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公开(公告)号：US08501071B2
公开(公告)日：2013-08-06
申请号：US12311654
申请日：2007-11-19
申请人： Hanneke Boerstoel , Johannes Bos , Adriaan Anton Schaap , Dennis Wilbers , Leonardus Antonius Godfried Busscher , Antonius Henricus Maria Schotman , Kurt Rainer Hans-Heinrich Stolze
发明人： Hanneke Boerstoel , Johannes Bos , Adriaan Anton Schaap , Dennis Wilbers , Leonardus Antonius Godfried Busscher , Antonius Henricus Maria Schotman , Kurt Rainer Hans-Heinrich Stolze
摘要： The invention relates to a method for obtaining high-tenacity aramid yarn, wherein the yarn is made of a copolymer obtained from a mixture of monomers comprising DAPBI, an aromatic para-diamine, and an aromatic para-diacid, wherein the yarn is heated in at least two process steps, characterized in that in a first step the yarn is heated at a temperature of 200 to 360° C. at a tension of at least 0.2 cN/dtex, followed by a second step wherein the yarn is heated at a temperature of 370 to 500° C. at a tension of less than 1 cN/dtex. The invention further pertains to a multifilament aramid yarn spun from a sulfuric acid spin dope and having a tenacity of at least 2500 mN/tex.
摘要翻译： 本发明涉及一种获得高强度芳族聚酰胺纱线的方法，其中纱线由由包含DAPBI，芳族对二胺和芳族对二酸的单体混合物获得的共聚物制成，其中纱线被加热 至少两个工艺步骤，其特征在于，在第一步骤中，纱线在200至360℃的温度下以至少0.2cN / dtex的张力加热，接着是第二步骤，其中纱线在 温度为370-500℃，张力小于1cN / dtex。 本发明还涉及从硫酸纺丝原液纺丝并具有至少2500mN / tex的强度的复丝芳纶纱线。
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公开(公告)号：US07838622B2
公开(公告)日：2010-11-23
申请号：US12092390
申请日：2006-11-01
CPC分类号： C08G69/32 , C08G69/26 , C08G73/22 , C08J3/05 , C08J2377/06 , C08L77/10 , C08L79/08 , C08L2205/02 , D01F6/60 , D01F6/605 , D01F6/74 , D01F6/805 , C08L2666/20
摘要： This invention is to provide a dope that has excellent formability and can be formed into a fiber, a film, pulp-shaped particles and the like by a wet method. This invention is also to provide a process for the production of a fiber excellent in heat resistance, strength and elastic modulus. This invention provides a dope and a process for the production of a fiber from the dope, the dope including a polyamide and a basic solvent, the polyamide containing a recurring unit of the following formula (I), wherein Ar1 represents at least one substituent selected from the group consisting of and having an inherent viscosity of 1.0 or more, the dope has a polyamide concentration of over 10% by weight but not more than 25% by weight and exhibits optical anisotropy at 50° C.
摘要翻译： 本发明提供一种具有优异成型性的涂料，可通过湿法形成纤维，薄膜，纸浆状颗粒等。 本发明还提供一种制造耐热性，强度和弹性模量优异的纤维的方法。 本发明提供了一种用于从涂料生产纤维的涂料和方法，所述涂料包括聚酰胺和碱性溶剂，所述聚酰胺含有下式（I）的重复单元，其中Ar 1表示选自至少一个取代基 由特性粘度为1.0以上的聚合物组成的聚酰胺浓度为10重量％以上且25重量％以下，在50℃下显示光学各向异性
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公开(公告)号：US20100001433A1
公开(公告)日：2010-01-07
申请号：US12311654
申请日：2007-11-19
申请人： Hanneke Boerstoel , Johannes Bos , Adriaan Anton Schaap , Dennis Wilbers , Leonardus Antonius Godfried Busscher , Antonius Henricus Maria Schotman , Kurt Rainer Hans-Heinrich Stolze
发明人： Hanneke Boerstoel , Johannes Bos , Adriaan Anton Schaap , Dennis Wilbers , Leonardus Antonius Godfried Busscher , Antonius Henricus Maria Schotman , Kurt Rainer Hans-Heinrich Stolze
IPC分类号： D01F6/00
摘要： The invention relates to a method for obtaining high-tenacity aramid yarn, wherein the yarn is made of a copolymer obtained from a mixture of monomers comprising DAPBI, an aromatic para-diamine, and an aromatic para-diacid, wherein the yarn is heated in at least two process steps, characterized in that in a first step the yarn is heated at a temperature of 200 to 360° C. at a tension of at least 0.2 cN/dtex, followed by a second step wherein the yarn is heated at a temperature of 370 to 500° C. at a tension of less than 1 cN/dtex. The invention further pertains to a multifilament aramid yarn spun from a sulfuric acid spin dope and having a tenacity of at least 2500 mN/tex.
