公开(公告)号：US4036783A

公开(公告)日：1977-07-19

申请号：US661241

申请日：1976-02-25

申请人： Kurt Blechschmitt ,  Peter Reuter ,  Friedrich Wirth ,  Gert Buerger ,  Rolf Seubert

发明人： Kurt Blechschmitt ,  Peter Reuter ,  Friedrich Wirth ,  Gert Buerger ,  Rolf Seubert

IPC分类号： C07D307/89 ,  B01J23/22 ,  B01J35/02 ,  B01J35/04 ,  B01J37/02 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  B01J21/06

CPC分类号： C07C51/265 ,  B01J23/22 ,  B01J35/04 ,  B01J37/0232 ,  C07C51/313

摘要： A supported catalyst containing vanadium and titanium, comprising a ring-shaped carrier having an external diameter of from 7.3 to 8.6 mm, a length of from 5.3 to 7 mm and a wall thickness of from 0.1 to 2 mm, and an active composition, applied thereto, of from 1 to 30 per cent by weight of vanadium pentoxide and from 70 to 99 per cent by weight of titanium dioxide and/or zirconium dioxide.

摘要翻译： 含有钒和钛的负载型催化剂，其包含外径为7.3至8.6mm，长度为5.3至7mm，壁厚为0.1至2mm的环形载体和施加的活性组合物 至10重量％的五氧化二钒和70至99重量％的二氧化钛和/或二氧化锆。

公开(公告)号：US4568427A

公开(公告)日：1986-02-04

申请号：US465767

申请日：1983-02-11

申请人： Eckehard Danz ,  Gerd Dumbgen ,  Ernest Miesen ,  Johannes E. Schmidt ,  Friedrich Wirth

发明人： Eckehard Danz ,  Gerd Dumbgen ,  Ernest Miesen ,  Johannes E. Schmidt ,  Friedrich Wirth

IPC分类号： C07D307/60 ,  C07C51/573 ,  C07D307/89 ,  B01D3/34

CPC分类号： C07C51/573

摘要： A process for the continuous isolation of phthalic anhydride and maleic anhydride from the reaction gases obtained by catalytic oxidation of o-xylene or naphthalene with air, wherein the reaction gases are treated with a hydrocarbon of boiling range from 115.degree. to 175.degree. C. as the solvent in a column, and are then treated with an organic solvent of boiling range from 180.degree. to 290.degree. C. in a second column, the phthalic anhydride and maleic anhydride being isolated from the liquid bottom product of the first column.

摘要翻译： 从通过邻二甲苯或萘与空气的催化氧化得到的反应气体中连续分离邻苯二甲酸酐和马来酸酐的方法，其中反应气体用沸点为115-175℃的烃进行处理 柱中的溶剂，然后在第二塔中用180-290℃的有机溶剂处理，邻苯二甲酸酐和马来酐与第一塔的液体底部产物分离。

公开(公告)号：US4489775A

公开(公告)日：1984-12-25

申请号：US287783

申请日：1981-07-28

申请人： Harry Kassat ,  Friedrich Wirth ,  Joachim Wagner

发明人： Harry Kassat ,  Friedrich Wirth ,  Joachim Wagner

IPC分类号： B01D7/00 ,  B01D7/02 ,  F28F9/013 ,  B01D51/00 ,  F28F7/00 ,  F28F9/00

CPC分类号： F28F9/0138 ,  B01D7/02

摘要： Desublimator for isolating sublimation products from reaction gases, which consists of a closed housing and a plurality of rows of finned tubes accommodated horizontally and superposedly therein, successive superposed finned tubes being supported, and mutually spaced, with limited adjustability, by means of cage-like perforated sliding shoes surrounding them in a box-like manner, the sliding shoes of the individual finned tubes being directly stacked one above the other and resting loosely on common supporting girders anchored to the housing, and the supporting girders having, in cross-section, the outline of a triangle with its apex pointing downward.

摘要翻译： 用于将升华产物与反应气体隔离的分离器，其由封闭的壳体和水平和重叠地容纳在其中的多排翅片管组成，连续的叠置的翅片管通过笼状支撑并相互间隔开，具有有限的可调节性 以盒状方式围绕它们的穿孔滑动鞋，各个翅片管的滑靴直接彼此堆叠堆叠并松动地搁置在锚固到壳体上的共同的支撑梁上，并且支撑梁的横截面， 三角形的轮廓，其顶点指向下方。

公开(公告)号：US4411818A

公开(公告)日：1983-10-25

申请号：US348198

申请日：1982-02-12

申请人： Peter Reuter ,  Kurt Blechschmitt ,  Friedrich Wirth

发明人： Peter Reuter ,  Kurt Blechschmitt ,  Friedrich Wirth

IPC分类号： C07D307/89 ,  B01J23/92 ,  B01J27/28 ,  B01J37/20 ,  B01J38/12 ,  B01J38/20 ,  C07B61/00 ,  C07C51/265 ,  B01J21/20

CPC分类号： B01J37/20 ,  B01J23/92 ,  B01J27/285 ,  C07C51/265 ,  Y02P20/584

摘要： A process for reactivating a vanadium-containing oxidation catalyst, wherein the catalyst is treated first at from 100.degree. to 600.degree. C., with a volatile phosphorus compound in the presence of an oxygen-containing gas, and then at from 50.degree. to 600.degree. C. with sulfur trioxide or a mixture of a volatile sulfur compound and an oxygen-containing gas.

