公开(公告)号：US20240343668A1

公开(公告)日：2024-10-17

申请号：US18251015

申请日：2021-10-28

Applicant: KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY ,  HANWHA SOLUTIONS CORPORATION

Inventor： Jae Woo LEE ,  Jeil PARK ,  Wonhyeong LEE

IPC: C07C51/31 ,  B01J23/889 ,  B01J27/198

CPC classification number: C07C51/313 ,  B01J23/8892 ,  B01J27/198 ,  C07C2601/14

Abstract: The present invention relates to a method for preparing hydrocarbon double acids using a cyclic hydrocarbon oxidation catalyst, wherein adipic acid and dodecanedioic acid may be produced with high yield while solving the problem of environmental pollution, the adipic acid and the dodecanedioic acid being prepared by using an oxidation reaction of a cyclohexane-cyclohexanone mixture and an oxidation reaction of a cyclododecane-cyclododecanone mixture, respectively, in the presence of a vanadium phosphate oxide-based catalyst and/or a cobalt-manganese oxide-based catalyst.

公开(公告)号：US20240278222A1

公开(公告)日：2024-08-22

申请号：US17927373

申请日：2021-05-17

Applicant: BASF SE

Inventor： Nicolas DUYCKAERTS ,  Kazuhiko AMAKAWA ,  Jens WEIGUNY ,  Christian WALSDORFF ,  Miguel Angel ROMERO VALLE ,  Gerald MEYER ,  Rouven WEILER

IPC: B01J27/198 ,  B01J8/02 ,  B01J35/40 ,  B01J35/55 ,  C07C51/25 ,  C07D307/60

CPC classification number: B01J27/198 ,  B01J8/02 ,  B01J35/40 ,  B01J35/55 ,  C07C51/252 ,  C07D307/60

Abstract: A shaped catalyst body for heterogeneously catalyzed reactions of organic compounds in the gas-phase in fixed-bed reactors, containing an element from group 3 to 12 of the Periodic Table of the Elements, and having a three-lobed structure with a lateral surface around the lobes, a top cover and a bottom cover, as well as three continuous holes running from one cover side to the other cover side, wherein each hole is assigned to one lobe and wherein the cover sides have outwardly shaped arches, its production and a process for its use in the heterogeneously catalyzed reaction of an organic compound in the gas phase.

公开(公告)号：US09931618B2

公开(公告)日：2018-04-03

申请号：US14673569

申请日：2015-03-30

Applicant: Thomas Cotter ,  Andreas Reitzmann ,  Gerhard Mestl ,  Gabriele Donabauer ,  Susanne Roehrer

Inventor： Thomas Cotter ,  Andreas Reitzmann ,  Gerhard Mestl ,  Gabriele Donabauer ,  Susanne Roehrer

IPC: B01J27/199 ,  B01J27/198 ,  B01J37/28 ,  C07D307/60 ,  B01J37/10 ,  B01J23/00 ,  B01J37/00

CPC classification number: B01J27/199 ,  B01J23/002 ,  B01J27/198 ,  B01J37/0063 ,  B01J37/10 ,  B01J37/28 ,  B01J2523/00 ,  C07D307/60 ,  B01J2523/12 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/55 ,  B01J2523/68

Abstract: The present invention relates to a catalyst containing a vanadium-phosphorus oxide and an alkali metal, wherein the proportion by weight of alkali metal in the vanadium-phosphorus oxide is in the range from 10 to 400 ppm, based on the total weight of the vanadium-phosphorus oxide, a process for producing it and also the use of the catalyst for the gas-phase oxidation of hydrocarbons, in particular for preparing maleic anhydride.

公开(公告)号：US20180085741A1

公开(公告)日：2018-03-29

申请号：US15829218

申请日：2017-12-01

Applicant: Eastman Chemical Company

Inventor： David William Norman ,  Greg Alan King

IPC: B01J27/199 ,  B01J37/08 ,  B01J21/06 ,  B01J23/00

CPC classification number: B01J27/199 ,  B01J21/063 ,  B01J23/002 ,  B01J27/198 ,  B01J35/002 ,  B01J37/03 ,  B01J37/086 ,  B01J2523/00 ,  B01J2523/13 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  C07C51/353 ,  C07C57/04

Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus modified with alkali metal. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed.

公开(公告)号：US09926256B2

公开(公告)日：2018-03-27

申请号：US13835187

申请日：2013-03-15

Applicant: The Procter & Gamble Company

Inventor： Janette Villalobos Lingoes ,  Dimitris Ioannis Collias

IPC: B01J27/00 ,  C07C51/48 ,  B01J27/18 ,  B01J27/187 ,  B01J27/25 ,  C07C51/377 ,  C07C51/09 ,  C07C57/04 ,  A61F13/534 ,  C08F2/10 ,  B01J27/16 ,  B01J27/185 ,  B01J27/186 ,  B01J27/188 ,  B01J27/195 ,  B01J27/198 ,  B01J35/02 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  C07C51/44 ,  A61F13/53

