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公开(公告)号:US08101786B2
公开(公告)日:2012-01-24
申请号:US12914595
申请日:2010-10-28
CPC分类号: C01B6/15 , C01B6/19 , C01B35/061
摘要: The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.
摘要翻译: 卤代硼化合物(B-X化合物,具有一个或多个硼 - 卤键的化合物)与硅烷的反应提供硼烷(B-H化合物,具有一个或多个B-H键的化合物)和卤代硅烷。 无机氢化物,例如表面结合的硅烷氢化物(Si-H)与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷在电化学上转化回表面结合的硅烷。 卤代硼化合物与锡烷(具有Sn-H键的锡化合物)反应形成硼烷和卤代烷(具有Sn-X键的锡化合物)。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物为BCl 3时,B-H化合物为B 2 H 6,并且其电还原电位或通过甲酸盐的热解提供还原电位。
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公开(公告)号:US20110105706A1
公开(公告)日:2011-05-05
申请号:US12914595
申请日:2010-10-28
IPC分类号: C08F130/04 , C07F5/02 , C07F7/22
CPC分类号: C01B6/15 , C01B6/19 , C01B35/061
摘要: The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.
摘要翻译: 卤代硼化合物(B-X化合物,具有一个或多个硼 - 卤键的化合物)与硅烷的反应提供硼烷(B-H化合物,具有一个或多个B-H键的化合物)和卤代硅烷。 无机氢化物,例如表面结合的硅烷氢化物(Si-H)与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷在电化学上转化回表面结合的硅烷。 卤代硼化合物与锡烷(具有Sn-H键的锡化合物)反应形成硼烷和卤代烷(具有Sn-X键的锡化合物)。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物为BCl 3时,B-H化合物为B 2 H 6,并且其还原电位通过电化学方法或通过甲酸盐的热解提供。
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公开(公告)号:US20110220583A1
公开(公告)日:2011-09-15
申请号:US12721139
申请日:2010-03-10
IPC分类号: C02F1/52
CPC分类号: C02F1/72 , C02F1/5236 , C02F1/66 , C02F1/722 , C02F1/78 , C02F2103/18
摘要: The invention provides a method of efficiently removing selenium from water. The method involves: adding an oxidant to the liquid, adjusting the liquid's pH to below 7.5, adding ferric salt in an amount such that less than a quarter of selenium in the liquid precipitates and adding a poly dithiocarbamate material to the liquid in an amount such that the amount of poly dithiocarbamate material (in ppm) is greater than the amount of ferric salt (in ppm). This method removes far more selenium than previous methods, and does it using a smaller amount of expensive chemicals. Moreover this method makes it far more likely to achieve cost effective compliance with the ever-increasing environmental standards for selenium in water.
摘要翻译: 本发明提供了一种有效地从水中除去硒的方法。 该方法包括:向液体中加入氧化剂,将液体的pH调节至7.5以下,加入三价盐,使得液体中少于四分之一的硒沉淀并加入聚二硫代氨基甲酸盐物质至一定量 聚二硫代氨基甲酸盐材料的量(ppm)大于铁盐的量(ppm)。 这种方法比以前的方法去除了更多的硒,并且使用较少量的昂贵的化学品。 此外,这种方法使得更有可能实现成本有效地符合不断增加的硒在水中的环境标准。
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公开(公告)号:US07837852B2
公开(公告)日:2010-11-23
申请号:US12533736
申请日:2009-07-31
IPC分类号: C01B6/00
CPC分类号: C01B6/15 , C01B6/19 , C01B35/061
摘要: The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.
摘要翻译: 卤代硼化合物(B-X化合物,具有一个或多个硼 - 卤键的化合物)与硅烷的反应提供硼烷(B-H化合物,具有一个或多个B-H键的化合物)和卤代硅烷。 无机氢化物,例如表面结合的硅烷氢化物(Si-H)与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷在电化学上转化回表面结合的硅烷。 卤代硼化合物与锡烷(具有Sn-H键的锡化合物)反应形成硼烷和卤代烷(具有Sn-X键的锡化合物)。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物为BCl 3时,B-H化合物为B 2 H 6,并且其还原电位通过电化学方法或通过甲酸盐的热解提供。
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公开(公告)号:US09032792B2
公开(公告)日:2015-05-19
申请号:US13306211
申请日:2012-01-19
摘要: A device and method for reducing and/or preventing fouling of a sensor is disclosed. The method comprises operating ultrasound technology that is submerged or partially submerged into a liquid medium that is responsible for the fouling. The device comprises the ultrasound technology itself. The ultrasound technology may be operated intermittently at high intensity to advantageously provide cavitation of the liquid medium, while avoiding the disadvantages typical of continuously operating ultrasound technology at high intensity. Additionally, the method may be carried out by taking advantage of the piezoelectric property of quartz.
