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1.发明授权Polymerized monomers in unsaturated compound-reacted epoxy resins advanced with dihydric phenol 失效不饱和化合物反应的环氧树脂中的聚合单体与二元酚进行反应
公开(公告)号：US4956425A
公开(公告)日：1990-09-11
申请号：US316847
申请日：1989-02-28
IPC分类号： C08F299/02 , C08G59/06 , C08G59/14 , C08G59/22
CPC分类号： C08G59/066 , C08F299/026 , C08G59/1433 , C08G59/226 , Y10S525/934
摘要： Novel advanced epoxy resins are disclosed which are the product resulting from (I) polymerizing in the presence of a catalytic quantity of a suitable polymerization catalyst (A) the reaction product of (1) a mixture consisting of (a) a diglycidyl ether of a dihydric phenol or a diglycidyl ether of a dihydric cyclohexanol and (b) a diglycidyl ether of a mono-, di-or polyetherdiol with (2) a compound containing both a group reactive with an epoxide group and a polymerizable ethylenically unsaturated group; with (B) a monomer mixture containing (1) at least one vinyl aromatic monomer, (2) a compound containing both a group reactive with an epoxide group and a polymerizable ethylenically unsaturated group and optionally (3) a hydroxyalkyl acrylate or methacrylate or an alkyl acrylate or methacrylate; and (II) advancing in the presence of a catalytic quantity of a suitable advancement catalyst, the product from (I) with (C) a dihydric phenol.
摘要翻译： 公开了新型先进的环氧树脂，其是由（I）在催化量的合适的聚合催化剂（A）的存在下聚合产生的产物，（A）由（a）由（a） 二元酚或二环己醇的二缩水甘油醚，（b）单 - ，二 - 或聚醚二醇的二缩水甘油醚与（2）含有与环氧基反应的基团和可聚合的烯属不饱和基团的化合物; 与（B）含有（1）至少一种乙烯基芳族单体的单体混合物，（2）含有与环氧基反应的基团和可聚合的烯属不饱和基团的化合物和任选的（3）丙烯酸酯或甲基丙烯酸羟烷基酯或 丙烯酸烷基酯或甲基丙烯酸烷基酯; 和（II）在催化量的合适的进料催化剂存在下进行，其中（I）与（C）二元酚的产物。
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公开(公告)号：US4611015A
公开(公告)日：1986-09-09
申请号：US681348
申请日：1984-12-13
CPC分类号： C04B41/009 , C04B26/04 , C04B26/10 , C04B26/18 , C04B41/48 , C04B41/63 , C04B2111/72
摘要： Polymer concrete compositions comprising an unsaturated thermosettable resin(s) and/or ethylenically unsaturated monomer(s), an aggregate component and a water absorbent polymer are cured to provide polymer concrete with enhanced adhesion to substrates, especially wet concrete. A primer or coating composition for concrete comprising a water absorbent polymer and an unsaturated thermosettable composition is also disclosed.
摘要翻译： 包含不饱和的可热固化树脂和/或烯键式不饱和单体，聚集体组分和吸水聚合物的聚合物混凝土组合物被固化以提供具有增强的与基材特别是湿混凝土的粘附性的聚合物混凝土。 还公开了一种包含吸水性聚合物和不饱和可热固化组合物的混凝土底漆或涂料组合物。
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3.发明授权Active hydrogen-containing compositions, process for preparing rigid polyurethane foams and articles prepared therefrom 失效活性含氢组合物，制备刚性聚氨酯泡沫的方法和由其制备的制品
公开(公告)号：US5241021A
公开(公告)日：1993-08-31
申请号：US788690
申请日：1991-11-06
CPC分类号： C08G59/56 , C08G18/4895 , C08G18/5069 , C08G18/581 , C08G18/584 , C08G65/04 , C08G2101/0025
摘要： The present invention refers to active hydrogen-containing compositions comprising alkoxylated epoxy resin adducts useful in the preparation of rigid polyurethane foams. The active hydrogen-containing compositions comprising alkoxylated epoxy resin adducts of the present invention provide improved physical properties, such as, for example, friability. This invention also refers to prepolymers and foamed articles prepared therefrom.
