公开(公告)号：US20190023640A1

公开(公告)日：2019-01-24

申请号：US16141501

申请日：2018-09-25

申请人： SAUDI BASIC INDUSTRIES CORPORATION

发明人： Khalid Karim ,  Labeeb Chaudhary Ahmed

IPC分类号： C07C51/225 ,  C07C51/215 ,  C07C51/25 ,  B01J37/03 ,  B01J27/051 ,  B01J27/057 ,  B01J23/889 ,  B01J27/187 ,  C07C1/04 ,  C07C57/04 ,  C07C53/08

CPC分类号： C07C51/225 ,  B01J23/8892 ,  B01J27/0515 ,  B01J27/0576 ,  B01J27/187 ,  B01J37/035 ,  C07C1/0435 ,  C07C1/0485 ,  C07C51/215 ,  C07C51/252 ,  C07C2523/889 ,  C07C2527/187 ,  C07C57/04 ,  C07C53/08

摘要： The method disclosed herein relates to two stage catalytic processes for converting syngas to acetic acid, acrylic acid and/or propylene. More specifically, the method described and claimed herein relate to a method of producing acrylic acid and acetic acid comprising the steps of: a) providing a feedstream comprising syngas; b) contacting the feedstream with a first catalyst to produce a first product stream comprising C2-C3 olefins and/or C2-C3 paraffins; and c) contacting the first product stream with oxygen gas and a second catalyst, thereby producing a second product stream comprising acrylic acid and acetic acid, wherein there is no step for separating the components of the first product stream before the first product stream is contacted with the second catalyst.

公开(公告)号：US20180353943A1

公开(公告)日：2018-12-13

申请号：US15562352

申请日：2016-03-25

申请人： Porocel International, LLC

发明人： James Dallas Seamans ,  Evonne Koh

IPC分类号： B01J27/051 ,  B01J37/20 ,  C10G45/08 ,  C10G47/06 ,  C10G3/00

CPC分类号： B01J27/0515 ,  B01J23/882 ,  B01J23/883 ,  B01J23/94 ,  B01J37/20 ,  C10G3/46 ,  C10G3/50 ,  C10G45/04 ,  C10G45/08 ,  C10G47/06 ,  C10G2300/202

摘要： A system and method of presulfurizing a catalyst. The presulfurizing of the catalyst includes contacting the catalyst with elemental sulfur, an olefin, and a triglyceride to form a mixture, and heating the mixture to give a presulfurized catalyst.

公开(公告)号：US09975112B2

公开(公告)日：2018-05-22

申请号：US14969747

申请日：2015-12-15

申请人： ENI S.p.A.

发明人： Giuseppe Bellussi ,  Angela Carati ,  Maria Federica Gagliardi ,  Stefano Zanardi ,  Marcello Marella ,  Roberto Scattolin ,  Michele Tomaselli

IPC分类号： B01J31/00 ,  B01J23/00 ,  B01J27/051 ,  B01J27/049 ,  B01J35/10 ,  B01J37/03 ,  B01J37/20 ,  C10G45/08 ,  B01J23/883 ,  B01J23/888 ,  B01J21/00 ,  B01J25/00

CPC分类号： B01J27/0515 ,  B01J23/002 ,  B01J23/883 ,  B01J23/8885 ,  B01J27/049 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/033 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G2300/1044 ,  C10G2300/1062 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2400/04 ,  C10G2400/06 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/41

摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC  (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, O is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH  (I) wherein the groups RIRIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N  (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.

公开(公告)号：US09849446B2

公开(公告)日：2017-12-26

申请号：US15241185

申请日：2016-08-19

申请人： ExxonMobil Research and Engineering Company

发明人： John P. Greeley ,  Paul Podsiadlo ,  William Ernest Lewis ,  Roby Bearden, Jr. ,  Amitava Sarkar ,  Mainak Ghosh ,  Ramanathan Sundararaman ,  Thomas F. Degnan, Jr. ,  Manuel A. Francisco

IPC分类号： C10G45/04 ,  B01J27/051 ,  B01J37/20 ,  B01J23/881 ,  C10G47/06 ,  B01J37/18

CPC分类号： B01J27/0515 ,  B01J23/881 ,  B01J27/049 ,  B01J35/0006 ,  B01J37/04 ,  B01J37/18 ,  B01J37/20 ,  C10G45/04 ,  C10G47/06

摘要： Systems and methods are provided for slurry hydroconversion of a heavy oil feedstock, such as an atmospheric or vacuum resid, in the presence of an enhanced or promoted slurry hydroconversion catalyst system. The slurry hydroconversion catalyst system can be formed from a) a Group VIII non-noble metal catalyst precursor/concentrate (such as an iron-based catalyst precursor/concentrate) and b) a Group VI metal catalyst precursor/concentrate (such as a molybdenum-based catalyst precursor/concentrate) and/or a Group VI metal sulfided catalyst.