摘要翻译: 公开了用于减少和/或防止传感器结垢的装置和方法。 该方法包括操作超声技术,其被浸没或部分浸没在负责污染的液体介质中。 该装置包括超声技术本身。 超声技术可以以高强度间歇地操作,以有利地提供液体介质的空化,同时避免了在高强度下连续操作超声技术的缺点。 此外,该方法可以通过利用石英的压电特性来实现。
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公开(公告)号:US08329140B2
公开(公告)日:2012-12-11
申请号:US12283462
申请日:2008-09-11
IPC分类号: C01B3/02
CPC分类号: C07D235/06 , C07D235/18
摘要: A method and system for storing and evolving hydrogen (H2) employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.
摘要翻译: 用于储存和演化氢气(H2)的方法和系统采用可被氢化以储存氢气并脱氢以放出氢气的化学化合物。 催化剂降低储存和放出氢气所需的能量。 该方法和系统可以为消耗氢气作为燃料的装置提供氢气。
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公开(公告)号:US08282835B2
公开(公告)日:2012-10-09
申请号:US12721139
申请日:2010-03-10
CPC分类号: C02F1/72 , C02F1/5236 , C02F1/66 , C02F1/722 , C02F1/78 , C02F2103/18
摘要: The invention provides a method of efficiently removing selenium from water. The method involves: adding an oxidant to the liquid, adjusting the liquid's pH to below 7.5, adding ferric salt in an amount such that less than a quarter of selenium in the liquid precipitates and adding a poly dithiocarbamate material to the liquid in an amount such that the amount of poly dithiocarbamate material (in ppm) is greater than the amount of ferric salt (in ppm). This method removes far more selenium than previous methods, and does it using a smaller amount of expensive chemicals. Moreover this method makes it far more likely to achieve cost effective compliance with the ever-increasing environmental standards for selenium in water.
摘要翻译: 本发明提供了一种有效地从水中除去硒的方法。 该方法包括:向液体中加入氧化剂,将液体的pH调节至7.5以下,加入三价盐,使得液体中少于四分之一的硒沉淀并加入聚二硫代氨基甲酸盐物质至一定量 聚二硫代氨基甲酸盐材料的量(ppm)大于铁盐的量(ppm)。 这种方法比以前的方法去除了更多的硒,并且使用较少量的昂贵的化学品。 此外,这种方法使得更有可能实现成本有效地符合不断增加的硒在水中的环境标准。
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公开(公告)号:US20090297423A1
公开(公告)日:2009-12-03
申请号:US12533736
申请日:2009-07-31
CPC分类号: C01B6/15 , C01B6/19 , C01B35/061
摘要: The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.
摘要翻译: 卤代硼化合物(B-X化合物,具有一个或多个硼 - 卤键的化合物)与硅烷的反应提供硼烷(B-H化合物,具有一个或多个B-H键的化合物)和卤代硅烷。 无机氢化物,例如表面结合的硅烷氢化物(Si-H)与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷在电化学上转化回表面结合的硅烷。 卤代硼化合物与锡烷(具有Sn-H键的锡化合物)反应形成硼烷和卤代烷(具有Sn-X键的锡化合物)。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物为BCl 3时,B-H化合物为B 2 H 6,并且其电还原电位或通过甲酸盐的热解提供还原电位。
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公开(公告)号:US20130186188A1
公开(公告)日:2013-07-25
申请号:US13306211
申请日:2012-01-19
IPC分类号: G01N29/02
摘要: A device and method for reducing and/or preventing fouling of a sensor is disclosed. The method comprises operating ultrasound technology that is submerged or partially submerged into a liquid medium that is responsible for the fouling. The device comprises the ultrasound technology itself. The ultrasound technology may be operated intermittently at high intensity to advantageously provide cavitation of the liquid medium, while avoiding the disadvantages typical of continuously operating ultrasound technology at high intensity. Additionally, the method may be carried out by taking advantage of the piezoelectric property of quartz.
摘要翻译: 公开了用于减少和/或防止传感器结垢的装置和方法。 该方法包括操作超声技术,其被浸没或部分浸没在负责污染的液体介质中。 该装置包括超声技术本身。 超声技术可以以高强度间歇地操作,以有利地提供液体介质的空化,同时避免了在高强度下连续操作超声技术的缺点。 此外,该方法可以通过利用石英的压电特性来实现。
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公开(公告)号:US20110129411A1
公开(公告)日:2011-06-02
申请号:US12283462
申请日:2008-09-11
IPC分类号: C01B3/02
CPC分类号: C07D235/06 , C07D235/18
摘要: A method and system for storing and evolving hydrogen (H2) employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.
摘要翻译: 用于储存和演化氢气(H2)的方法和系统采用可被氢化以储存氢气并脱氢以放出氢气的化学化合物。 催化剂降低储存和放出氢气所需的能量。 该方法和系统可以为消耗氢气作为燃料的装置提供氢气。
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