PROCESS FOR MAKING COMPOSITE LITHIUM POWDERS FOR BATTERIES
    1.
    发明申请
    PROCESS FOR MAKING COMPOSITE LITHIUM POWDERS FOR BATTERIES 审中-公开
    制造电池用复合锂电池的方法

    公开(公告)号:US20100154206A1

    公开(公告)日:2010-06-24

    申请号:US12339846

    申请日:2008-12-19

    Abstract: This invention relates to lithium-ion batteries and cathode powders for making lithium-ion batteries where the cathode powder comprises a blend or mixture of at least one lithium transition metal poly-anion and with one or more lithium transition-metal oxide powders. A number of different lithium transition-metal oxides are suitable, especially formulations that include nickel, manganese and cobalt. The preferred lithium transition metal poly-anion is carbon-containing lithium vanadium phosphate. Batteries using the mixture or blend of these powders have been found to have high specific capacity, especially based on volume, high cycle life, substantially improved safety issues as compared to lithium transition-metal oxides, per se, and an attractive electrode potential profile.

    Abstract translation: 本发明涉及用于制造锂离子电池的锂离子电池和阴极粉末,其中阴极粉末包含至少一种锂过渡金属多阴离子和一种或多种锂过渡金属氧化物粉末的共混物或混合物。 许多不同的锂过渡金属氧化物是合适的,特别是包括镍,锰和钴的制剂。 优选的锂过渡金属多阴离子是含碳的磷酸钒锂。 已经发现使用这些粉末的混合物或混合物的电池具有高比容量,特别是基于体积,高循环寿命,与锂过渡金属氧化物本身相比显着改善的安全性问题以及吸引电极电位分布。

    Methods of preparing carbonaceous anode materials and using same
    2.
    发明授权
    Methods of preparing carbonaceous anode materials and using same 有权
    制备碳质阳极材料及其使用方法

    公开(公告)号:US07597999B2

    公开(公告)日:2009-10-06

    申请号:US11422824

    申请日:2006-06-07

    CPC classification number: H01M4/587 C01B32/20 H01M10/052

    Abstract: A method for the production of carbon particles comprising selecting a precursor material, sizing said precursor material, stabilizing said precursor material, carbonizing said precursor material, and graphitizing said precursor material, wherein the precursor material has a volatile matter content of from about 5 wt. % to about 60 wt. %. A method for the production of electrode materials comprising selecting a precursor material, sizing said precursor material, stabilizing said precursor material, carbonizing said precursor material, and graphitizing said precursor material, wherein said electrode material has an average particle size of from about 1 μm to about 50 μm, a fixed carbon content of greater than about 80 wt. %, and a graphitic structure. A carbon particle having an average particle size of from about 1 μm to about 50 μm, a degree of stabilization of from about 0.1 wt. % to about 10 wt. %, a fixed carbon content of greater than about 80 wt. %, and a graphitic structure.

    Abstract translation: 一种用于生产碳颗粒的方法,包括选择前体材料,调整所述前体材料的尺寸,稳定所述前体材料,碳化所述前体材料,以及石墨化所述前体材料,其中所述前体材料的挥发物含量为约5wt。 %至约60wt。 %。 一种用于生产电极材料的方法,包括选择前体材料,调整所述前体材料的尺寸,稳定所述前体材料,碳化所述前体材料,并石墨化所述前体材料,其中所述电极材料的平均粒度为约1μm至 约50μm,固定碳含量大于约80wt。 %,和石墨结构。 平均粒度为约1〜50μm的碳粒子,稳定度为约0.1重量% %至约10wt。 %,固定碳含量大于约80wt。 %,和石墨结构。

    Process for producing isotropic coke
    4.
    发明授权
    Process for producing isotropic coke 失效
    生产各向同性焦炭的方法

    公开(公告)号:US5160602A

    公开(公告)日:1992-11-03

    申请号:US766998

    申请日:1991-09-27

    CPC classification number: C10B57/06 C10B55/00

    Abstract: A non air-blown low sulfur heavy aromatic mineral oil which does not produce acceptable isotropic coke when subjected to delayed coking is combined with an inorganic additive which promotes pyrolysis and which vaporizes during calcining and the combination is subjected to delayed coking to produce isotropic coke having a low CTE ratio. The isotropic coke is further processed (including calcination) to produce graphite logs used in nuclear reactors.

