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    Process for the preparation of porous polymers and polymers obtainable thereof
    3.
    发明授权
    Process for the preparation of porous polymers and polymers obtainable thereof 失效
    制备可获得的多孔聚合物和聚合物的方法

    公开(公告)号：US07183332B2

    公开(公告)日：2007-02-27

    申请号：US10450603

    申请日：2001-12-21

    申请人： Angelo Ferraro ,  Giovanni Baruzzi ,  Constantine A. Stewart ,  Ofelia Fusco

    发明人： Angelo Ferraro ,  Giovanni Baruzzi ,  Constantine A. Stewart ,  Ofelia Fusco

    IPC分类号： C08F10/06 ,  C08F4/02 ,  C08L23/10

    CPC分类号： C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/027 ,  C08F2/001 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/24

    摘要： A process for preparing porous olefin polymers comprising bringing into contact in a polymerization reactor, at a temperature T1, one or more olefins of the formula (I) CH2═CHR1, R1 being hydrogen, a C1–C20-alkyl or a C6–C12-aryl group, with a catalyst obtained by reacting a solid catalyst component in the form of spheroidal particles comprising a compound of Ti or V not containing metal-π bonds and a Mg halide, optionally containing one or more electron donor compounds, with an aluminum-alkyl (Al-alkyl) compound, then raising the temperature up to the polymerization temperature, said process being characterized in that: a) if the temperature T1 is lower than 40° C., the temperature is raised up to the polymerization temperature is such a way that, for a time of at least one minute after the introduction temperature in such a way that, for a time of at least one minute after the introduction of the catalyst system into the reactor, the temperature of the reaction T2 fulfills the following condition of formula (II) wherein m is the time expressed in minutes employed for reaching the temperature T2; or b) if temperature T1 is 40° C. or higher, the reactor is maintained for a time of at least one minute at a temperature of at least 40° C.

    摘要翻译： 一种制备多孔烯烃聚合物的方法，包括在聚合反应器中，在温度T 1下接触一种或多种式（I）CH 2 -CHR的烯烃 R 1是氢，C 1 -C 20 - 烷基或C 6 - 与通过使包含不含金属-Ip键的Ti或V的化合物的球形颗粒形式的固体催化剂组分与Mg的反应获得的催化剂与Mg 卤化物，任选地含有一个或多个电子给体化合物与烷基铝（Al-烷基）化合物，然后将温度升高到聚合温度，所述方法的特征在于：a）如果温度T 1 低于40℃，温度升高到聚合温度是这样一种方式，使得在引入温度之后至少1分钟的时间，使得在 在介绍后至少一分钟 催化剂体系进入反应器中，反应温度T 2满足以下条件（II），其中m是达到温度T 2的分钟所用的时间 ; 或b）如果温度T≥0.4℃或更高，则反应器在至少40℃的温度下保持至少1分钟的时间。

    Alpha-olefin polymerization catalyst system which contains an aromatic silane compound
    4.
    发明授权
    Alpha-olefin polymerization catalyst system which contains an aromatic silane compound 失效
    含有芳族硅烷化合物的α-烯烃聚合催化剂体系

    公开(公告)号：US06723865B2

    公开(公告)日：2004-04-20

    申请号：US10116445

    申请日：2002-04-04

    申请人： Eric J. Evain ,  Constantine A. Stewart

    发明人： Eric J. Evain ,  Constantine A. Stewart

    IPC分类号： C07F704

    CPC分类号： C08F297/083 ,  C07F7/1804 ,  C08F10/00 ,  C08F297/08 ,  C08F4/6465

    摘要： Aromatic silane compounds containing at least an aromatic ring bound directly to the silicon atom, wherein the aromatic ring has at least one substituent located in the ortho position selected from C1-10 hydrocarbon groups, are useful as electron donors in olefin polymerization catalysts for the production of polyolefins having a stereoblock content of from about 7 to about 25%.

    摘要翻译： 至少含有直接与硅原子结合的芳环的芳族硅烷化合物，其中芳环具有位于选自C1-10烃基的邻位的至少一个取代基，可用作用于生产的烯烃聚合催化剂中的电子给体 的立构嵌段含量为约7至约25％的聚烯烃。

    Organosilane compounds
    6.
    发明授权
    Organosilane compounds 失效
    有机硅烷化合物

    公开(公告)号：US6165930A

    公开(公告)日：2000-12-26

    申请号：US934885

    申请日：1992-08-24

    申请人： Constantine A. Stewart

    发明人： Constantine A. Stewart

    IPC分类号： C07F7/18 ,  C08F4/656 ,  C08F10/00 ,  C08F110/06 ,  C07F7/02 ,  C07F7/10 ,  C07F4/16

    CPC分类号： C08F10/00 ,  C07F7/1804 ,  C08F110/06 ,  C08F4/6465 ,  C08F2500/17

    摘要： Organosilane compounds having the structural formula ##STR1## wherein R is a linear or branched C.sub.1-4 alkyl, 4-methylpiperidyl, C.sub.6-12 aryl or C.sub.5-7 cycloalkyl; R.sup.1 is hydrogen, methyl or ethyl, R.sup.2 is methyl or ethyl and; n is 4 to 7.These organosilane compounds are useful as electron donors in Ziegler-Natta type catalyst systems.

