公开(公告)号：US20090123678A1

公开(公告)日：2009-05-14

申请号：US11663374

申请日：2005-09-26

申请人： Douglas E. Beyer ,  Steven R. Jenkins ,  Eric K.C. Lee

发明人： Douglas E. Beyer ,  Steven R. Jenkins ,  Eric K.C. Lee

IPC分类号： B32B1/00 ,  B29C47/00

CPC分类号： C08J5/18 ,  B29C55/28 ,  B29K2027/08 ,  B29K2033/04 ,  B29K2105/0038 ,  B29K2105/0085 ,  B29L2023/002 ,  C08J2327/08 ,  C08K5/0016 ,  Y10T428/1324 ,  Y10T428/1345 ,  Y10T428/1379 ,  Y10T428/1397 ,  C08L27/08

摘要： Articles comprise a monolayer blown film prepared from a composition comprising at least one vinylidene chloride polymer and at least one plasticizer wherein at least one vinylidene chloride polymer comprises vinylidene chloride and at least one alkyl acrylate, selected from methyl acrylate, ethyl acrylate, or butyl acrylate or a combination thereof in an amount of from 2.5 to 9 mole percent of the monomer content of the vinylidene chloride polymer and wherein the plasticizer is present in an amount of from 1 to 15 parts by weight per hundred parts of polymer, wherein the article is selected from a package, a container, a laminate, sausage casing or combination thereof, particularly a sausage casing, wherein at least 4 of designated characteristics are present. The invention also includes processes for making articles of the invention and films used therein.

摘要翻译： 制品包括由包含至少一种偏二氯乙烯聚合物和至少一种增塑剂的组合物制备的单层吹塑薄膜，其中至少一种偏二氯乙烯聚合物包含偏二氯乙烯和至少一种选自丙烯酸甲酯，丙烯酸乙酯或丙烯酸丁酯的丙烯酸烷基酯 或其组合，其量为偏二氯乙烯聚合物的单体含量的2.5至9摩尔％，并且其中增塑剂的存在量为每100份聚合物1至15重量份，其中制品为 选自包装，容器，层压体，香肠肠衣或其组合，特别是香肠肠衣，其中存在至少4个指定特征。 本发明还包括制造本发明的制品和其中使用的薄膜的方法。

公开(公告)号：US20080274245A1

公开(公告)日：2008-11-06

申请号：US11547486

申请日：2005-04-05

申请人： Eric K.C. Lee ,  John A. Naumovitz ,  Mladen Ladika

发明人： Eric K.C. Lee ,  John A. Naumovitz ,  Mladen Ladika

IPC分类号： B29C65/14 ,  B32B27/36 ,  B32B27/30 ,  B29C47/08 ,  B65D81/34 ,  B32B7/10 ,  B32B1/08

CPC分类号： B32B7/12 ,  B32B27/08 ,  B32B27/30 ,  B32B27/304 ,  B32B2310/0837 ,  B32B2439/00 ,  C08J5/12 ,  Y10T428/1307 ,  Y10T428/1321 ,  Y10T428/1352 ,  Y10T428/1362 ,  Y10T428/31616 ,  Y10T428/31667 ,  Y10T428/31681 ,  Y10T428/31797

摘要： The present invention includes a multicomponent structure comprising at least two components having a tie layer or adhesive layer directly between them, the tie layer comprising at least one olefin unsaturated ester copolymer and at least one photoinitiator and optionally a crosslinking enhancer. The tie layer is preferably irradiated with sufficient actinic radiation to result in increased interlayer adhesion strength between the two components as compared with the interlayer adhesion strength before treatment with the actinic radiation or between the components having a tie layer of the same composition except without the added photoinitiator or crosslinking enhancer. Without the photoinitiator, optionally crosslinking enhancer, and radiation the interlayer adhesion of the components is preferably less than 55 N/m. At least one of the components (first component or layer) preferably comprises a halopolymer, more preferably vinylidene chloride polymer, most preferably at least a majority of a vinyl idene chloride polymer. In another embodiment, at least one component exhibits interlayer adhesion strength similar to vinylidene chloride polymers. The structure optionally is or comprises such structures as a multilayer film, bag, or package, a lined or composite pipe, or other structure having more than one component. The tie layer is advantageously irradiated with an amount of UV light effective to increase the adhesion strength between the first and second components.

摘要翻译： 本发明包括多组分结构，其包含至少两个在其间直接连接层或粘合剂层的组分，所述粘结层包含至少一种烯烃不饱和酯共聚物和至少一种光引发剂和任选的交联增强剂。 与使用光化辐射处理之前的层间粘合强度或具有相同组成的粘结层的组分之间相比，接合层优选用足够的光化辐射照射以导致两组分之间的层间粘合强度增加，除了不添加 光引发剂或交联增强剂。 没有光引发剂，任选的交联增强剂和辐射，组分的层间粘附优选小于55N / m。 组分（第一组分或第一组分）中的至少一种优选包含卤代聚合物，更优选偏二氯乙烯聚合物，最优选氯乙烯基氯化聚合物的至少大部分。 在另一个实施方案中，至少一种组分显示类似于偏二氯乙烯聚合物的层间粘合强度。 该结构任选地或包括诸如多层膜，袋或包装，衬里或复合管或具有多于一种组分的其它结构的结构。 接合层有利地用一定量的UV光照射，以有效地增加第一和第二组分之间的粘合强度。