公开(公告)号：US4241141A

公开(公告)日：1980-12-23

申请号：US21748

申请日：1979-03-19

申请人： Douglas W. Dill

发明人： Douglas W. Dill

IPC分类号： B05D1/32 ,  B05D5/00 ,  C09D5/00 ,  C09D133/06 ,  B32B27/00

CPC分类号： B05D5/00 ,  C09D133/064 ,  C09D5/008 ,  B05D1/325 ,  Y10T428/31855

摘要： A method for protecting painted and other surfaces from being permanently marked by graffiti and particularly markings of flexible tip permanent marking pens comprising coating the surface with a removable composition consisting essentially of from 10 to 35% by weight of a polymer having a monomer content of from 25-70% by weight of a hard monomer, 15-50% by weight of a soft monomer, and 15-30% by weight of an acid monomer, the polymer having been solubilized with sodium hydroxide, potassium hydroxide, or mixtures thereof, from 0-15% of a potassium or sodium salt of a maleic anhydride adduct with a mixed alpha olefin having chain lengths of more than 30 carbon atoms, from 0 to 2% of a coalescing solvent selected from the group consisting of diethylene glycol monoethyl ether, diethylene glycol monobutyl ethyl and mixtures thereof; from 0 to 3% of defoamers, leveling agents, and mixtures thereof; and 90 to 45% by weight water, the composition having an MFT of less than 30.degree. C. and a pH of from 7.0 to 10.0 and allowing the coating to dry on the surface to be protected.

摘要翻译： 一种用于保护涂漆和其它表面的方法不被永久标记的涂鸦和特别是柔性尖端永久标记笔的标记，包括用可移除的组合物涂覆表面，该组合物基本上由10至35重量％的单体含量为 25-70重量％的硬单体，15-50重量％的软单体和15-30重量％的酸单体，所述聚合物已经用氢氧化钠，氢氧化钾或其混合物溶解， 0-15％的具有链长超过30个碳原子的混合α-烯烃的马来酐加合物的钾盐或钠盐，0至2％的聚结溶剂，其选自二甘醇单乙醚 ，二甘醇单丁基乙基及其混合物; 0％至3％的消泡剂，流平剂及其混合物; 和90至45重量％的水，所述组合物具有小于30℃的MFT和7.0至10.0的pH，并使得涂层在待保护的表面上干燥。

公开(公告)号：US3983060A

公开(公告)日：1976-09-28

申请号：US491589

申请日：1974-07-24

申请人： Douglas W. Dill

发明人： Douglas W. Dill

IPC分类号： B05D7/00 ,  C04B41/48 ,  C04B41/83 ,  C08L33/08 ,  C08L33/12 ,  C09D133/12

CPC分类号： B05D7/542 ,  B05D7/587 ,  C04B41/483 ,  C04B41/83 ,  C08L33/08 ,  C09D133/12 ,  C08L2205/02 ,  C08L33/12

摘要： A low temperature glazing composition consisting essentially of a mixture of 25-75% by weight of an aqueous dispersion of an acrylic resin having a monomer composition of 40-85% by weight methyl methacrylate, 45-15% by weight butyl acrylate and 0-15% by weight methacrylic acid, this dispersion having 15-25% non-volatiles and a pH of 8.5-10.5; and 75-25% by weight of a powdered resin composition having a particle size within the range of 100-400 mesh consisting essentially of 100-80% by weight of a resin having a monomer composition of 60-85% by weight methyl methacrylate and 40-15% by weight butyl acrylate having a molecular weight of 10,000-20,000 and a Tg greater than 45.degree.C and 0-20% by weight of a pigment.

摘要翻译： 基本上由25-75重量％的丙烯酸树脂的水分散体的混合物组成的低温玻璃组合物，所述水分散体的单体组成为40-85重量％的甲基丙烯酸甲酯，45-15重量％的丙烯酸丁酯和0- 15重量％甲基丙烯酸，该分散体具有15-25％的非挥发物，pH为8.5-10.5; 和75-25重量％的粒径在100-400目范围内的粉末状树脂组合物基本上由100-80重量％的单体组成为60-85重量％的甲基丙烯酸甲酯和 40-15重量％的丙烯酸丁酯，分子量为10,000-20,000，Tg大于45℃，颜料为0-20重量％。

公开(公告)号：US4053664A

公开(公告)日：1977-10-11

申请号：US705203

申请日：1976-07-14

申请人： Douglas W. Dill

发明人： Douglas W. Dill

IPC分类号： B05D7/00 ,  C04B41/48 ,  C04B41/83 ,  C08L33/12 ,  B05D1/38 ,  B05D3/02

CPC分类号： C04B41/009 ,  B05D7/542 ,  B05D7/587 ,  C04B41/483 ,  C04B41/83 ,  C08L2205/02 ,  C08L33/12

摘要： A low temperature glazing composition consisting essentially of a mixture of 25-75% by weight of an aqueous dispersion of an acrylic resin having a monomer composition of 40-85% by weight methyl methacrylate, 45-15% by weight butyl acrylate and 0-15% by weight methacrylic acid, this dispersion having 15-25% non-volatiles and a pH of 8.5-10.5; and 75-25% by weight of a powdered resin composition having a particle size within the range of 100-400 mesh consisting essentially of 100-80% by weight of a resin having a monomer composition of 60-85% by weight methyl methacrylate and 40-15% by weight butyl acrylate having a molecular weight of 10,000-20,000 and a Tg greater than 45.degree. C and 0-20% by weight of a pigment.