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    Functionalized elastomer nanocomposite
    5.
    发明申请
    Functionalized elastomer nanocomposite 审中-公开
    官能化弹性体纳米复合材料

    公开(公告)号：US20050277723A1

    公开(公告)日：2005-12-15

    申请号：US10518127

    申请日：2003-05-30

    申请人： Caiguo Gong ,  Anthony Dias ,  Andy Tsou ,  Beverly Poole ,  Kriss Karp

    发明人： Caiguo Gong ,  Anthony Dias ,  Andy Tsou ,  Beverly Poole ,  Kriss Karp

    IPC分类号： B60C5/02 ,  B60C5/14 ,  C01B33/44 ,  C08K3/04 ,  C08K3/34 ,  C08K3/36 ,  C08L21/00

    CPC分类号： C08K3/346 ,  C08L51/00 ,  C08L23/22

    摘要： An embodiment of the present invention is a nanocomposite comprising a clay and an elastomer comprising at least C2 to C10 olefin derived units; wherein the elastomer also comprises functionalized monomer units pendant to the elastomer. Desirable embodiments of the elastomer include poly(isobutylene-co-p-alkylstyrene) elastomers and poly(isobutylene-co-isoprene) elastomers, which are functionalized via Friedel-Crafts reaction with a Lewis acid and a functionalizing agent such as acid anhydrides and/or acylhalides. The clay is exfoliated in one embodiment by the addition of exfoliating agents such as alkyl amines and silanes to the clay. The composition can include secondary rubbers such as general purpose rubbers, and curatives, fillers, and the like. The nanocomposites of the invention have improved air barrier properties such as are useful for tire innerliners and innertubes.

    摘要翻译： 本发明的一个实施方案是包含粘土和弹性体的纳米复合材料，所述弹性体包含至少C 2至C 10 O 12烯烃衍生单元; 其中弹性体还包括垂直于弹性体的官能化单体单元。 弹性体的优选实施方案包括聚（异丁烯 - 共 - 对烷基苯乙烯）弹性体和聚（异丁烯 - 共异戊二烯）弹性体，其通过与路易斯酸和官能化试剂如酸酐和/ 或酰卤。 粘土在一个实施方案中通过向粘土中加入去角质剂如烷基胺和硅烷来剥离。 组合物可以包括二次橡胶，例如通用橡胶，固化剂，填料等。 本发明的纳米复合材料具有改善的空气阻隔性能，例如可用于轮胎内衬和内管。

    Functionalized elastomer nanocomposite
    8.
    发明申请
    Functionalized elastomer nanocomposite 有权
    官能化弹性体纳米复合材料

    公开(公告)号：US20060100339A1

    公开(公告)日：2006-05-11

    申请号：US10518193

    申请日：2003-05-30

    申请人： Caiguo Gong ,  Anthony Dias ,  Andy Tsou ,  Beverly Poole ,  Kriss Karp

    发明人： Caiguo Gong ,  Anthony Dias ,  Andy Tsou ,  Beverly Poole ,  Kriss Karp

    IPC分类号： C08K3/34

    CPC分类号： B82Y30/00 ,  C08F8/00 ,  C08K3/346 ,  C08K9/04 ,  C08K2201/011 ,  C08F10/00 ,  C08L15/00 ,  C08L19/006 ,  C08L19/00

    摘要： An embodiment of the present invention is a nanocomposite comprising a clay and an elastomer comprising at least C2 to C10 olefin derived units; wherein the elastomer also comprises functionalized monomer units pendant to the elastomer. Desirable embodiments of the elastomer include poly(isobutylene-co-p-alkylstyrene) elastomers and poly(isobutylene-co-isoprene) elastomers, which are functionalized by reacting free radical generating agents and unsaturated carboxylic acids, unsaturated esters, unsaturated imides, and the like, with the elastomer. The clay is exfoliated in one embodiment by the addition of exfoliating agents such as alkyl amines and silanes to the clay. The composition can include secondary rubbers such as general purpose rubbers, and curatives, fillers, and the like. The nanocomposites of the invention have improved air barrier properties such as are useful for tire innerliners and innertubes.

    摘要翻译： 本发明的一个实施方案是包含粘土和弹性体的纳米复合材料，所述弹性体包含至少C 2至C 10 O 12烯烃衍生单元; 其中弹性体还包括垂直于弹性体的官能化单体单元。 弹性体的优选实施方案包括聚（异丁烯 - 共 - 对烷基苯乙烯）弹性体和聚（异丁烯 - 共异戊二烯）弹性体，其通过使自由基产生剂和不饱和羧酸，不饱和酯，不饱和酰亚胺和 像弹性体一样。 粘土在一个实施方案中通过向粘土中加入去角质剂如烷基胺和硅烷来剥离。 组合物可以包括二次橡胶，例如通用橡胶，固化剂，填料等。 本发明的纳米复合材料具有改善的空气阻隔性能，例如可用于轮胎内衬和内管。

    Nanocomposite comprising stabilization functionalized thermoplastic polyolefins
    9.
    发明申请
    Nanocomposite comprising stabilization functionalized thermoplastic polyolefins 有权
    包含稳定官能化的热塑性聚烯烃的纳米复合材料

    公开(公告)号：US20050203235A1

    公开(公告)日：2005-09-15

    申请号：US10800455

    申请日：2004-03-15

    申请人： Caiguo Gong ,  Alan Oshinski ,  Beverly Poole ,  Jerry Ball ,  Thomas Sykes

    发明人： Caiguo Gong ,  Alan Oshinski ,  Beverly Poole ,  Jerry Ball ,  Thomas Sykes

    IPC分类号： C08F8/00 ,  C08K3/34 ,  C08L21/00

    CPC分类号： B82Y30/00 ,  C08F8/32 ,  C08K2201/011 ,  C08L21/00 ,  C08F255/02 ,  C08F8/46 ,  C08F110/06

    摘要： This invention relates to nanocomposites comprising organo-clay and at least one stabilization functionalized thermoplastic polyolefin. Preferably the stabilization functionalized thermoplastic polyolefin is represented by the formula: T-(R1G)n Wherein T represents the thermoplastic polyolefin Each R1 is a bridging group, preferably independently selected from the group consisting of C1 to C20 aliphatic; C1 to C20 aromatic; substituted C1 to C20 aliphatic; substituted C1 to C20 aromatic; C1 to C20 aliphatic ester; C1 to C20 aliphatic ether; C1 to C20 aliphatic amide; C1 to C20 aliphatic imide; n is the number of stabilization functional/bridging groups bound to T and may be from 1-300; and G is selected from one or more of phenols, ketones, hindered amines, substituted phenols, substituted ketones, substituted hindered amines, or combinations thereof.

    摘要翻译： 本发明涉及包含有机粘土和至少一种稳定官能化的热塑性聚烯烃的纳米复合材料。 优选地，稳定化官能化的热塑性聚烯烃由下式表示：<？in-line-formula description =“In-line Formulas”end =“lead”？> T-（R＆lt; 1＆gt; G） > n <？in-line-formula description =“In-line Formulas”end =“tail”？>其中T表示热塑性聚烯烃。每个R 1是桥连基，优选 独立地选自C 1至C 20脂族基团; C 1至C 20芳族; 取代的C 1至C 20脂族基; 取代的C 1至C 20芳族; C 1至C 20脂族酯; C 1至C 20脂族醚; C 1至C 20脂族酰胺; C 1至C 20脂族酰亚胺; n是与T结合的稳定性功能性/桥连基团的数目，可以是1-300; 并且G选自酚，酮，受阻胺，取代酚，取代的酮，取代的受阻胺或其组合中的一种或多种。