    Abstract translation: 当经受延迟焦化时不产生可接受的各向同性焦炭的非气吹低硫重质芳族矿物油与促进热解并在煅烧期间汽化的无机添加剂组合,并且组合经受延迟焦化以产生具有 低CTE比例。 将各向同性焦炭进一步加工(包括煅烧)以生产用于核反应堆的石墨原木。

    PRODUCING COATED GRAPHITIC ANODE POWDERS BY EXTRACTING PITCH FROM HIGH VOLATILE MATTER COKE AND COATING THE SAME IN-SITU
    5.
    发明申请
    PRODUCING COATED GRAPHITIC ANODE POWDERS BY EXTRACTING PITCH FROM HIGH VOLATILE MATTER COKE AND COATING THE SAME IN-SITU 失效
    通过从高挥发性焦炭中提取沥青并涂覆相同的原位生产涂覆的青光眼的阳极粉末

    公开(公告)号:US20100183801A1

    公开(公告)日:2010-07-22

    申请号:US12355888

    申请日:2009-01-19

    Abstract: This invention relates to a process for making carbon coated graphitic anode powders for use in batteries including rechargeable lithium-ion batteries wherein the process includes a side product isotropic pitch for use as a precursor in other products and more preferably, as a coating material for other powder or particle products. The process includes the steps of solvent extraction of volatile materials from high volatile material green coke powder. When a desirable amount of the volatile materials have been extracted, the solvent strength is altered to cause some of the volatile materials to precipitate on the powder particles to coat the same. The coated and solvent-extracted particles are then separated from the solvent and oxidatively stabilized, then carbonized and preferably graphitized. The volatile materials remaining in the solvent are valuable and are recovered for use in other processes and other products.

    Abstract translation: 本发明涉及一种制备用于包括可再充电锂离子电池的电池的碳涂覆石墨阳极粉末的方法,其中该方法包括用作其它产品中的前体的副产物各向同性沥青,更优选地,作为其它产品的涂料 粉末或颗粒产品。 该方法包括从高挥发性物质绿色焦炭粉中溶剂萃取挥发性物质的步骤。 当提取出所需量的挥发性物质时,改变溶剂强度以使一些挥发性物质沉淀在粉末颗粒上以涂覆其上。 然后将涂覆和溶剂萃取的颗粒与溶剂分离并氧化稳定,然后碳化并优选石墨化。 残留在溶剂中的挥发性物质是有价值的并被回收用于其它工艺和其它产品。

    Method for producing lithium vanadium polyanion powders for batteries
    7.
    发明申请
    Method for producing lithium vanadium polyanion powders for batteries 审中-公开
    电池用锂钒聚阴离子粉末的制造方法

    公开(公告)号:US20080305256A1

    公开(公告)日:2008-12-11

    申请号:US12024038

    申请日:2008-01-31

    CPC classification number: H01M4/5825 C01B25/45

    Abstract: This invention relates to a process for producing an improved cathode powder for making lithium ion batteries wherein the powder comprises lithium, vanadium and a polyanion. The process includes forming a solution-suspension of the precursors, which include vanadium pentoxide, with a reducing agent, a solvent, and a carbon-residue-forming material. The reducing agent causes the vanadium in vanadium pentoxide to reduce from V5+ to V3+. The solution-suspension is heated in an inert environment to drive the synthesis of the LVP (Li3V2(PO4)3) such that the carbon-residue-forming material is also oxidized to precipitate in and on the LVP forming carbon-containing LVP or CCLVP. The liquids are separated from the solids and the dry powder is heated to a second higher temperature to drive the crystallization of the product. The resulting product retains a small particle size, includes carbon in the LVP for conductivity and is created with very low cost precursors and avoids the need for milling or other processing to reduce the product to a particle size suitable for use in batteries. It also does not require the addition of carbon black, graphite or other form of carbon to provide the conductivity required for use in batteries.