摘要翻译： 本发明涉及一种获得高强度芳族聚酰胺纱线的方法，其中纱线由由包含DAPBI，芳族对二胺和芳族对二酸的单体混合物获得的共聚物制成，其中纱线被加热 至少两个工艺步骤，其特征在于，在第一步骤中，纱线在200至360℃的温度下以至少0.2cN / dtex的张力加热，接着是第二步骤，其中纱线在 温度为370-500℃，张力小于1cN / dtex。 本发明还涉及从硫酸纺丝原液纺丝并具有至少2500mN / tex的强度的复丝芳纶纱线。
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公开(公告)号：US09194061B2
公开(公告)日：2015-11-24
申请号：US10582119
申请日：2004-11-30
申请人： Anton Johannes Josef Hendriks , Dennis Wilbers , Harrie Grotendorst , René Journee , Mirjam Ellen Oldenzeel
发明人： Anton Johannes Josef Hendriks , Dennis Wilbers , Harrie Grotendorst , René Journee , Mirjam Ellen Oldenzeel
CPC分类号： D01F6/605 , D21H13/26 , Y10T428/249924
摘要： A para-aramid fibrid film is disclosed that has at least 95% of the bonds of the polymer are para-oriented. A method for making said para-aramid fibrid film by (a) polymerizing a para-oriented aromatic diamine and a para-oriented aromatic dicarboxylic acid halide to an aramid polymer having only para-oriented bonds in a mixture of solvents consisting of N-methylpyrrolidone or dimethylacetamide and calcium chloride or lithium chloride to obtain a dope wherein the polymer is dissolved in the mixture of solvents and the polymer concentration is 2 to 6 wt. %, and (b) converting the dope to para-aramid fibrid film is also described.
摘要翻译： 公开了对位芳族聚酰胺隔离纤维膜，其中至少95％的聚合物的键是对位取向的。 （a）将对位芳族二胺和对位芳族二羧酸卤化物聚合到由N-甲基吡咯烷酮组成的溶剂混合物中仅具有对位取向键的芳族聚酰胺聚合物制备所述对位芳族聚酰胺隔离纤维膜的方法 或二甲基乙酰胺和氯化钙或氯化锂以获得其中聚合物溶解在溶剂混合物中并且聚合物浓度为2至6重量％的涂料。 ％，和（b）将涂料转化为对位芳族聚酰胺隔离纤维膜也被描述。
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公开(公告)号：US20100222544A1
公开(公告)日：2010-09-02
申请号：US12092685
申请日：2006-11-02
摘要： This invention seeks to provide a fiber formed of an aromatic polyazole that has a high molecular weight and is excellent in mechanical properties such as elastic modulus, strength, etc., and a process for the production thereof.This invention provides a fiber formed of a polyazole containing a recurring unit of the following formula (1), wherein Ar1 is a divalent aromatic group having 4 to 20 carbon atoms, Ar2 is a tetravalent aromatic group having 4 to 20 carbon atoms and each X is O, S or NH, and having a phosphorus atom content of 30 ppm or less, and a process for the production thereof.