摘要翻译： 一种使含钒氧化催化剂再生的方法，其中催化剂首先在100℃至600℃下与含氧气体存在下的挥发性磷化合物，然后在50至600℃ 与三氧化硫或挥发性硫化合物和含氧气体的混合物。

公开(公告)号：US4369327A

公开(公告)日：1983-01-18

申请号：US313177

申请日：1981-10-20

申请人： Dieter Stockburger ,  Wilhelm Schultz ,  Johannes E. Schmidt ,  Friedrich Wirth ,  Herwig Hoffmann ,  Bernhard Holzknecht ,  Klaus Wintermantel

发明人： Dieter Stockburger ,  Wilhelm Schultz ,  Johannes E. Schmidt ,  Friedrich Wirth ,  Herwig Hoffmann ,  Bernhard Holzknecht ,  Klaus Wintermantel

IPC分类号： C07D307/89 ,  C07C51/265 ,  C07C51/31

CPC分类号： C07C51/265 ,  C07C51/313

摘要： A process for the preparation of phthalic anhydride (PA) of catalytic oxidation of naphthalene or o-xylene with air, a preheated mixture of air and naphthalene or o-xylene being passed into a reactor charged with the catalyst, and the reaction gas leaving the reactor being passed through a separator in which the PA is separated out as a solid, in which process the air fed to the reactor is preheated, before or after the admixture of naphthalene or of o-xylene, by using it to cool the reaction gas in the PA separator.

摘要翻译： 制备萘和邻二甲苯与空气催化氧化邻苯二甲酸酐（PA）的方法，将预热的空气和萘或邻二甲苯的混合物送入装有催化剂的反应器中，并将反应气体离开 反应器通过分离器，其中PA作为固体分离，在该过程中，在萘或邻二甲苯的混合之前或之后，通过使用它来冷却反应气体，将进料到反应器的空气预热 在PA分离器中。

公开(公告)号：US4324694A

公开(公告)日：1982-04-13

申请号：US157782

申请日：1980-06-09

申请人： Peter Reuter ,  Kurt Blechschmitt ,  Friedrich Wirth

发明人： Peter Reuter ,  Kurt Blechschmitt ,  Friedrich Wirth

IPC分类号： C07D307/89 ,  B01J23/22 ,  B01J27/18 ,  B01J27/198 ,  B01J37/02 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  B01J21/06 ,  B01J23/04 ,  B01J27/16

CPC分类号： C07C51/265 ,  B01J23/22 ,  B01J27/198 ,  C07C51/313 ,  B01J37/0244

摘要： A supported catalyst, containing vanadium pentoxide, titanium dioxide, phosphorus, rubidium and any optionally added cesium, with or without zirconium dioxide, in which the catalytic material contains from 1 to 40% by weight of V.sub.2 O.sub.5, from 60 to 99% by weight of TiO.sub.2 and/or ZrO.sub.2 and, based on the total amount of TiO.sub.2, ZrO.sub.2 and V.sub.2 O.sub.5, up to 2% by weight of phosphorus and up to 1.5% by weight of rubidium and/or cesium, and which comprises two layers, of which the inner layer contains more than 0.2 and up to 2% by weight of phosphorus, but no rubidium and/or cesium, and the outer layer contains from 0 to 0.2% by weight of phosphorus and from 0.02 to 1.5% by weight of rubidium and/or cesium, the outer layer accounting for from 10 to 90% by weight of the total catalytic material.

摘要翻译： 一种负载催化剂，其含有五氧化二钒，二氧化钛，磷，铷和任何任选加入的铯，具有或不具有二氧化锆，其中催化材料含有1至40重量％的V 2 O 5，60至99重量％ TiO 2和/或ZrO 2，并且基于TiO 2的总量ZrO 2和V 2 O 5，高达2重量％的磷和至多1.5重量％的铷和/或铯，并且其包含两层，其中 内层含有多于0.2重量％至2重量％的磷，但不含铷和/或铯，外层含有0至0.2重量％的磷和0.02至1.5重量％的铷和/ 或铯，外层占总催化材料的10〜90重量％。

公开(公告)号：US4282116A

公开(公告)日：1981-08-04

申请号：US138413

申请日：1980-04-08

申请人： Peter Reuter ,  Kurt Blechschmitt ,  Friedrich Wirth

发明人： Peter Reuter ,  Kurt Blechschmitt ,  Friedrich Wirth

IPC分类号： C07D307/89 ,  B01J23/22 ,  B01J35/02 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  B01J21/06 ,  B01J35/00

CPC分类号： C07C51/265 ,  B01J23/22 ,  B01J35/026 ,  C07C51/313

摘要： A supported catalyst, containing vanadium and titanium and/or zirconium, obtained by applying a mixture of finely divided titanium dioxide and/or zirconium dioxide, and a solution or suspension of a vanadium compound, to an inert, non-porous, ring-shaped carrier having an external diameter of from 6 to 10 mm, a length of from 4 to 10 mm and a wall thickness of from 0.5 to 3 mm, the two end faces of the ring-shaped carrier being outwardly beveled at an angle such that the length of the outer cylindrical wall is at least 20% shorter than the length of the inner cylindrical wall.

