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公开(公告)号：US5264612A
公开(公告)日：1993-11-23
申请号：US952118
申请日：1992-09-28
申请人： Eric J. Evain , Krishna Raman
发明人： Eric J. Evain , Krishna Raman
IPC分类号： B01J23/02 , B01J31/02 , B01J31/12 , C07B61/00 , C07C67/347 , C07C69/732 , C07C69/76
CPC分类号： C07C67/347
摘要： Disclosed is a process for the preparation of aryl-substituted propionic acid esters having the formula: ##STR1## wherein R and R.sup.1 are a C.sub.1 -C.sub.12 linear or branched alkyl, a C.sub.5 -C.sub.12 cycloalkyl, a C.sub.6 -C.sub.12 aryl or a C.sub.7 -C.sub.12 alkaryl or aralkyl, R.sup.2 is hydrogen or a C.sub.1 -C.sub.20 linear or branched alkyl and R.sup.3 is a C.sub.1 -C.sub.20 linear or branched alkyl, a C.sub.5 -C.sub.12 cycloalkyl, a C.sub.6 -C.sub.12 aryl or a C.sub.7 -C.sub.20 alkaryl or aralkyl, and may be the same or different, or R.sup.1 is hydrogen, which comprises forming a reaction mixture of a phenol, at least one base catalyst and an acrylate, in the presence of 1,2-dimethoxybenzene, wherein the acrylate is added at once or over a period of time from 5 to 60 minutes at atmospheric pressure. The process results in excellent yields of the desired product with good rates of conversion.
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公开(公告)号：US5702815A
公开(公告)日：1997-12-30
申请号：US811307
申请日：1997-03-04
申请人： Eric J. Evain
发明人： Eric J. Evain
CPC分类号： D01D10/00 , D01F6/06 , Y10T428/29 , Y10T428/2913
摘要： A process for preparing thermal bondable fibers including exposing molten fiber grade polymer to electromagnetic radiation at the one or more orifices of the spinneret and the upper portion of the spin line, and the fibers prepared therefrom.
摘要翻译： 一种制备热可粘合纤维的方法，包括将熔融纤维级聚合物暴露于喷丝头的一个或多个孔和纺丝线的上部的电磁辐射，以及由其制备的纤维。
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3.发明授权Water clarification using compositions containing a water clarifier component and a floc modifier component 失效使用含有水澄清剂组分和絮凝剂改性剂组分的组合物进行水净化
公开(公告)号：US5302296A
公开(公告)日：1994-04-12
申请号：US20760
申请日：1993-02-22
IPC分类号： C02F1/54
CPC分类号： C02F1/54
摘要： Materials such as amines, alcohols, aminoalcohols, ethers and mixtures thereof, including halogenated adducts thereof, have been found to be useful floc modifiers for water clarifiers to form an effective overall water clarifier composition. The water clarifier portion of the composition is a dithiocarbamate. The floc modifier of a particular water clarifier composition need not be the same compound that is reacted with carbon disulfide (CS.sub.2) to make the water clarifier portion of the novel compositions.
摘要翻译： 已经发现，诸如胺，醇，氨基醇，醚及其混合物，包括其卤代加合物的材料是用于水净化器的有用的絮凝剂改性剂，以形成有效的整体水净化器组合物。 组合物的净水器部分是二硫代氨基甲酸盐。 特定水净化器组合物的絮凝剂改性剂不必是与二硫化碳（CS2）反应以制备新组合物的水净化器部分的相同化合物。
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4.发明授权Alpha-olefin polymerization catalyst system which contains an aromatic silane compound 失效含有芳族硅烷化合物的α-烯烃聚合催化剂体系公开(公告)号：US07009015B2
公开(公告)日：2006-03-07
申请号：US09742868
申请日：2000-12-21
IPC分类号： C08F2/00
CPC分类号： C08F297/083 , C07F7/1804 , C08F10/00 , C08F297/08 , C08F4/6465
摘要： Aromatic silane compounds containing at least an aromatic ring bound directly to the silicon atom, wherein the aromatic ring has at least one substituent located in the ortho position selected from C1-10 hydrocarbon groups, are useful as electron donors in olefin polymerization catalysts for the production of polyolefins having a stereoblock content of from about 7 to about 25%.