公开(公告)号：US09731283B2

公开(公告)日：2017-08-15

申请号：US15243007

申请日：2016-08-22

申请人： ExxonMobil Research and Engineering Company

发明人： Majosefina Cunningham ,  Jason M. Golias ,  Chuansheng Bai

IPC分类号： B01J31/02 ,  B01J31/34 ,  B01J31/06 ,  B01J35/10 ,  C10G45/08 ,  B01J37/08 ,  B01J23/882 ,  B01J23/883 ,  B01J31/04 ,  B01J31/12

CPC分类号： B01J31/34 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J27/049 ,  B01J27/0515 ,  B01J31/04 ,  B01J31/069 ,  B01J31/124 ,  B01J35/002 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0018 ,  B01J37/084 ,  B01J37/086 ,  B01J37/20 ,  C10G45/08

摘要： Bulk metallic catalyst precursor compositions are provided that include a Group VIB metal, a Group VIII metal, an organic-compound based component, and an organo-metalloxane polymer or gel. The catalyst precursor compositions can further include a binder. Amorphous sulfided catalysts formed from the catalyst precursor compositions are also provided. The catalyst precursor compositions can have a surface area of about 20 m2/g or less.

公开(公告)号：US20170080410A1

公开(公告)日：2017-03-23

申请号：US15243007

申请日：2016-08-22

申请人： ExxonMobil Research and Engineering Company

发明人： Majosefina CUNNINGHAM ,  Jason M. GOLIAS ,  Chuansheng BAI

IPC分类号： B01J31/34 ,  B01J35/10 ,  C10G45/08 ,  B01J31/06

CPC分类号： B01J31/34 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J27/049 ,  B01J27/0515 ,  B01J31/04 ,  B01J31/069 ,  B01J31/124 ,  B01J35/002 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0018 ,  B01J37/084 ,  B01J37/086 ,  B01J37/20 ,  C10G45/08

摘要： Bulk metallic catalyst precursor compositions are provided that include a Group VIB metal, a Group VIII metal, an organic-compound based component, and an organo-metalloxane polymer or gel. The catalyst precursor compositions can further include a binder. Amorphous sulfided catalysts formed from the catalyst precursor compositions are also provided. The catalyst precursor compositions can have a surface area of about 20 m2/g or less.

公开(公告)号：US09573118B2

公开(公告)日：2017-02-21

申请号：US14441155

申请日：2013-11-08

申请人： STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

发明人： Michele Colozzi ,  Lucia Barbato ,  Fabio Angelini ,  Emma Palo ,  Vincenzo Palma ,  Vincenzo Vaiano

IPC分类号： B01J27/051 ,  B01J35/08 ,  B01J37/08 ,  C01B3/04 ,  B01J37/20 ,  B01J37/02 ,  B01J23/881 ,  C01B17/04

CPC分类号： B01J27/0515 ,  B01J23/881 ,  B01J35/08 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/0215 ,  B01J37/08 ,  B01J37/20 ,  C01B3/04 ,  C01B17/046 ,  C01B17/0465 ,  C01B17/0495 ,  Y02E60/364

摘要： Disclosed is a catalyst suitable for the catalytic oxidative cracking of a H2S-containing gas stream, particularly in the event that the stream also contains methane and/or ammonia. The catalyst comprises iron and molybdenum supported by a carrier comprising aluminum. The carrier preferably is alumina. The iron and molybdenum preferably are in the form of sulphides. Also disclosed is a method for the production of hydrogen from a H2S-containing gas stream, comprising subjecting the gas stream to catalytic oxidative cracking so as to form H2 and S2, using a catalyst in accordance with any one of the preceding claims.

摘要翻译： 公开了一种适用于含H2S的气流的催化氧化裂解的催化剂，特别是在流还含有甲烷和/或氨的情况下。 催化剂包括由包含铝的载体负载的铁和钼。 载体优选为氧化铝。 铁和钼优选为硫化物的形式。 还公开了一种用于从含H 2 S的气流生产氢的方法，包括使用根据前述权利要求中任一项的催化剂使气流进行催化氧化裂化以形成H 2和S 2。

公开(公告)号：US09545621B2

公开(公告)日：2017-01-17

申请号：US14717107

申请日：2015-05-20

申请人： Neste Oil Oyj

发明人： Mika Kettunen ,  Jukka Myllyoja ,  Rami Piilola ,  Goran Sandstrom ,  Pekka Aalto

IPC分类号： C07C45/41 ,  B01J23/00 ,  B01J27/051 ,  C11C3/12 ,  C10L1/04 ,  C10G3/00 ,  B01J35/00 ,  B01J23/04 ,  B01J23/883 ,  C11C1/00 ,  C07C1/24 ,  C07C45/54 ,  C10M105/24 ,  B01D3/00 ,  B01J23/887 ,  C07C1/22 ,  C07C5/27 ,  C10M105/04 ,  C10M177/00 ,  B01J37/20 ,  B01J21/06

