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    ENERGY EFFICIENT SYNTHESIS OF BORANES
    4.
    发明申请
    ENERGY EFFICIENT SYNTHESIS OF BORANES 有权
    能量有效地合成硼

    公开(公告)号：US20110105706A1

    公开(公告)日：2011-05-05

    申请号：US12914595

    申请日：2010-10-28

    申请人： David L. Thorn ,  William Tumas ,  Daniel E. Schwarz ,  Anthony K. Burrell

    发明人： David L. Thorn ,  William Tumas ,  Daniel E. Schwarz ,  Anthony K. Burrell

    IPC分类号： C08F130/04 ,  C07F5/02 ,  C07F7/22

    CPC分类号： C01B6/15 ,  C01B6/19 ,  C01B35/061

    摘要： The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.

    摘要翻译： 卤代硼化合物（B-X化合物，具有一个或多个硼 - 卤键的化合物）与硅烷的反应提供硼烷（B-H化合物，具有一个或多个B-H键的化合物）和卤代硅烷。 无机氢化物，例如表面结合的硅烷氢化物（Si-H）与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷在电化学上转化回表面结合的硅烷。 卤代硼化合物与锡烷（具有Sn-H键的锡化合物）反应形成硼烷和卤代烷（具有Sn-X键的锡化合物）。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物为BCl 3时，B-H化合物为B 2 H 6，并且其还原电位通过电化学方法或通过甲酸盐的热解提供。

    Energy efficient synthesis of boranes
    5.
    发明授权
    Energy efficient synthesis of boranes 失效
    能量高效合成硼烷

    公开(公告)号：US07837852B2

    公开(公告)日：2010-11-23

    申请号：US12533736

    申请日：2009-07-31

    申请人： David L. Thorn ,  William Tumas ,  Daniel E. Schwarz ,  Anthony K. Burrell

    发明人： David L. Thorn ,  William Tumas ,  Daniel E. Schwarz ,  Anthony K. Burrell

    IPC分类号： C01B6/00

    CPC分类号： C01B6/15 ,  C01B6/19 ,  C01B35/061

    摘要： The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.

    摘要翻译： 卤代硼化合物（B-X化合物，具有一个或多个硼 - 卤键的化合物）与硅烷的反应提供硼烷（B-H化合物，具有一个或多个B-H键的化合物）和卤代硅烷。 无机氢化物，例如表面结合的硅烷氢化物（Si-H）与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷在电化学上转化回表面结合的硅烷。 卤代硼化合物与锡烷（具有Sn-H键的锡化合物）反应形成硼烷和卤代烷（具有Sn-X键的锡化合物）。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物为BCl 3时，B-H化合物为B 2 H 6，并且其还原电位通过电化学方法或通过甲酸盐的热解提供。

    ENERGY EFFICIENT SYNTHESIS OF BORANES
    6.
    发明申请
    ENERGY EFFICIENT SYNTHESIS OF BORANES 失效
    能量有效地合成硼

    公开(公告)号：US20090297423A1

    公开(公告)日：2009-12-03

    申请号：US12533736

    申请日：2009-07-31

    申请人： David L. Thorn ,  William Tumas ,  Daniel E. Schwarz ,  Anthony K. Burrell

    发明人： David L. Thorn ,  William Tumas ,  Daniel E. Schwarz ,  Anthony K. Burrell

    IPC分类号： C01B6/10 ,  C08F8/42 ,  C08G77/00 ,  C08G79/02 ,  C08G79/08 ,  C08G73/00

    CPC分类号： C01B6/15 ,  C01B6/19 ,  C01B35/061

    摘要： The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.

    摘要翻译： 卤代硼化合物（B-X化合物，具有一个或多个硼 - 卤键的化合物）与硅烷的反应提供硼烷（B-H化合物，具有一个或多个B-H键的化合物）和卤代硅烷。 无机氢化物，例如表面结合的硅烷氢化物（Si-H）与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷在电化学上转化回表面结合的硅烷。 卤代硼化合物与锡烷（具有Sn-H键的锡化合物）反应形成硼烷和卤代烷（具有Sn-X键的锡化合物）。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物为BCl 3时，B-H化合物为B 2 H 6，并且其电还原电位或通过甲酸盐的热解提供还原电位。

    Bootstrap synthesis of boranes
    8.
    发明申请
    Bootstrap synthesis of boranes 审中-公开
    引导合成硼烷

    公开(公告)号：US20080175781A1

    公开(公告)日：2008-07-24

    申请号：US11901007

    申请日：2007-09-13

    申请人： David L. Thorn ,  William Tumas

    发明人： David L. Thorn ,  William Tumas

    IPC分类号： C01B35/14 ,  C07F5/02

    CPC分类号： C01B6/13 ,  C01B3/0015 ,  C07F5/00 ,  Y02E60/328

    摘要： Metal hydride materials react with BZ3 compounds in the presence of ligand to form BH3-L compounds. A compound of the formula HBZ2 is prepared from a compound of the formula BZ3 by reacting a first amount of a compound of the formula HBZ2 with a metal hydride material “MH” and a compound “L” to form a material of the formula BH3-L, and then reacting the BH3-L thus formed with a compound of the formula BZ3 to form HBZ2 in a second amount greater than the first amount of HBZ2. Z is selected from alkoxy, aryloxy, amido, arylamido, doubly substituted alkoxy, doubly substituted aryloxy, doubly substituted amido, doubly substituted arylamido, alkoxy-amido, and aryloxy-arylamido. When Z is bidentate, then HBZ2 has a ring structure. “L” is selected from ethers, aromatic ethers, amines, aromatic amines, heterocyclic nitrogen compounds, sulfides, aromatic sulfides, and heterocyclic sulfur compounds. “L” becomes a ligand in the BH3-L material.

    摘要翻译： 在配体存在下，金属氢化物与BZ 3 N 3化合物反应形成BH 3 -L-L化合物。 由式BZ 3 3的化合物通过使第一量的式为HBZ 2的化合物/ SUB 与金属氢化物材料“MH”和化合物“L”形成式BH 3 -L的材料，然后使BH 3 -L 3 -L 由式BZ 3 3的化合物形成，以形成大于第一量的HBZ 2 N 2的第二量的HBZ 2 N 2。 Z选自烷氧基，芳氧基，酰胺基，芳基酰氨基，双取代的烷氧基，双取代的芳氧基，双取代的酰氨基，双取代的芳基酰氨基，烷氧基 - 酰氨基和芳氧基 - 芳基酰氨基。 当Z为双齿时，则HBZ 2具有环结构。 “L”选自醚，芳香醚，胺，芳胺，杂环氮化合物，硫化物，芳族硫化物和杂环硫化合物。 “L”成为BH 3 -L材料中的配体。