    Abstract translation: 本发明涉及一种制备用于制备锂离子电池的改进的阴极粉末的方法,其中该粉末包括锂,钒和聚阴离子。 该方法包括形成包含五氧化二钒的前体与还原剂,溶剂和形成碳残留物的溶液的悬浮液。 还原剂使五氧化二钒中的钒从V5 +降低至V3 +。 将溶液 - 悬浮液在惰性环境中加热以驱动LVP(Li 3 V 2(PO 4)3)的合成),使得碳残留物形成材料也被氧化沉淀在LVP形成含碳的LVP或CCLVP中 。 将液体与固体分离,将干燥粉末加热至第二较高温度以驱使产物结晶。 所得到的产品保持小的粒度,包括LVP中的导电性碳,并且以非常低成本的前体产生,并且避免需要研磨或其它加工以将产品降低至适合用于电池的粒度。 它也不需要添加炭黑,石墨或其他形式的碳,以提供用于电池所需的电导率。

    Producing coated graphitic anode powders by extracting pitch from high volatile matter coke and coating the same in-situ
    9.
    发明授权
    Producing coated graphitic anode powders by extracting pitch from high volatile matter coke and coating the same in-situ 失效
    通过从高挥发物焦炭中提取沥青并原位涂覆石墨生成阳极粉末涂层

    公开(公告)号:US07964240B2

    公开(公告)日:2011-06-21

    申请号:US12355888

    申请日:2009-01-19

    Abstract: This invention relates to a process for making carbon coated graphitic anode powders for use in batteries including rechargeable lithium-ion batteries wherein the process includes a side product isotropic pitch for use as a precursor in other products and more preferably, as a coating material for other powder or particle products. The process includes the steps of solvent extraction of volatile materials from high volatile material green coke powder. When a desirable amount of the volatile materials have been extracted, the solvent strength is altered to cause some of the volatile materials to precipitate on the powder particles to coat the same. The coated and solvent-extracted particles are then separated from the solvent and oxidatively stabilized, then carbonized and preferably graphitized. The volatile materials remaining in the solvent are valuable and are recovered for use in other processes and other products.

    Abstract translation: 本发明涉及一种制备用于包括可再充电锂离子电池的电池的碳涂覆石墨阳极粉末的方法,其中该方法包括用作其它产品中的前体的副产物各向同性沥青,更优选地,作为其它产品的涂料 粉末或颗粒产品。 该方法包括从高挥发性物质绿色焦炭粉中溶剂萃取挥发性物质的步骤。 当提取出所需量的挥发性物质时,改变溶剂强度以使一些挥发性物质沉淀在粉末颗粒上以涂覆其上。 然后将涂覆和溶剂萃取的颗粒与溶剂分离并氧化稳定,然后碳化并优选石墨化。 残留在溶剂中的挥发性物质是有价值的并被回收用于其它工艺和其它产品。

    METHODS OF PREPARING CARBONACEOUS ANODE MATERIALS AND USING SAME
    10.
    发明申请
    METHODS OF PREPARING CARBONACEOUS ANODE MATERIALS AND USING SAME 有权
    制备碳阳极材料并使用其的方法

    公开(公告)号:US20070286792A1

    公开(公告)日:2007-12-13

    申请号:US11422824

    申请日:2006-06-07

    CPC classification number: H01M4/587 C01B32/20 H01M10/052

    Abstract: A method for the production of carbon particles comprising selecting a precursor material, sizing said precursor material, stabilizing said precursor material, carbonizing said precursor material, and graphitizing said precursor material, wherein the precursor material has a volatile matter content of from about 5 wt. % to about 60 wt. %. A method for the production of electrode materials comprising selecting a precursor material, sizing said precursor material, stabilizing said precursor material, carbonizing said precursor material, and graphitizing said precursor material, wherein said electrode material has an average particle size of from about 1 μm to about 50 μm, a fixed carbon content of greater than about 80 wt. %, and a graphitic. structure. A carbon particle having an average particle size of from about 1 μm to about 50 μm, a degree of stabilization of from about 0.1 wt. % to about 10 wt. %, a fixed carbon content of greater than about 80 wt. %, and a graphitic structure.

    Abstract translation: 一种用于生产碳颗粒的方法,包括选择前体材料,调整所述前体材料的尺寸,稳定所述前体材料,碳化所述前体材料,以及石墨化所述前体材料,其中所述前体材料的挥发物含量为约5wt。 %至约60wt。 %。 一种用于生产电极材料的方法,包括选择前体材料,调整所述前体材料的尺寸,稳定所述前体材料,碳化所述前体材料,并石墨化所述前体材料,其中所述电极材料的平均粒度为约1μm至 约50μm,固定碳含量大于约80wt。 %,和石墨。 结构体。 平均粒度为约1〜50μm的碳粒子,稳定度为约0.1重量% %至约10wt。 %,固定碳含量大于约80wt。 %,和石墨结构。

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