摘要:
A yttrium-silicate molecular sieve is disclosed which comprises a complex represented in terms of mole ratios of oxides as follows:aA.sub.2 O:Y.sub.2 O.sub.3 :bSiO.sub.2 :cH.sub.2 Owherein A is an alkali metal; a is a number ranging from about 0.5 to about 20; b is a number ranging from about 2 to about 400; and c is a number ranging from about 1 to about 500.
摘要:
A catalyst is disclosed which comprises a ruthenium-copper-containing complex of the formulaM.sub.a A.sub.b RuCu.sub.c N.sub.z O.sub.xwhereinM is selected from the group consisting of Ce, Cr, Fe, Mn, and mixtures thereof,A is an alkali metal, alkaline earth metal or mixture thereof,a is from 0 to about 1,b is from about 0.002 to about 10,c is from about 0.2 to about 20,z is from 0 to about 1% by weight,x is the number of oxygens needed to fulfill the valence requirements of the other elements, said complex being supported by an activated carbon support having a surface area of at least about 300 square meters per gram.A process for converting mixtures of hydrogen and carbon monoxide, particularly synthesis gas, to alcohol with minimal levels of hydrocarbon by-products being formed is also disclosed.
摘要:
This invention relates to a process for converting a hydrocarbon reactant to a product comprising an oxygenate or a nitrile, the process comprising: (A) flowing a reactant composition comprising the hydrocarbon reactant, and oxygen or a source of oxygen, and optionally ammonia, through a microchannel reactor in contact with a catalyst to convert the hydrocarbon reactant to the product, the hydrocarbon reactant undergoing an exothermic reaction in the microchannel reactor; (B) transferring heat from the microchannel reactor to a heat exchanger during step (A); and (C) quenching the product from step (A).
摘要:
A catalyst is disclosed which comprises a ruthenium-copper-containing complex of the formulaM.sub.a A.sub.b RuCu.sub.c N.sub.z O.sub.xwhereinM is selected from the group consisting of Ce, Cr, Fe, Mn, and mixtures thereof,A is an alkali metal, alkaline earth metal or mixture thereof,a is from 0 to about 1,b is from about 0.002 to about 10,c is from about 0.2 to about 20,z is from 0 to about 1% by weight,x is the number of oxygens needed to fulfill the valence requirements of the other elements, said complex being supported by an activated carbon support having a surface area of at least about 300 square meters per gram. A process for converting mixtures of hydrogen and carbon monoxide, particularly synthesis gas, to alcohol with minimal levels of hydrocarbon by-products being formed is also disclosed.