摘要:
Perfluoropolyether compounds and mixtures thereof having the formula:A--O--(C.sub.3 F.sub.6 O).sub.P --(CF.sub.2 O).sub.Q --(C.sub.2 F.sub.4 O).sub.R --CF(Z)--CO--N(R)Arwherein the perfluoroalkyleneoxy groups are randomly distributed and A is a perfluoroalkyl group or a --CF(Z)--CO--N(R)Ar group; P, Q and R are zero but not simultaneously or numbers from 1 to 100, the sum of P, Q and R being 3 to 200; Z is a fluorine atom or a CF.sub.3 group; Ar is an aryl group; and R is hydrogen, alkyl, alkyl-aryl or an aryl group.These compounds are excellent stabilizers for perfluoropolyether fluids of the formula:X--O--(C.sub.3 F.sub.6 O).sub.P --(CF.sub.2 O).sub.q --(C.sub.2 F.sub.4 O).sub.r --Ywherein p, q and r are each zero or numbers from 1 to 100, the sum of p, q and r being 6 to 200, and X and Y are the same or different and are perfluoroalkyl groups having 1 to 3 carbon atoms.
摘要翻译:全氟聚醚化合物及其具有下式的混合物:AO-(C 3 F 6 O)P-(CF 2 O)Q-(C 2 F 4 O)R-CF(Z)-CO-N(R)Ar,其中全氟亚烷基氧基是随机分布的,A是全氟烷基 基团或-CF(Z)-CO-N(R)Ar基团; P,Q和R为零但不同时或数字从1到100,P,Q和R之和为3至200; Z是氟原子或CF 3基团; Ar是芳基; 和R是氢,烷基,烷基 - 芳基或芳基。 这些化合物是具有下式的全氟聚醚流体的优异稳定剂:XO-(C 3 F 6 O)P - (CF 2 O)q - (C 2 F 4 O)r Y其中p,q和r各自为零或数字为1至100,p,q r为6〜200,X和Y相同或不同,为碳原子数1〜3的全氟烷基。
摘要:
A process is disclosed for preparing peroxidic perfluoropolyethers comprising perfluoroalkylenoxy units having at least two carbon atoms, characterized in that one or more perfluoroolefins, except tetrafluoroethylene used alone, are reacted with oxygen in the liquid phase at a temperature not exceeding 50.degree. C. and in the presence of one or more compounds having one or more F-X bonds, in which X is selected from the group consisting of F, O and Cl.
摘要:
A process is disclosed for preparing peroxidic perfluoropolyethers containing perfluoroalkylenoxy units (CF.sub.2 --CF.sub.2 O) and (CF.sub.2 O), which is characterized in that tetrafluoroethylene and oxygen are reacted in a solvent at a temperature not exceeding 50.degree. C. and in the presence of one or more compounds having one or more F--X bonds, in which X is selected from the group consisting of F, O and Cl.
摘要:
Amorphous, highly viscous high molecular weight copolyethers containing in excess of 200 total repeating units and formed of --CF.sub.2 --CF.sub.2 --O-- and --CF.sub.2 --O-- repeating units randomly distributed along the chain and linked to each other either directly or through an oxygen atom, in which latter case a peroxy group is present along the chain. These copolyethers, which are useful for preparing bifunctional telomers, high molecular weight fluoropolymers, and highly stable lubricants and heat exchange materials, are prepared by reacting molecular oxygen with tetrafluoroethylene dissolved in a fluorinated or chlorofluorinated solvent selected from the group consisting of dichlorodifluoromethane, perfluorocyclobutane, perfluorodimethylcyclobutane, 1,2-dichloro-hexafluoropropane and 1,2-dichloro-tetrafluoroethane in the presence of ultraviolet radiation and under such conditions that the molar ratio of the tetrafluoroethylene to the oxygen in the reactant feed is between about 0.1 and 2, the reaction temperature is between about -80.degree. C. and -35.degree. C., the total pressure at the point where the gaseous reactants are introduced into the reaction zone is between about 1 and 2 atmospheres, and the ratio F/VE is greater than 3.0.times.10.sup.-4 (mols./cc. watt hour) where F is the number of mols/hour of tetrafluoroethylene fed to the reaction zone, E is the number of watts of ultraviolet rays having a wave length below 3,300 .ANG. which penetrate the reaction zone, and V is the volume of the reaction zone.