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公开(公告)号:US20110290672A1
公开(公告)日:2011-12-01
申请号:US13048134
申请日:2011-03-15
CPC分类号: G01N27/4045 , B82Y15/00 , B82Y30/00 , G01N27/308
摘要: An electrochemical gas sensor for detecting ozone or nitrogen dioxide in a gas sample has a measuring electrode (3) formed of carbon nanotubes (CNT) or a counterelectrode (8) in an electrolyte solution (9), which contains lithium chloride or lithium bromide in an aqueous solution.
摘要翻译: 用于检测气体样品中的臭氧或二氧化氮的电化学气体传感器具有在电解质溶液(9)中由碳纳米管(CNT)或反电极(8)形成的测量电极(3),其包含氯化锂或溴化锂 水溶液。
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公开(公告)号:US20060124458A1
公开(公告)日:2006-06-15
申请号:US11232562
申请日:2005-09-22
申请人: Andreas Nauber , Dieter Kruger , Michael Sick , Christoph Bernstein , Michael Dietrich , Hans-Jurgen Busack , Rigobert Chrzan , Kathrin Hermann
发明人: Andreas Nauber , Dieter Kruger , Michael Sick , Christoph Bernstein , Michael Dietrich , Hans-Jurgen Busack , Rigobert Chrzan , Kathrin Hermann
IPC分类号: G01N27/26
CPC分类号: G01N27/404 , Y02E60/366
摘要: An electrochemical gas sensor with a stacked arrangement of electrodes and nonwoven layers arranged in parallel, comprising at least one measuring electrode (3) and at least one counterelectrode (5). A porous membrane (8) that is permeable to air is in contact with the stacked arrangement of electrodes and nonwoven layers arranged in parallel at least on one side, at least one layer of a hydrophilic nonwoven (7) is located between the electrodes. The porous membrane (8) that is permeable to air and the hydrophilic nonwoven (7) extend into a separate equalization volume (9), which is filled with electrolyte at least partially and is located at least partially in one plane with the electrodes. The separate equalization volume (9) surrounds the electrode arrangement at least partially in this plane, and the porous membrane (8) that is permeable to air is exposed to ambient pressure at least in partial areas. Such sensors are characterized by a flat shape, high insensitivity to shocks, independence from the position, and high tolerance to variations in environmental humidity.
摘要翻译: 一种电化学气体传感器,其具有并联布置的电极和非织造层的堆叠布置,包括至少一个测量电极(3)和至少一个反电极(5)。 可渗透空气的多孔膜(8)与至少在一侧平行布置的电极和非织造层的堆叠布置接触,至少一层亲水性无纺布(7)位于电极之间。 可渗透空气的多孔膜(8)和亲水性无纺布(7)延伸到独立的均衡体积(9)中,其中至少部分地填充有电解质并且至少部分地与电极位于一个平面中。 分离的均衡体积(9)至少部分地围绕电极装置在该平面中,并且可渗透空气的多孔膜(8)至少在部分区域暴露于环境压力。 这种传感器的特征在于平坦的形状,对冲击的高度不敏感性,与位置的独立性以及对环境湿度变化的高耐受性。
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公开(公告)号:US20050229675A1
公开(公告)日:2005-10-20
申请号:US11058654
申请日:2005-02-15
申请人: Stephan Haupt , Michael Sick , Rigobert Chrzan , Andreas Nauber , Dieter Kruger , Christoph Bernstein , Wilfried Diekmann
发明人: Stephan Haupt , Michael Sick , Rigobert Chrzan , Andreas Nauber , Dieter Kruger , Christoph Bernstein , Wilfried Diekmann
IPC分类号: G01N1/28 , G01N27/00 , G01N27/16 , G01N27/26 , G01N27/413 , G01N27/416 , G01N33/00 , G01N37/00
CPC分类号: G01N33/0016
摘要: A gas sensor (1) with a detector element (2), which is specific of the gas to be measured and sends a measured signal that depends on the measured gas concentration, has increased measuring sensitivity for measurements in the concentration range from less than 1 ppb to a few ppb. The detector element (2) is exposed in a gas admission adapter (4) to a gas to be measured via a diaphragm (3) arranged in front of it, wherein the gas admission adapter (4) has at least a first opening (20) for the entry of the gas to be measured as well as at least a second opening (30), which is connected with a pressure modulator, which generates periodic gas pressure vibrations in the gas admission adapter (4) and is designed, for example, as a pump (5).