    摘要翻译： 具有以下结构式的有机硅烷化合物其中R是直链或支链C 1-4烷基，4-甲基哌啶基，C 6-12芳基或C 5-7环烷​​基; R1是氢，甲基或乙基，R2是甲基或乙基; n为4至7.这些有机硅烷化合物可用作齐格勒 - 纳塔型催化剂体系中的电子给体。

    Alpha-olefin polymerization catalyst system which contains an aromatic silane compound
    7.
    发明授权
    Alpha-olefin polymerization catalyst system which contains an aromatic silane compound 失效
    含有芳族硅烷化合物的α-烯烃聚合催化剂体系

    公开(公告)号：US07009015B2

    公开(公告)日：2006-03-07

    申请号：US09742868

    申请日：2000-12-21

    申请人： Eric J. Evain ,  Constantine A. Stewart

    发明人： Eric J. Evain ,  Constantine A. Stewart

    IPC分类号： C08F2/00

    CPC分类号： C08F297/083 ,  C07F7/1804 ,  C08F10/00 ,  C08F297/08 ,  C08F4/6465

    摘要： Aromatic silane compounds containing at least an aromatic ring bound directly to the silicon atom, wherein the aromatic ring has at least one substituent located in the ortho position selected from C1-10 hydrocarbon groups, are useful as electron donors in olefin polymerization catalysts for the production of polyolefins having a stereoblock content of from about 7 to about 25%.

    摘要翻译： 至少含有与硅原子键合的至少一个芳环的芳族硅烷化合物，其中芳环具有位于选自C 1-10 1-10烃基的邻位的至少一个取代基，可用作电子 用于生产立体嵌段含量为约7至约25％的聚烯烃的烯烃聚合催化剂中的供体。

    Catalyst for the polymerization of alpha-olefins containing substituted amino silane compounds
    8.
    发明授权
    Catalyst for the polymerization of alpha-olefins containing substituted amino silane compounds 失效
    用于含有取代氨基硅烷化合物的α-烯烃聚合的催化剂

    公开(公告)号：US6130180A

    公开(公告)日：2000-10-10

    申请号：US996854

    申请日：1997-12-23

    申请人： Constantine A. Stewart ,  Eric J. Evain

    发明人： Constantine A. Stewart ,  Eric J. Evain

    IPC分类号： C07F7/18 ,  C08F4/606 ,  C08F4/642 ,  C08F4/646 ,  C08F4/654 ,  C08F10/00 ,  B01J31/00 ,  C08F4/656

    CPC分类号： C07F7/184 ,  C08F10/00

    摘要： An aminosilane of the formula: ##STR1## where R.sub.1 is a linear or branched C.sub.1-22 alkyl or C.sub.3-22 cycloalkyl, which may be substituted with at least one halogen atom; R.sub.2 is a bis(linear or branched C.sub.1-22 alkyl or C.sub.3-22 cycloalkyl)amino, a substituted piperidinyl, a substituted pyrrolidinyl, decahydroquinolinyl, 1,2,3,4-tetrahydroquinolinyl or 1,2,3,4-tetrahydroisoquinolinyl, with the substituent selected from the group consisting of C.sub.1-8 alkyl, pheny. C.sub.1-8 linear or branched alkylsubstituted phenyl and trimethylsilyl, with the proviso that when the substituent is C.sub.1-8 alkyl, there must be at least two such substituent groups present and R.sub.1 must contain halogen; and R.sub.3 is a linear or branched C.sub.1-8 alkyl or C.sub.3-8 cycloalkyl. The aminosilane may be reacted with an aluminum-alkyl compound and a solid component comprising a titanium compound having at least one titanium-halogen bond and an electron donor, both supported on an activated anhydrous magnesium dihalide, to form a catalyst for polymerization of olefins.

    摘要翻译： 下式的氨基硅烷：其中R 1是可被至少一个卤素原子取代的直链或支链C 1-22烷基或C 3-20环烷基; R2是双（直链或支链C 1-22烷基或C 3--22环烷基）氨基，取代的哌啶基，取代的吡咯烷基，十氢喹啉基，1,2,3,4-四氢喹啉基或1,2,3,4-四氢异喹啉基， 与选自C 1-8烷基，苯基的取代基取代。 C 1-8直链或支链烷基取代的苯基和三甲基甲硅烷基，条件是当取代基为C 1-8烷基时，必须存在至少两个这样的取代基，R1必须含有卤素; 并且R 3是直链或支链C 1-8烷基或C 3-8环烷基。 氨基硅烷可以与铝 - 烷基化合物和包含具有至少一个钛 - 卤素键的钛化合物和电子给体的固体组分反应，两者都负载在活性无水二卤化镁上，形成烯烃聚合催化剂。