摘要翻译： 通过将细碎的二氧化钛和/或二氧化锆的混合物以及钒化合物的溶液或悬浮液施加到惰性，无孔的环状的载体催化剂中，其含有钒和钛和/或锆 具有6至10mm的外径，4至10mm的长度和0.5至3mm的壁厚的载体，环形载体的两个端面以一定角度向外倾斜，使得 外圆筒壁的长度比内筒壁的长度短至少20％。

公开(公告)号：US4008255A

公开(公告)日：1977-02-15

申请号：US589566

申请日：1975-06-23

申请人： Friedrich Wirth ,  Wolfgang Kube ,  Paul Hornberger ,  Otto Leman ,  Joachim Wagner ,  Dieter Karau

发明人： Friedrich Wirth ,  Wolfgang Kube ,  Paul Hornberger ,  Otto Leman ,  Joachim Wagner ,  Dieter Karau

IPC分类号： C07C51/573 ,  C07D307/89

CPC分类号： C07C51/573

摘要： Process for the recovery of phthalic anhydride in which gases as obtained in the catalytic atmospheric oxidation of o-xylene or naphthalene are treated with a hydrocarbon containing C.sub.26.sub.- paraffins, cooling, if necessary, the hydrocarbon laden with phthalic anhydride, separating the solid phthalic anhydride followed by melting and distillation thereof.

摘要翻译： 回收邻苯二甲酸酐的方法，其中在邻二甲苯或萘的催化气氛氧化中获得的气体用含有C 26 - 链烷烃的烃处理，如果需要，用邻苯二甲酸酐冷却，分离固体邻苯二甲酸酐 然后进行熔融和蒸馏。

公开(公告)号：US4007136A

公开(公告)日：1977-02-08

申请号：US591415

申请日：1975-06-30

申请人： Kurt Blechschmitt ,  Friedrich Wirth ,  Paul Hornberger ,  Peter Reuter ,  Gert Buerger

发明人： Kurt Blechschmitt ,  Friedrich Wirth ,  Paul Hornberger ,  Peter Reuter ,  Gert Buerger

IPC分类号： C07D307/89 ,  B01J23/22 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  B01J21/06 ,  B01J23/04

CPC分类号： C07C51/265 ,  B01J23/22 ,  C07C51/313

摘要： Supported catalyst for the oxidation of o-xylene or naphthalene to phthalic anhydride, comprising an inert carrier and the active material applied thereto, which contains from 1 to 40 per cent by weight of vanadium pentoxide, from 60 to 98.84 per cent by weight of titanium dioxide and from 0.16 to 0.6 per cent by weight, based on titanium dioxide, of rubidium in the form of rubidium oxide, the vanadium pentoxide content being from 0.05 to 4 per cent by weight, based on the (complete) catalyst.

摘要翻译： 用于将邻二甲苯或萘氧化成邻苯二甲酸酐的负载催化剂，其包含惰性载体和施加到其上的活性材料，其含有1至40重量％的五氧化二钒，60至98.84重量％的钛 基于二氧化钛，以氧化铷形式的铷为0.16至0.6重量％，五氧化二钒的含量为（完全）催化剂的0.05至4重量％。

公开(公告)号：US4096094A

公开(公告)日：1978-06-20

申请号：US730827

申请日：1976-10-08

申请人： Kurt Blechschmitt ,  Peter Reuter ,  Friedrich Wirth

发明人： Kurt Blechschmitt ,  Peter Reuter ,  Friedrich Wirth

IPC分类号： C07D307/89 ,  B01J23/22 ,  B01J35/02 ,  B01J37/02 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  B01J23/04 ,  B01J21/06 ,  B01J23/18

CPC分类号： C07C51/265 ,  B01J23/22 ,  C07C51/313 ,  B01J35/026 ,  B01J37/0223

摘要： A supported catalyst for the oxidation of aromatic or unsaturated aliphatic hydrocarbons, comprising an inert nonporous carrier to which is applied a thin layer of a catalytic composition which contains from 1 to 39.9 percent by weight of vanadium pentoxide, from 60 to 98.9 percent by weight of titanium dioxide and from 0.1 to 10% by weight of rubidium and antimony in an atomic ratio Rb : Sb of from 1:2.5 to 1:30, the vanadium pentoxide content being from 0.05 to 4 percent by weight, based on the supported catalyst.

摘要翻译： 用于氧化芳族或不饱和脂族烃的负载催化剂，其包含惰性无孔载体，向其中施加薄层催化组合物，其含有1至39.9重量％的五氧化二钒，60至98.9重量％的 二氧化钛和0.1-10重量％的原子比为Rb:Sb为1:2.5至1:30的铷和锑，五氧化二钒含量为基于负载型催化剂的0.05-4重量％。