摘要翻译: 具有检测器元件(2)的气体传感器(1),其被测量的气体的特异性并且发送取决于测量的气体浓度的测量信号具有增加的测量灵敏度,其浓度范围从小于1 ppb到几ppb 检测器元件(2)通过布置在其前面的隔膜(3)暴露在气体接纳适配器(4)中的待测气体中,其中气体接纳适配器(4)至少具有第一开口(20) ),以及至少第二开口(30),其与压力调节器连接,其在气体进入适配器(4)中产生周期性气体压力振动,并被设计为例如 ,作为泵(5)。
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公开(公告)号:US07608177B2
公开(公告)日:2009-10-27
申请号:US11232562
申请日:2005-09-22
申请人: Andreas Nauber , Dieter Krüger , Michael Sick , Christoph Bernstein , Michael Dietrich , Hans-Jürgen Busack , Rigobert Chrzan , Kathrin Hermann
发明人: Andreas Nauber , Dieter Krüger , Michael Sick , Christoph Bernstein , Michael Dietrich , Hans-Jürgen Busack , Rigobert Chrzan , Kathrin Hermann
CPC分类号: G01N27/404 , Y02E60/366
摘要: An electrochemical gas sensor with a stacked arrangement of electrodes and nonwoven layers arranged in parallel, comprising at least one measuring electrode (3) and at least one counterelectrode (5). A porous membrane (8) that is permeable to air is in contact with the stacked arrangement of electrodes and nonwoven layers arranged in parallel at least on one side, at least one layer of a hydrophilic nonwoven (7) is located between the electrodes. The porous membrane (8) that is permeable to air and the hydrophilic nonwoven (7) extend into a separate equalization volume (9), which is filled with electrolyte at least partially and is located at least partially in one plane with the electrodes. The separate equalization volume (9) surrounds the electrode arrangement at least partially in this plane, and the porous membrane (8) that is permeable to air is exposed to ambient pressure at least in partial areas. Such sensors are characterized by a flat shape, high insensitivity to shocks, independence from the position, and high tolerance to variations in environmental humidity.
摘要翻译: 一种电化学气体传感器,其具有并联布置的电极和非织造层的堆叠布置,包括至少一个测量电极(3)和至少一个反电极(5)。 可渗透空气的多孔膜(8)与至少在一侧平行布置的电极和非织造层的堆叠布置接触,至少一层亲水性无纺布(7)位于电极之间。 可渗透空气的多孔膜(8)和亲水性无纺布(7)延伸到独立的均衡体积(9)中,其中至少部分地填充有电解质并且至少部分地与电极位于一个平面中。 分离的均衡体积(9)至少部分地围绕电极装置在该平面中,并且可渗透空气的多孔膜(8)至少在部分区域暴露于环境压力。 这种传感器的特征在于平坦的形状,对冲击的高度不敏感性,与位置的独立性以及对环境湿度变化的高耐受性。
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公开(公告)号:US06579433B2
公开(公告)日:2003-06-17
申请号:US09971759
申请日:2001-10-09
IPC分类号: G01N2726
CPC分类号: G01N27/4045
摘要: An electrochemical measuring cell for detecting hydrocyanic acid is improved in such a manner that a stable measurement signal is provided after a short time. The measuring cell includes a measuring electrode (1) of sintered gold and a counter electrode (2). A measuring cell housing (4) accommodates the measuring electrode (1) and the counter electrode (2). An electrolyte is in the measuring cell housing (4) and includes sulphuric acid with an additive of silver sulphate. A diffusion membrane (5) is disposed between the measuring electrode (1) and the substance to be detected.
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公开(公告)号:US07257986B2
公开(公告)日:2007-08-21
申请号:US11058654
申请日:2005-02-15
申请人: Stephan Haupt , Michael Sick , Rigobert Chrzan , Andreas Nauber , Dieter Krüger , Christoph Bernstein , Wilfried Diekmann
发明人: Stephan Haupt , Michael Sick , Rigobert Chrzan , Andreas Nauber , Dieter Krüger , Christoph Bernstein , Wilfried Diekmann
IPC分类号: G01N27/00
CPC分类号: G01N33/0016
摘要: A gas sensor (1) with a detector element (2), which is specific to a gas to be measured and sends a measured signal that depends on the measured gas concentration, has increased measuring sensitivity for measurements in the concentration range from less than 1 ppb to a few ppb. The detector element (2) is exposed in a gas admission adapter (4) to a gas to be measured via a diaphragm (3) arranged in front of the detector element (2), wherein the gas admission adapter (4) has at least a first opening (20) for the entry of the gas to be measured as well as at least a second opening (30), which is connected with a pressure modulator, which generates periodic gas pressure vibrations in the gas admission adapter (4) and is designed, for example, as a pump (5).