摘要翻译： 本发明涉及包含可用于制备刚性聚氨酯泡沫的烷氧基化环氧树脂加合物的含活性氢的组合物。 包含本发明的烷氧基化环氧树脂加合物的活性含氢组合物提供改善的物理性能，例如脆性。 本发明还涉及由其制备的预聚物和发泡制品。
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公开(公告)号：US5212262A
公开(公告)日：1993-05-18
申请号：US516018
申请日：1990-04-27
CPC分类号： C08G59/14 , C08G59/066 , C08G59/226 , C09D5/4434
摘要： A composition useful as an electrodepositable coating comprises a curing agent and an advanced epoxy resin prepared by advancing a diglycidyl ether of a dihydric phenol with an aromatic hydroxyl-containing reaction product of a diglycidyl ether of an oxyalkylated dihydric phenol and/or a diglycidyl ether of a (cyclo) aliphatic diol, optionally with a dihydric phenol and/or a monofunctional capping agent, combined with a diglycidyl ether of a dihydric phenol.
摘要翻译： 可用作电可沉积涂料的组合物包括固化剂和通过使二元酚的二缩水甘油醚与含烷氧基化的二元酚的二缩水甘油醚和/或二环氧基醚的二缩水甘油醚的芳族羟基反应产物 任选具有二元酚和/或单官能封端剂的（环）脂族二醇，与二元酚的二缩水甘油醚组合。
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5.发明授权
公开(公告)号：US5024785A
公开(公告)日：1991-06-18
申请号：US298432
申请日：1989-01-17
IPC分类号： C08F299/00 , C08F290/00 , C08F299/02 , C08G59/14 , C08G59/17 , C08G59/20 , C08G59/22 , C08G59/32
CPC分类号： C08G59/1466 , C08F299/026 , C08G59/20 , C08G59/22 , C08G59/3254 , C09K19/3814
摘要： Epoxy resins and vinyl ester resins are prepared which contain a polymeric domain containing mesogenic or rigid rodlike moieties.
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公开(公告)号：US4835228A
公开(公告)日：1989-05-30
申请号：US126397
申请日：1987-11-30
IPC分类号： C08F299/02 , C08G59/06 , C08G59/14 , C08G59/22
CPC分类号： C08G59/066 , C08F299/026 , C08G59/1433 , C08G59/226 , Y10S525/934
摘要： Novel advanced epoxy resins are disclosed which are the product resulting from (I) polymerizing in the presence of a catalytic quantity of a suitable polymerization catalyst (A) the reaction product of (1) a mixture consisting of (a) a diglycidyl ether of a dihydric phenol or a diglycidyl ether of a dihydric cyclohexanol and (b) a diglycidyl ether of a mono-, di- or polyetherdiol with (2) a compound containing both a group reactive with an epoxide group and a polymerizable ethylenically unsaturated group; with (B) a monomer mixture containing (1) at least one vinyl aromatic monomer, (2) a compound containing both a group reactive with an epoxide group and a polymerizable ethylenically unsaturated group and optionally (3) a hydroxyalkyl acrylate or methacrylate or an alkyl acrylate or methacrylate; and (II) advancing in the presence of a catalytic quantity of a suitable advancement catalyst, the product from (I) with (C) a dihydric phenol.
