摘要:
A positive active material for rechargeable lithium batteries includes an active material component processed from a manganese-based compound. The transition metal compound is selected from LixMnO2, LixMnF2, LixMnS2, LixMnO2-zFz, LixMnO2-zSz, LixMn1-yMyO2, LixMn1-yMyF2, LixMn1-yMyS2, LixMn1-yMyO2-zFz, LixMn1-yMyO2-zSz, LixMn2O4, LixMn2F4, LixMn2O4-zFz, LixMn2O4-zSz, LixMn2-yMyO4, LixMn2-yMyF4, LixMn2-yMyS4, LixMn2-yMyO4-zFz, or LixMn2-yMyO4-zSz where 0
摘要:
Disclosed is active material for a positive electrode used in lithium secondary batteries of Formula 1 below and a method of manufacturing the active material. The active material includes large particles of 1 to 25 &mgr;m formed of a plurality of minute particles of 0.4 to 0.7 &mgr;m. The method includes the steps of adding a chelating agent to a mixture derived by dissolving lithium salt, nickel salt and cobalt salt in a solvent to a molar ratio of 0.95-1.06: 0.5-1:0-0.5; producing a gel by heating the mixture; for precursor by thermally decomposing the gel; and heat treating the precursor. LixNi1−yCoyO2 [Formula 1] where x is between 0.95 and 1.06, and y is between 0 and 0.5.
摘要:
A positive active material composition for a rechargeable battery includes a positive active material selected from compounds represented by formulas 1 to 13, and at least one semi-metal, metal or oxides thereof: LixMnA2(1) LixMnO2-zAz(2) LixMn1-yM′yA2(3) LixMn2A4(4) LixMn2O4-zAz(5) LixMn2-yM′yA4(6) LixBA2(7) LIxBO2-zAz(8) LixB1-yM″yA2(9) LixB1-yM″yO2-zAz(10) LixNiCoO2-zAz(11) LixNiCoO2-zAz(12) LixNi1-y-zCoyM″zA2(13) where 1.0≦x≦1.1, 0.01≦y≦0.1, 0.01≦z≦0.5, M′ is at least one transition metal or lanthanide metal selected from Al, Cr, Co, Mg, La, Ce, Sr, or V, M″ is at least one transition metal or lanthanide metal selected from Al, Cr, Mn, Fe, Mg, La, Ce, Sr or V, A is selected from O, F, S or P, and B is Ni or Co.
摘要翻译:用于可再充电电池的正极活性材料组合物包括选自由式1至13表示的化合物的正极活性物质和至少一种半金属,金属或氧化物:LixMnA2(1)LixMnO2-zAz(2)LixMn1-yM 'yA2(3)LixMn2A4(4)LixMn2O4-zAz(5)LixMn2-yM'yA4(6)LixBA2(7)LIxBO2-zAz(8)LixB1-yM''A2(9)LixB1-yM''yO2-zAz (10)LixNiCoO2-zA2(11)LixNiCoO2-zA2(12)LixNi1-y-zCoyM''zA2(13)其中1.0 <= x <= 1.1,0.01 <= y <= 0.1,0.01 <= z <= 0.5 M'是选自Al,Cr,Co,Mg,La,Ce,Sr或V中的至少一种过渡金属或镧系金属,M“是选自Al,Cr,Mn中的至少一种过渡金属或镧系金属 ,Fe,Mg,La,Ce,Sr或V,A选自O,F,S或P,B为Ni或Co
摘要:
A positive active material composition for a rechargeable battery includes a positive active material selected from compounds represented by formulas 1 to 13, and at least one semi-metal, metal or oxides thereof: LixMnA2 (1) LixMnO2−zAz (2) LixMn1−yM′yA2 (3) LixMn2A4 (4) LixMn2O4−zAz (5) LixMn2−yM′yA4 (6) LixBA2 (7) LixBO2−zAz (8) LixB1−yM″yA2 (9) LixB1−yM″yO2−zAz (10) LixNiCoO2−zAz (11) LixNiCoO2−zAz (12) LixNi1−y−zCoyM″zA2 (13)where 1.0≦x≦1.1, 0.01≦y≦0.1, 0.01≦z≦0.5, M′ is at least one transition metal or lanthanide metal selected from Al, Cr, Co, Mg, La, Ce, Sr, or V, M″ is at least one transition metal or lanthanide metal selected from Al, Cr, Mn, Fe, Mg, La, Ce, Sr or V, A is selected from 0, F, S or P, and B is Ni or Co.