摘要翻译: 具有检测器元件(2)的气体传感器(1),其特异于被测量的气体并发送取决于测量的气体浓度的测量信号,具有增加的测量灵敏度,其浓度范围从小于1 ppb到几ppb 检测器元件(2)通过布置在检测器元件(2)前面的隔膜(3)暴露在气体接纳适配器(4)中至要测量的气体,其中气体接纳适配器(4)至少具有 用于输入待测气体的第一开口(20)以及与压力调节器连接的至少第二开口(30),其在气体进入适配器(4)中产生周期性的气体压力振动,以及 例如被设计为泵(5)。
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公开(公告)号:US5932079A
公开(公告)日:1999-08-03
申请号:US987206
申请日:1997-12-09
CPC分类号: G01N27/4045
摘要: An electrochemical measuring cell for the simultaneous detection of different gas components in a gas sample, with a plurality of measuring electrodes (4, 5, 6) behind a diffusion barrier (7), with a common reference electrode (8) and counterelectrode (9) in an acid electrolyte, and with a potentiostatic evaluating circuit. Improvements in terms of service life for a sensor for the simultaneous detection of oxygen and carbon monoxide is provided with a reference electrode formed of a sintered mixture of metal and its metal oxide, preferably from the platinum group, the iridium group or gold and the potential of the CO-measuring electrode (5) relative to the reference electrode (8) is set at about 0 to 300 mV, and that of the O.sub.2 -measuring electrode (4) is set at a value between -300 and -800 mV.
摘要翻译: 一种用于同时检测气体样品中不同气体组分的电化学测量单元,其具有在扩散阻挡层(7)后面的多个测量电极(4,5,6),具有公共参考电极(8)和反电极(9 )在酸性电解质中,并具有恒电位评估电路。 用于同时检测氧气和一氧化碳的传感器的使用寿命方面的改进提供了由金属和其金属氧化物的烧结混合物形成的参比电极,优选由铂族,铱基或金形成的电极和电位 相对于参考电极(8)的CO测量电极(5)设定为约0〜300mV,将O 2测量电极(4)设定为-300〜-800mV。
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公开(公告)号:US5723036A
公开(公告)日:1998-03-03
申请号:US713474
申请日:1996-09-13
IPC分类号: G01N27/403 , G01N27/49 , G01N27/404
CPC分类号: G01N27/4045
摘要: The invention is directed to an electrochemical measuring cell 1 for detecting different gas components. The electrochemical measuring cell includes several measuring electrodes (8, 12, 13), a common counter electrode 21 and a common reference electrode 20 in an aqueous electrolyte 3. The measuring electrodes each include a diffusion membrane (7, 11) and individual diaphragms (9, 14) limiting the inflow of gas to the individual measuring electrodes (8, 12). The diffusion membranes (7, 11) cover the measuring electrodes (8, 12, 13). The measuring cell 1 is so improved that the selectivity of the detection of different gas components is improved. An electrolyte barrier 19 is provided at least between one of the measuring electrodes 8 and the remaining measuring electrodes (12, 13). The electrolyte barrier 19 prevents lateral diffusion within the diffusion membrane (7, 11).
摘要翻译: 本发明涉及一种用于检测不同气体组分的电化学测量单元1。 电化学测量单元包括在含水电解质3中的几个测量电极(8,12,13),公共对电极21和公共参比电极20.测量电极各自包括扩散膜(7,11)和各个隔膜 限制气体到各个测量电极(8,12)的流入。 扩散膜(7,11)覆盖测量电极(8,12,13)。 测量单元1得到如此改进,从而提高了不同气体组分的检测选择性。 至少在一个测量电极8和剩余的测量电极(12,13)之间提供电解质屏障19。 电解质屏障19防止扩散膜(7,11)内的横向扩散。
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