2%, Cr: 15–22%, Ni: 8–15%, Ti: 0.002–0.05%, Nb: 0.3–1.5%, sol. Al: 0.0005–0.03%, N: 0.005–0.2% and O (oxygen): 0.001–0.008%, and the balance Fe and impurities, the austenitic stainless steel tube having austenitic grain size number of 7 or more and a mixed grain ratio of preferably 10% or less.
摘要:
A high-strength high-Cr ferritic, heat-resistant steel exhibiting improved high-temperature, long-term creep strength and a process for producing the same are disclosed. The steel consists essentially of, by weight %:C: not more than 0.2%,Si: not more than 1.0%,Mn: 0.1-1.5%,P: not more than 0.03%,S: not more than 0.03%,Ni: not more than 1.0%,Cr: 5.0-15%,Mo: 0.02-3.0%,W: not more than 4.0%,sol. Al: 0.005-0.04%,N: not more than 0.07%,at least one of V: 0.01-0.4% and Nb: 0.01-0.3%,B: 0-0.02%,at least one of Ca, Ti, Zr, Y, La, and Ce: 0-0.2%, andthe balance Fe and incidental impurities, the A.sub.cl point defined by Formula (1) below being 820.degree. or higher.A.sub.cl (.degree.C.)=765-500 C-450N+30Si-25 Mn+25 Mo+15W+11Cr+50V+30Nb-30Ni+30 sol. Al (weight %).
摘要:
An austenitic heat resistant alloy includes, by mass percent, C: 0.15% or less, Si: 2% or less, Mn: 3% or less, Ni: 40 to 60%, Co: 10.14 to 25%, Cr: 15% or more and less than 28%, either one or both of Mo: 12% or less and W: less than 0.05%, the total content thereof being 0.1 to 12%, Nd: 0.001 to 0.1%, B: 0.0005 to 0.006%, N: 0.03% or less, O: 0.03% or less, at least one selected from Al: 1.36% or less, Ti: 3% or less, and Nb: 3% or less, and the balance being Fe and impurities. The contents of P and S in the impurities are P: 0.03% or less and S: 0.01% or less. The alloy satisfies 1≦4×Al+2×Ti+Nb≦12 and P+0.2×Cr×B≦0.035, where an element in the Formulas represents the content by mass percent.