摘要翻译： 至少含有与硅原子键合的至少一个芳环的芳族硅烷化合物，其中芳环具有位于选自C 1-10 1-10烃基的邻位的至少一个取代基，可用作电子 用于生产立体嵌段含量为约7至约25％的聚烯烃的烯烃聚合催化剂中的供体。
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5.发明授权Catalyst for the polymerization of alpha-olefins containing substituted amino silane compounds 失效用于含有取代氨基硅烷化合物的α-烯烃聚合的催化剂
公开(公告)号：US6130180A
公开(公告)日：2000-10-10
申请号：US996854
申请日：1997-12-23
IPC分类号： C07F7/18 , C08F4/606 , C08F4/642 , C08F4/646 , C08F4/654 , C08F10/00 , B01J31/00 , C08F4/656
摘要： An aminosilane of the formula: ##STR1## where R.sub.1 is a linear or branched C.sub.1-22 alkyl or C.sub.3-22 cycloalkyl, which may be substituted with at least one halogen atom; R.sub.2 is a bis(linear or branched C.sub.1-22 alkyl or C.sub.3-22 cycloalkyl)amino, a substituted piperidinyl, a substituted pyrrolidinyl, decahydroquinolinyl, 1,2,3,4-tetrahydroquinolinyl or 1,2,3,4-tetrahydroisoquinolinyl, with the substituent selected from the group consisting of C.sub.1-8 alkyl, pheny. C.sub.1-8 linear or branched alkylsubstituted phenyl and trimethylsilyl, with the proviso that when the substituent is C.sub.1-8 alkyl, there must be at least two such substituent groups present and R.sub.1 must contain halogen; and R.sub.3 is a linear or branched C.sub.1-8 alkyl or C.sub.3-8 cycloalkyl. The aminosilane may be reacted with an aluminum-alkyl compound and a solid component comprising a titanium compound having at least one titanium-halogen bond and an electron donor, both supported on an activated anhydrous magnesium dihalide, to form a catalyst for polymerization of olefins.
摘要翻译： 下式的氨基硅烷：其中R 1是可被至少一个卤素原子取代的直链或支链C 1-22烷基或C 3-20环烷基; R2是双（直链或支链C 1-22烷基或C 3--22环烷基）氨基，取代的哌啶基，取代的吡咯烷基，十氢喹啉基，1,2,3,4-四氢喹啉基或1,2,3,4-四氢异喹啉基， 与选自C 1-8烷基，苯基的取代基取代。 C 1-8直链或支链烷基取代的苯基和三甲基甲硅烷基，条件是当取代基为C 1-8烷基时，必须存在至少两个这样的取代基，R1必须含有卤素; 并且R 3是直链或支链C 1-8烷基或C 3-8环烷基。 氨基硅烷可以与铝 - 烷基化合物和包含具有至少一个钛 - 卤素键的钛化合物和电子给体的固体组分反应，两者都负载在活性无水二卤化镁上，形成烯烃聚合催化剂。
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公开(公告)号：US5507997A
公开(公告)日：1996-04-16
申请号：US331319
申请日：1994-10-28
申请人： Eric J. Evain
发明人： Eric J. Evain
CPC分类号： D01D10/00 , D01F6/06 , Y10T428/29 , Y10T428/2913
摘要： A process for preparing thermal bondable fibers including exposing molten fiber grade polymer to electromagnetic radiation at the one or more orifices of the spinneret and the upper portion of the spin line, and the fibers prepared therefrom.
摘要翻译： 一种制备热可粘合纤维的方法，包括将熔融纤维级聚合物暴露于喷丝头的一个或多个孔和纺丝线的上部的电磁辐射，以及由其制备的纤维。
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7.发明授权Water clarification composition containing a water clarifier component and a floc modifier component 失效水澄清组合物含有水澄清剂组分和絮体改性剂组分
公开(公告)号：US5190683A
公开(公告)日：1993-03-02
申请号：US540048
申请日：1990-06-19
IPC分类号： C02F1/54
CPC分类号： C02F1/54
摘要： Materials such as amines, alcohols, aminoalcohols, ethers and mixtures thereof, including halogenated adducts thereof, have been found to be useful floc modifiers for water clarifiers to form an effective overall water clarifier composition. The water clarifier portion of the composition is a dithiocarbamate. The floc modifier of a particular water clarifier composition need not be the same compound that is reacted with carbon disulfide (CS.sub.2) to make the water clarifier portion of the novel compositions.
摘要翻译： 已经发现，诸如胺，醇，氨基醇，醚及其混合物，包括其卤代加合物的材料是用于水净化器的有用的絮凝剂改性剂，以形成有效的整体水净化器组合物。 组合物的净水器部分是二硫代氨基甲酸盐。 特定水净化器组合物的絮凝剂改性剂不必是与二硫化碳（CS2）反应以制备新组合物的水净化器部分的相同化合物。
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8.发明授权Alpha-olefin polymerization catalyst system which contains an aromatic silane compound 失效含有芳族硅烷化合物的α-烯烃聚合催化剂体系公开(公告)号：US06723865B2
公开(公告)日：2004-04-20
申请号：US10116445
申请日：2002-04-04
IPC分类号： C07F704
CPC分类号： C08F297/083 , C07F7/1804 , C08F10/00 , C08F297/08 , C08F4/6465
摘要： Aromatic silane compounds containing at least an aromatic ring bound directly to the silicon atom, wherein the aromatic ring has at least one substituent located in the ortho position selected from C1-10 hydrocarbon groups, are useful as electron donors in olefin polymerization catalysts for the production of polyolefins having a stereoblock content of from about 7 to about 25%.
摘要翻译： 至少含有直接与硅原子结合的芳环的芳族硅烷化合物，其中芳环具有位于选自C1-10烃基的邻位的至少一个取代基，可用作用于生产的烯烃聚合催化剂中的电子给体 的立构嵌段含量为约7至约25％的聚烯烃。
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