摘要翻译： 公开了新型先进的环氧树脂，其是由（I）在催化量的合适的聚合催化剂（A）的存在下聚合产生的产物，（A）由（a）由（a） 二元酚或二环己醇的二缩水甘油醚和（b）单 - ，二 - 或聚醚二醇的二缩水甘油醚与（2）含有与环氧基反应的基团和可聚合的烯键式不饱和基团的化合物; 与（B）含有（1）至少一种乙烯基芳族单体的单体混合物，（2）含有与环氧基反应的基团和可聚合的烯属不饱和基团的化合物和任选的（3）丙烯酸酯或甲基丙烯酸羟烷基酯或 丙烯酸烷基酯或甲基丙烯酸烷基酯; 和（II）在催化量的合适的进料催化剂存在下进行，其中（I）与（C）二元酚的产物。
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公开(公告)号：US4782124A
公开(公告)日：1988-11-01
申请号：US39192
申请日：1987-04-14
IPC分类号： C08L63/00 , C08F283/02
CPC分类号： C08L63/00
摘要： Modified epoxy resins are prepared by the reaction of one or more epoxy resins with polycarbonate resins or oligomers. One or more monoalcohols and/or monophenols can also be used in the modification reaction. The epoxy resins also can be advanced by inclusion of a polyphenol during the reaction. The modified epoxy resins have a chain branching and/or crosslinking due to carbonate bonding of polycarbonate chain scission products to the epoxy resin. The epoxy resins are useful to make powder coatings with enhanced adhesion to metal and resistance to cathodic disbondment.
摘要翻译： 改性环氧树脂通过一种或多种环氧树脂与聚碳酸酯树脂或低聚物的反应来制备。 一种或多种一元醇和/或单酚也可用于改性反应。 环氧树脂也可以通过在反应期间包含多酚进行。 改性环氧树脂由于聚碳酸酯链断裂产物与环氧树脂的碳酸键结合而具有支链和/或交联。 环氧树脂可用于制备具有增强的与金属粘合性和耐阴极剥离性的粉末涂料。
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8.发明授权Epoxy resin advanced with polyphenol/oxyalkylated aromatic or cycloyaliphatic diglycidyl ether product 失效环氧树脂与多酚/烷氧基化芳族或环脂族二缩水甘油醚产品一起推进
公开(公告)号：US5334676A
公开(公告)日：1994-08-02
申请号：US121398
申请日：1993-09-14
CPC分类号： C08G59/14 , C08G59/066 , C08G59/226 , C09D5/4434
摘要： Advanced epoxy resin compositions are prepared by reacting a composition comprising (1) an aromatic hydroxyl-containing product resulting from reacting a composition comprising (a) at least one diglycidyl ether of (i) an oxyalkylated aromatic diol, or (ii) at least one compound having two hydroxyl groups per molecule in which the hydroxyl groups are attached to an aliphatic or cycloaliphatic carbon atom and which compound is free of aromatic rings; or (iii) a combination of (i) and (ii); and (iv) optionally a diglycidyl ether compound different from (i) and (ii); and (b) at least one compound containing two aromatic hydroxyl groups per molecule; (2) at least one diglycidyl ether of a compound containing two aromatic groups per molecule; (3) optionally, one or more compounds containing two aromatic hydroxyl groups per molecule; and (4) optionally, a monofunctional capping agent. The advanced resins are useful in coating compositions.
摘要翻译： 先进的环氧树脂组合物是通过使包含（1）含芳族羟基的产物的组合物反应来制备的，所述组合物是使包含（a）至少一种（i）烷氧基化芳族二醇的二缩水甘油醚，或（ii）至少一种 每分子具有两个羟基的化合物，其中羟基连接到脂族或脂环族碳原子上，该化合物不含芳环; 或（iii）（i）和（ii）的组合; 和（iv）任选的不同于（i）和（ii）的二缩水甘油醚化合物; 和（b）至少一种每分子含有两个芳族羟基的化合物; （2）每分子含有两个芳族基团的化合物的至少一种二缩水甘油醚; （3）任选地，每个分子含有一个或多个含有两个芳族羟基的化合物; 和（4）任选的单官能封端剂。 先进的树脂可用于涂料组合物中。
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