摘要翻译： 本发明寻求提供一种由具有高分子量并且机械性能如弹性模量，强度等优异的芳族聚唑形成的纤维及其制备方法。 本发明提供一种由含有下式（1）的重复单元的聚唑形成的纤维，其中Ar1为碳原子数为4〜20的二价芳香族基团，Ar 2为碳原子数4〜20的四价芳香族基团，各X 是O，S或NH，并且磷原子含量为30ppm以下，以及其制造方法。
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公开(公告)号：US20100121017A1
公开(公告)日：2010-05-13
申请号：US12451122
申请日：2008-04-24
IPC分类号： C08G63/127 , B29C47/88
CPC分类号： C08G73/22 , B29C48/04 , B29C48/05 , B29C48/08 , B29C48/919 , C08L77/06 , C08L79/04 , D01F6/74 , C08L2666/20
摘要： The invention relates to a fiber, pulp, fibril, or fibrid comprising polybenzazole having a repeating unit of formula (I) or (II) wherein Ar1 and Ar2 are independently an aromatic group having 4 to 12 carbon atoms, Ar1 has the para configuration and 40-100% of the repeating units are repeating unit I and/or repeating unit II and wherein the polybenzazole contains less than 1500 ppm of non-extractable phosphorus compound if 100% of the repeating units are repeating unit I and/or repeating unit II and X and Y are the same. The method allows the manufacture of phosphorous element free a fiber, pulp, fibril, or fibrid containing said polybenzazole precursor or polybenzazole and a spinning method for obtaining said fiber, pulp, fibril, or fibrid.
摘要翻译： 本发明涉及包含具有式（I）或（II）重复单元的聚吲哚的纤维，纸浆，原纤维或纤维素，其中Ar 1和Ar 2独立地为具有4至12个碳原子的芳族基团，Ar 1具有对位构型和 40-100％的重复单元是重复单元I和/或重复单元II，其中如果100％的重复单元是重复单元I和/或重复单元II，聚吲唑含有小于1500ppm的不可萃取的磷化合物 X和Y相同。 该方法允许制造含有所述聚吲哚前体或聚吲哚的纤维，纸浆，原纤维或纤维状物的磷元素，以及用于获得所述纤维，纸浆，原纤维或纤条体的纺丝方法。
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公开(公告)号：US20090127735A1
公开(公告)日：2009-05-21
申请号：US12092390
申请日：2006-11-01
CPC分类号： C08G69/32 , C08G69/26 , C08G73/22 , C08J3/05 , C08J2377/06 , C08L77/10 , C08L79/08 , C08L2205/02 , D01F6/60 , D01F6/605 , D01F6/74 , D01F6/805 , C08L2666/20
摘要： The object of this invention is to provide a dope that has excellent formability and can be formed into a fiber, a film, pulp-shaped particles and the like by a wet method. The object of this invention is also to provide a process for the production of a fiber excellent in heat resistance, strength and elastic modulus.This invention provides a dope and a process for the production of a fiber from the dope, the dope comprising a polyamide and a basic solvent, the polyamide containing a recurring unit of the following formula (I), wherein Ar1 represents at least one substituent selected from the group consisting of and having an inherent viscosity of 1.0 or more, the dope has a polyamide concentration of over 10% by weight but not more than 25% by weight and exhibits optical anisotropy at 50° C.
