Flame retarded fibers and filaments and process of production therefor
    1.
    发明授权
    Flame retarded fibers and filaments and process of production therefor 失效
    阻燃纤维和长丝及其生产工艺

    公开(公告)号:US07666944B2

    公开(公告)日:2010-02-23

    申请号:US11928900

    申请日:2007-10-30

    IPC分类号: C08L67/02

    摘要: A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %, and a GPC weight average molecular weight in the range of about 5000 to about 40,000, or a GPC weight average molecular weight of at least about 600,000. When the fiber-forming thermoplastic polymer is a polyester, the polybrominated anionic styrenic polymer is present in a flame resistant or flame retardant amount. When the fiber-forming thermoplastic polymer is a polyamide, the polybrominated anionic styrenic polymer is at least about 2 wt % of the fiber or filament. When the fiber-forming thermoplastic polymer is a polyolefin, at least one synergist is present and the polybrominated anionic styrenic polymer is no more than about 15 wt % of the fiber or filament.

    摘要翻译: 提供由包含(a)至少一种成纤热塑性聚合物和(b)至少一种多溴化阴离子苯乙烯聚合物的成分形成的纤维或长丝。 多溴化阴离子苯乙烯聚合物的溴含量为至少约50重量%,GPC重均分子量在约5000至约40,000范围内,GPC重均分子量至少为约600,000。 当成纤热塑性聚合物是聚酯时,多溴化阴离子苯乙烯聚合物以阻燃或阻燃的量存在。 当成纤热塑性聚合物是聚酰胺时,多溴化阴离子苯乙烯聚合物是纤维或长丝的至少约2重量%。 当成纤热塑性聚合物是聚烯烃时,存在至少一种增效剂,多溴化阴离子苯乙烯聚合物不超过纤维或长丝的约15重量%。

    FLAME RETARDED FIBERS AND FILAMENTS AND PROCESS OF PRODUCTION THEREFOR
    2.
    发明申请
    FLAME RETARDED FIBERS AND FILAMENTS AND PROCESS OF PRODUCTION THEREFOR 失效
    阻燃纤维和纤维及其生产工艺

    公开(公告)号:US20080139752A1

    公开(公告)日:2008-06-12

    申请号:US11928900

    申请日:2007-10-30

    IPC分类号: C08G61/02

    摘要: A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %, and a GPC weight average molecular weight in the range of about 5000 to about 40,000, or a GPC weight average molecular weight of at least about 600,000. When the fiber-forming thermoplastic polymer is a polyester, the polybrominated anionic styrenic polymer is present in a flame resistant or flame retardant amount. When the fiber-forming thermoplastic polymer is a polyamide, the polybrominated anionic styrenic polymer is at least about 2 wt % of the fiber or filament. When the fiber-forming thermoplastic polymer is a polyolefin, at least one synergist is present and the polybrominated anionic styrenic polymer is no more than about 15 wt % of the fiber or filament.

    摘要翻译: 提供由包含(a)至少一种成纤热塑性聚合物和(b)至少一种多溴化阴离子苯乙烯聚合物的成分形成的纤维或长丝。 多溴化阴离子苯乙烯聚合物的溴含量为至少约50重量%,GPC重均分子量在约5000至约40,000范围内或GPC重均分子量至少为约600,000。 当成纤热塑性聚合物是聚酯时,多溴化阴离子苯乙烯聚合物以阻燃或阻燃的量存在。 当成纤热塑性聚合物是聚酰胺时,多溴化阴离子苯乙烯聚合物是纤维或长丝的至少约2重量%。 当成纤热塑性聚合物是聚烯烃时,存在至少一种增效剂,多溴化阴离子苯乙烯聚合物不超过纤维或长丝的约15重量%。

    Flame retardant polymer compositions
    3.
    发明授权
    Flame retardant polymer compositions 失效
    阻燃聚合物组合物

    公开(公告)号:US06617379B2

    公开(公告)日:2003-09-09

    申请号:US10005653

    申请日:2001-12-04

    IPC分类号: C08K534

    摘要: N,N′-piperazinebis(neopentylglycol)phosphoramidate is used in combination with at least one co-additive which is (i) melamine, (ii) one or more melamine compounds or derivatives, or (iii) both of (i) and (ii) to provide effective flame retardancy in thermoplastic polymers. With polymers that tend to release trace amounts of acid under thermal processing conditions, a hydrotalcite is preferably included in the composition. In acid-sensitive polymers such as polyesters, the N,N′-piperazinebis(neopentylglycol)phosphoramidate should be free or essentially free of acid species as determinable by use of nmr, mass spec, and/or HPLC.

    摘要翻译: N,N'-哌嗪双(新戊二醇)氨基磷酸酯与至少一种共添加剂组合使用,所述共添加剂为(i)三聚氰胺,(ii)一种或多种三聚氰胺化合物或衍生物,或(iii)(i)和 ii)在热塑性聚合物中提供有效的阻燃性。 对于在热加工条件下倾向于释放痕量酸的聚合物,组合物中优选包括水滑石。 在酸敏感聚合物如聚酯中,N,N'-哌嗪二(新戊二醇)氨基磷酸酯应该是游离的或基本上不含酸性物质,可以通过使用nmr,质谱和/或HPLC来测定。