摘要:
A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %, and a GPC weight average molecular weight in the range of about 5000 to about 40,000, or a GPC weight average molecular weight of at least about 600,000. When the fiber-forming thermoplastic polymer is a polyester, the polybrominated anionic styrenic polymer is present in a flame resistant or flame retardant amount. When the fiber-forming thermoplastic polymer is a polyamide, the polybrominated anionic styrenic polymer is at least about 2 wt % of the fiber or filament. When the fiber-forming thermoplastic polymer is a polyolefin, at least one synergist is present and the polybrominated anionic styrenic polymer is no more than about 15 wt % of the fiber or filament.
摘要:
A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %, and a GPC weight average molecular weight in the range of about 5000 to about 40,000, or a GPC weight average molecular weight of at least about 600,000. When the fiber-forming thermoplastic polymer is a polyester, the polybrominated anionic styrenic polymer is present in a flame resistant or flame retardant amount. When the fiber-forming thermoplastic polymer is a polyamide, the polybrominated anionic styrenic polymer is at least about 2 wt % of the fiber or filament. When the fiber-forming thermoplastic polymer is a polyolefin, at least one synergist is present and the polybrominated anionic styrenic polymer is no more than about 15 wt % of the fiber or filament.
摘要:
N,N′-piperazinebis(neopentylglycol)phosphoramidate is used in combination with at least one co-additive which is (i) melamine, (ii) one or more melamine compounds or derivatives, or (iii) both of (i) and (ii) to provide effective flame retardancy in thermoplastic polymers. With polymers that tend to release trace amounts of acid under thermal processing conditions, a hydrotalcite is preferably included in the composition. In acid-sensitive polymers such as polyesters, the N,N′-piperazinebis(neopentylglycol)phosphoramidate should be free or essentially free of acid species as determinable by use of nmr, mass spec, and/or HPLC.
摘要:
Novel polymer compositions of specified formula are converted into pellets of this invention by process technology provided by this invention. By forming a binder free melt of a polymer of such polymer compositions, and converting the melt into pellets as described here-in, pellets can be formed produce during production, handling, and use, no more than acceptably small amounts of “fines” or air-entrainable dusts.
摘要:
The present invention relates to low triphenyl phosphate, high phosphorous content aryl phosphates with high ortho alkylation that are suitable for use as flame retardant compositions, processes for their preparation, and their use as flame retardants.
摘要:
New branched or star-branched styrene polymeric, telomeric, and monomeric product distributions, their preparation, their use as raw materials for bromination to produce flame retardants, the flame retardants themselves, and their use as flame retardants in various polymeric substrates are described.
摘要:
The present invention relates to low triphenyl phosphate, high phosphorous content aryl phosphates with high ortho alkylation that are suitable for use as flame retardant compositions, processes for their preparation, and their use as flame retardants.
摘要:
Described are a particular group of novel aromatic hydrocarbon telomers that, on bromination, result in the formation of novel flame retardants having a uniquely beneficial combination of properties. The resultant flame retardants and uses thereof are also described. The disclosure includes descriptions of methods for preparing both the aromatic hydrocarbon telomers and the brominated flame retardant polymers.
摘要:
New branched or star-branched styrene polymeric, telomeric, and monomeric product distributions, their preparation, their use as raw materials for bromination to produce flame retardants, the flame retardants themselves, and their use as flame retardants in various polymeric substrates are described.
摘要:
Brominated styrenic polymer is recovered from solution in a vaporizable solvent by converting the solution in a devolatilization extruder into a brominated styrenic polymer melt or flow and a separate vapor phase comprised predominately of vaporizable solvent, recovering the melt or flow from the devolatilization extruder, and allowing or causing the melt or flow to solidify. The solidified brominated styrenic polymer can be subdivided into a powder or pelletized form. Pellets so made have improved hardness and/or crush strength properties along with reduced formation of fines. Brominated anionic styrenic polymer is preferably used in the process.