摘要翻译： 本发明的目的是提供一种具有优异成型性的涂料，并可通过湿法形成纤维，薄膜，纸浆状颗粒等。 本发明的目的还在于提供一种制造耐热性，强度和弹性模量优异的纤维的方法。 本发明提供了一种用于从纺丝原液生产纤维的涂料和方法，所述涂料包含聚酰胺和碱性溶剂，所述聚酰胺含有下式（I）的重复单元，其中Ar 1表示至少一个选自 由特性粘度为1.0以上的聚合物组成的聚酰胺浓度为10重量％以上且25重量％以下，在50℃下显示光学各向异性
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公开(公告)号：US20070087178A1
公开(公告)日：2007-04-19
申请号：US10582119
申请日：2004-11-30
IPC分类号： D01D5/08
CPC分类号： D01F6/605 , D21H13/26 , Y10T428/249924
摘要： A para-aramid fibrid film is disclosed that has at least 95% of the bonds of the polymer are para-oriented. A method for making said para-aramid fibrid film by (a) polymerizing a para-oriented aromatic diamine and a para-oriented aromatic dicarboxylic acid halide to an aramid polymer having only para-oriented bonds in a mixture of solvents consisting of N-methylpyrrolidone or dimethylacetamide and calcium chloride or lithium chloride to obtain a dope wherein the polymer is dissolved in the mixture of solvents and the polymer concentration is 2 to 6 wt. %, and (b) converting the dope to para-aramid fibrid film is also described.
摘要翻译： 公开了对位芳族聚酰胺隔离纤维膜，其中至少95％的聚合物的键是对位取向的。 （a）将对位芳族二胺和对位芳族二羧酸卤化物聚合到由N-甲基吡咯烷酮组成的溶剂混合物中仅具有对位取向键的芳族聚酰胺聚合物制备所述对位芳族聚酰胺隔离纤维膜的方法 或二甲基乙酰胺和氯化钙或氯化锂以获得其中聚合物溶解在溶剂混合物中并且聚合物浓度为2至6重量％的涂料。 ％，和（b）将涂料转化为对位芳族聚酰胺隔离纤维膜也被描述。
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公开(公告)号：US09505183B2
公开(公告)日：2016-11-29
申请号：US14116507
申请日：2012-05-08
申请人： Hendrik Van De Hee , Dennis Wilbers
发明人： Hendrik Van De Hee , Dennis Wilbers
CPC分类号： B29D7/01 , B29C55/06 , B29C55/18 , B29K2023/0683
摘要： A process for rolling and stretching of a sheet into a tape is provided. A sheet may be rolled into a rolled sheet in the nip between two rolls of the calender and the rolled sheet is stretched immediately thereafter into a tape on the surface of one of the two calender rolls. The speed of the rolled sheet on the surface of the calender roll may be higher than the speed of the calender roll. The position of the start of the neck-down of the rolled sheet and the rate of neck-down can be easily controlled by the proposed process.
摘要翻译： 提供了将片材拉伸和拉伸成带材的方法。 在压延机的两个辊之间的辊隙中，可以将片材卷成轧制板，然后将轧制的片材立即拉伸到两个压延辊之一的表面上的带中。 压延辊的表面上的轧制速度可以高于压延辊的速度。 通过提出的方法可以容易地控制轧制板的颈缩开始的位置和颈缩的速度。
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公开(公告)号：US20140070449A1
公开(公告)日：2014-03-13
申请号：US14116507
申请日：2012-05-08
申请人： Hendrik Van De Hee , Dennis Wilbers
发明人： Hendrik Van De Hee , Dennis Wilbers
IPC分类号： B29D7/01
CPC分类号： B29D7/01 , B29C55/06 , B29C55/18 , B29K2023/0683
摘要： A process for rolling and stretching of a sheet into a tape is provided. A sheet may be rolled into a rolled sheet in the nip between two rolls of the calender and the rolled sheet is stretched immediately thereafter into a tape on the surface of one of the two calender rolls. The speed of the rolled sheet on the surface of the calender roll may be higher than the speed of the calender roll. The position of the start of the neck-down of the rolled sheet and the rate of neck-down can be easily controlled by the proposed process.
摘要翻译： 提供了将片材拉伸和拉伸成带材的方法。 在压延机的两个辊之间的辊隙中，可以将片材卷成轧制板，然后将轧制的片材立即拉伸到两个压延辊之一的表面上的带中。 压延辊的表面上的轧制速度可以高于压延辊的速度。 通过提出的方法可以容易地控制轧制板的颈缩开始的位置和颈缩的速度。
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