CPC分类号： B01J27/0515 ,  B01D3/009 ,  B01J21/063 ,  B01J23/04 ,  B01J23/883 ,  B01J23/8872 ,  B01J35/0006 ,  B01J37/20 ,  C07C1/22 ,  C07C1/24 ,  C07C5/2735 ,  C07C5/2737 ,  C07C45/41 ,  C07C45/54 ,  C07C2523/16 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C10G3/42 ,  C10G3/44 ,  C10G3/45 ,  C10G3/46 ,  C10L1/04 ,  C10L2200/0484 ,  C10M105/04 ,  C10M105/24 ,  C10M177/00 ,  C11C1/005 ,  C11C3/123 ,  Y02P30/20

摘要： The present invention provides a method for simultaneous production of components suitable for production of base oil and fuel components. In the method a feedstock comprising fatty acids and/or fatty acid esters is entered into a reaction zone and subjected to a ketonization reaction in the presence of a dual catalyst system. This system is configured to perform a ketonization reaction and a hydrotreatment reaction, under hydrogen pressure. Subsequently ketones are obtained.

摘要翻译： 本发明提供了一种用于同时生产适用于生产基础油和燃料组分的组分的方法。 在该方法中，包含脂肪酸和/或脂肪酸酯的原料进入反应区并在双重催化剂体系的存在下进行酮化反应。 该系统配置为在氢气压力下进行酮化反应和加氢处理反应。 随后得到酮。

公开(公告)号：US09327274B2

公开(公告)日：2016-05-03

申请号：US14019319

申请日：2013-09-05

申请人： Jinyi Han ,  Alexander E. Kuperman

发明人： Jinyi Han ,  Alexander E. Kuperman

IPC分类号： B01J27/051 ,  B01J27/049 ,  B01J27/043 ,  B01J27/047 ,  B01J35/00 ,  B01J35/10

CPC分类号： B01J27/0515 ,  B01J27/043 ,  B01J27/047 ,  B01J27/049 ,  B01J27/051 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1038 ,  C10G45/08

摘要： The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The self-supported MMS catalyst contains Ni:W in a mole ratio of 1:3 to 4:1, on a transition metal basis. The self supported MMS catalyst is characterized as having an HYD reaction rate constant of at least 15% higher than that of a catalyst comprising nickel sulfide alone or a catalyst comprising tungsten sulfide alone, when compared on same metal molar basis in hydrotreating of benzene as a feedstock at identical process conditions.

摘要翻译： 本发明涉及一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂及其制备方法。 自支撑的MMS催化剂以过渡金属为基础，含有摩尔比为1:3至4:1的Ni:W。 自支撑的MMS催化剂的特征在于，与单独的硫化镍或仅含硫化钨的催化剂相比，HYD反应速率常数比单独的硫化镍催化剂高至少15％，当与 原料在相同的工艺条件下。

公开(公告)号：US20150291420A1

公开(公告)日：2015-10-15

申请号：US14441162

申请日：2013-11-08

申请人： STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER

发明人： Michele COLOZZI ,  Lucia BARBATO ,  Fabio ANGELINI ,  Emma PALO ,  Vincenzo PALMA ,  Vincenzo VAIANO

IPC分类号： C01B3/04 ,  B01J27/051 ,  B01J21/04

CPC分类号： C01B3/04 ,  B01J21/04 ,  B01J27/0515 ,  C01B3/047 ,  Y02E60/364

摘要： Disclosed is a method for the production of hydrogen from a H2S-containing gas stream also containing ammonia, comprising subjecting both gas stream to catalytic oxidative cracking of both the H2S and the NH3, so as to form H2, S2 and N2. In this method, preferably, an additional amount of oxygen is added as compared to the amount used for H2S catalytic oxidative cracking. Also, preferably, the contact time of the gas stream with the catalyst is increased. The catalyst preferably is provided as a single bed, and then preferably comprises iron and molybdenum supported by a carrier comprising aluminum. The preferred carrier is alumina. The iron and molybdenum preferably are in the form of sulfides.

摘要翻译： 公开了一种从含有氨的含H2S的气体流中生产氢气的方法，包括使两种气流同时进行H2S和NH3两者的催化氧化裂解，以形成H2，S2和N2。 在该方法中，与用于H 2 S催化氧化裂化的量相比，优选加入附加量的氧。 此外，优选地，气流与催化剂的接触时间增加。 催化剂优选以单一床提供，然后优选包含由包含铝的载体担载的铁和钼。 优选的载体是氧化铝。 铁和钼优选为硫化物的形式。