公开(公告)号：US4713338A

公开(公告)日：1987-12-15

申请号：US893922

申请日：1986-08-06

申请人： Carlos J. R. Gonzalez Oliver ,  Olivier De Pous ,  Michel Schneider

发明人： Carlos J. R. Gonzalez Oliver ,  Olivier De Pous ,  Michel Schneider

IPC分类号： B01J20/281 ,  B01D39/06 ,  B01J20/06 ,  B01J20/10 ,  B01J20/28 ,  B01J20/283 ,  C03B8/02 ,  C03B19/10 ,  C03B19/12 ,  G01N30/88 ,  C12N11/14 ,  C03C11/00

CPC分类号： G01N30/482 ,  B01J20/06 ,  B01J2220/54 ,  Y10S435/814 ,  Y10S435/815

摘要： Porous glass beads for filtation applications having a homogeneous metaloxane structure and comprising oxides of Si, Zr and optionally Ti and Al. A preferred method for making these beads comprises the steps of (a) providing a mother solution of Si and Zr alkoxides in a water soluble solvent, for instance a lower aliphatic alcohol, (b) providing a liquid dispersant phase in which solution (a) is dispersible and stirring this liquid phase sufficiently to cause (a) to be formed into droplets of substantially uniform size when added to (b), (c) adding (a) to (b) at a rate sufficient to provide said droplets and effecting the hydrolysis of the alkoxides contained therein with consecutive gelation of said droplets into corresponding hardened beads of condensed mixed Si and Zr hydroxides, and (d) separating said beads from the liquid phase and drying to achieve the desired porous mixed oxide structure for the beads.

摘要翻译： 用于过滤应用的多孔玻璃珠具有均匀的金属氧化物结构并且包含Si，Zr和任选的Ti和Al的氧化物。 制备这些珠粒的优选方法包括以下步骤：（a）在水溶性溶剂例如低级脂族醇中提供Si和Zr醇盐的母溶液，（b）提供液体分散相，其中溶液（a） 是可分散的并且充分搅拌该液相以使（a）在加入到（b）中时形成基本上均匀大小的液滴，（c）以足以提供所述液滴的速度加入（a）至（b） 其中所含的醇盐的水解使所述液滴连续凝胶化成冷凝的混合Si和Zr氢氧化物的相应的硬化珠粒，和（d）将所述珠粒与液相分离并干燥以达到所需的多孔混合氧化物结构。

公开(公告)号：US4495297A

公开(公告)日：1985-01-22

申请号：US507829

申请日：1983-06-24

申请人： Ramon Puyane ,  Carlos J. R. Gonzalez-Oliver ,  Alan L. Harmer

发明人： Ramon Puyane ,  Carlos J. R. Gonzalez-Oliver ,  Alan L. Harmer

IPC分类号： C03B19/12 ,  C03B37/016 ,  C08G77/00 ,  C08G77/22 ,  C08G77/398 ,  C08G77/58 ,  C03C3/04

CPC分类号： C08G77/398 ,  C03B19/12 ,  C03B37/016 ,  C08G77/58 ,  Y10S65/901

摘要： A partly hydrolyzed gelled polysiloxane mass is contacted with a solution of dopant metal compounds which diffuse therein under thermally controlled condition; alternatively, a partly hydrolyzed gelled polysiloxane mass containing distributed therein dopant metal compounds is contacted with a solvent into which said dopant metal compounds will partly diffuse under thermally controlled conditions.

摘要翻译： 将部分水解的胶凝聚硅氧烷物质与在热控制条件下扩散其中的掺杂剂金属化合物的溶液接触; 或者，包含分布在掺杂剂金属化合物中的部分水解的胶凝聚硅氧烷质量与所述掺杂剂金属化合物在热控制条件下将部分扩散的溶剂接触。