摘要:
A positive active material for rechargeable lithium batteries includes an active material component processed from a manganese-based compound. The transition metal compound is selected from LixMnO2, LixMnF2, LixMnS2, LixMnO2-zFz, LixMnO2-xSz, LixMn1-yMyO2, LixMn1-yMyF2, LixMn1-yMyS2, LixMn1-yMyO2-zFz, LixMn1-yMyO2-zSz, LixMn2O4, LixMn2F4, LixMn2S4, LixMn2O4-zFz, LixMn2O4-zSz, LixMn2-yMyO4, LixMn2-yMyF4, LixMn2-yMyS4, LixMn2-yMyO4-zFz, or LixMn2-yMyO4-zSz where O
摘要:
A positive active material composition for a rechargeable battery includes a positive active material selected from compounds represented by formulas 1 to 13, and at least one semi-metal, metal or oxides thereof: LixMnA2 (1) LixMnO2−zAz (2) LixMn1−yM′yA2 (3) LixMn2A4 (4) LixMn2O4−zAz (5) LixMn2−yM′yA4 (6) LixBA2 (7) LixBO2−zAz (8) LixB1−yM″yA2 (9) LixB1−yM″yO2-zAz (10) LixNiCoO2−zAz (11) LixNiCoO2−zAz (12) LixNi1−y-zCoyM″zA2 (13) where 1.0≦x≦1.1, 0.01≦y≦0.1, 0.01≦z≦0.5, M′ is at least one transition metal or lanthanide metal selected from Al, Cr, Co, Mg, La, Ce, Sr, or V, M″ is at least one transition metal or lanthanide metal selected from Al, Cr, Mn, Fe, Mg, La, Ce, Sr or V, A is selected from 0, F, S or P, and B is Ni or Co.
摘要翻译:用于可再充电电池的正极活性材料组合物包括选自由式1至13表示的化合物的正极活性物质和至少一种半金属,金属或氧化物:LixMnA2(1)LixMnO2-zAz(2)LixMn1-yM 'yA2(3)LixMn2A4(4)LixMn2O4-zAz(5)LixMn2-yM'yA4(6)LixBA2(7)LixBO2-zAz(8)LixB1-yM''A2(9)LixB1-yM''yO2-zAz (10)LixNiCoO2-zAz(11)LixNiCoO2-zAz(12)LixNi1-y-zCoyM''zA2(13)其中1.0 <= x <= 1.1,0.01 <= y <= 0.1,0.01 <= z <= 0.5 M'是选自Al,Cr,Co,Mg,La,Ce,Sr或V中的至少一种过渡金属或镧系金属,M“是选自Al,Cr,Mn中的至少一种过渡金属或镧系金属 ,Fe,Mg,La,Ce,Sr或V,A选自0,F,S或P,B为Ni或Co
摘要:
A positive active material for rechargeable lithium batteries includes an active material component processed from a manganese-based compound. The transition metal compound is selected from LixMnO2, LixMnF2, LixMnS2, LixMnO2-zFz, LixMnO2-zSz, LixMn1-yMyO2, LixMn1-yMyF2, LixMn1-yMyS2, LixMn1-yMyO2-zFz, LixMn1-yO2-zSz, LixMn2O4, LixMn2F4, LixMn2S4, LixMn2O4-zFz, LixMn2O4-zSz, LixMn2-yMyO4, LixMn2-yMyF4, LixMn2-yMyS4, LixMn2-yMyO4-zFz, or LixMn2-yMyO4-zSz where 0
摘要:
A method for fabricating a porous composite oxide is provided. The method includes the steps of: (a) slowly mixing a solution including a silicon oxide source and a solution including an aluminum oxide source; (b) adding hydrochloric acid to the mixed solution prepared in said step (a) to obtain a sol; and (c) adding sodium hydroxide to said sol, reacting the obtained resultant at room temperature for 30 minutes to 12 hours, and drying the resultant. The porous composite oxide has an abundance of fine pores and the distribution of pore size is relatively uniform, so that the porous composite oxide is suitable for a carrier.
摘要:
Disclosed is a positive active material for a rechargeable lithium battery. The positive active material includes a core including at least one compound represented by Formula 1 and an active metal oxide shell formed on the core. Formula 1 LiA1−x−yBxCyO2 where 0≦x≦0.3, 0≦y≦0.01, and A is an element selected from the group consisting of Co and Mn; B is an element selected from the group consisting of Ni, Co, Mn, B, Mg, Ca, Sr, Ba, Ti, V, Cr, Fe, Cu and Al; and C is an element selected from the group consisting of Ni, Co, Mn, B, Mg, Ca, Sr, Ba, Ti, V, Cr, Fe, Cu and Al.
摘要:
Disclosed is a positive active material for a lithium secondary battery having high capacity and long durability properties and particularly to a powder of LiaNi1-x-yC OxMyO2, LiaNi1-x-yC OxMyO2-zFz or LiaNi1-x-yC OxMyO2-zSz (where M is a metal selected from the group consisting of Al, Mg, Sr, La, Ce, V, and Ti and wherein 0≦0.99, 0.01≦y≦0.1, 0.01≦z≦0.1, and 1.00≦a≦1.1) is surface-treated by a metal alkoxide solution whereby the durability, capacity and structural safety of said positive active material is increased.
摘要翻译:公开了具有高容量和长的耐久性的锂二次电池的正极活性材料,特别是对于LiaNi1-x-yC OxMyO2,LiaNi1-x-yC OxMyO2-zFz或LiaNi1-x-yC OxMyO2-zSz的粉末(其中 M是选自Al,Mg,Sr,La,Ce,V和Ti的金属,其中0 <=0.99,0.01≤y≤0.1,0.01≤z≤0.1, = a <= 1.1)由金属醇盐溶液进行表面处理,由此提高所述正极活性物质的耐久性,容量和结构安全性。