CPC classification number: C07C51/48 ,  A61F13/53 ,  A61F13/534 ,  A61F2013/530489 ,  A61F2013/530496 ,  B01J27/16 ,  B01J27/1806 ,  B01J27/1811 ,  B01J27/1817 ,  B01J27/1853 ,  B01J27/1856 ,  B01J27/186 ,  B01J27/187 ,  B01J27/188 ,  B01J27/195 ,  B01J27/198 ,  B01J27/25 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/04 ,  B01J37/08 ,  C07C51/09 ,  C07C51/377 ,  C07C51/44 ,  C07C57/04 ,  C08F2/10

Abstract: Disclosed herein is a mixed phosphate catalyst for converting lactic acid to acrylic acid, which is characterized by a high conversion of lactic acid, a high selectivity for acrylic acid, a high yield of acrylic acid, and correspondingly low selectivity and molar yields for undesired by-products. This is achieved with a particular class of catalysts defined by a mixture of metal-containing phosphate salts. Further, the catalyst is believed to be stable and active for lengthy periods heretofore unseen in the art for such dehydration processes.

公开(公告)号：US20180078927A1

公开(公告)日：2018-03-22

申请号：US15829245

申请日：2017-12-01

Applicant: Eastman Chemical Company

Inventor： David William Norman ,  Greg Alan King

IPC: B01J27/199 ,  B01J23/00 ,  B01J27/198 ,  C07C57/04 ,  B01J37/03 ,  B01J37/08 ,  C07C51/353 ,  B01J21/06 ,  B01J35/00

CPC classification number: B01J27/199 ,  B01J21/063 ,  B01J23/002 ,  B01J27/198 ,  B01J35/002 ,  B01J37/03 ,  B01J37/086 ,  B01J2523/00 ,  B01J2523/13 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  C07C51/353 ,  C07C57/04

Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus modified with alkali metal. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed.

公开(公告)号：US09593065B2

公开(公告)日：2017-03-14

申请号：US14794955

申请日：2015-07-09

Applicant: BASF SE

Inventor： Lukas Schulz ,  Nicolai Tonio Woerz ,  Tim Blaschke ,  Marco Hartmann ,  Frank Huetten

IPC: C07C51/347 ,  B01J23/50 ,  B01J27/198 ,  C07C57/04 ,  C07C45/38 ,  C07C51/353 ,  C07C45/32 ,  C07C45/78

CPC classification number: C07C51/347 ,  B01J23/50 ,  B01J27/198 ,  C07C45/32 ,  C07C45/38 ,  C07C45/783 ,  C07C51/353 ,  C07C57/04 ,  C07C47/04

Abstract: A process for preparing acrylic acid from methanol and acetic acid, comprising (i) contacting a gaseous stream S0 comprising methanol, oxygen and inert gas with an oxidation catalyst to obtain a gaseous stream S1 comprising formaldehyde and inert gas; (ii) removing at least a portion of the inert gas present in S1 from at least a portion of the formaldehyde present in S1 by absorbing this formaldehyde in an absorbent to obtain a gaseous stream S2 comprising the portion of the inert gas removed, and to obtain a stream S3 comprising absorbent and absorbate comprising formaldehyde; (iii) optionally removing a portion or the entirety of the absorbent present in stream S3, such that a stream S3a remains from stream S3, and producing a stream S4 from at least stream S3 or stream S3a and a stream S5 comprising acetic acid; and (iv) contacting stream S4 in gaseous form with an aldol condensation catalyst to obtain a gaseous stream S6 comprising acrylic acid.

Abstract translation: 一种从甲醇和乙酸制备丙烯酸的方法，包括（i）使包含甲醇，氧气和惰性气体的气流S0与氧化催化剂接触以获得包含甲醛和惰性气体的气流S1; （ii）通过在吸收剂中吸收该甲醛从S1中存在的甲醛的至少一部分除去S1中存在的至少一部分惰性气体，以获得包含去除部分惰性气体的气流S2，并且 获得包含含甲醛的吸收剂和吸收剂的流S3; （iii）任选地除去流S3中存在的吸收剂的一部分或全部，使得流S3a从流S3保留，并从至少流S3或流S3a和包含乙酸的流S5产生流S4; 和（iv）将气态的流S4与醛醇缩合催化剂接触以获得包含丙烯酸的气流S6。

公开(公告)号：US09579643B2

公开(公告)日：2017-02-28

申请号：US13771804

申请日：2013-02-20

Applicant: Huntsman Petrochemical LLC

Inventor： Zhiping Shan

IPC: B01J23/22 ,  B01J37/06 ,  B01J27/198 ,  B01J35/10 ,  C07C51/215 ,  C07D307/60 ,  B01J38/50

CPC classification number: B01J37/06 ,  B01J27/198 ,  B01J35/10 ,  B01J35/1014 ,  B01J38/50 ,  C07C51/215 ,  C07D307/60 ,  Y02P20/584 ,  C07C57/145

Abstract: A process for preparing a catalyst by selecting an active catalyst and contacting the active catalyst with one or more fluids containing an organic solvent or mixture of organic solvents. In one embodiment, each organic solvent has a dielectric constant within a range of about 5 to about 55 when measured at a temperature of 20° C. to 25° C. The catalyst thus prepared may be used in a process for preparing maleic anhydride.

Abstract translation: 通过选择活性催化剂并使活性催化剂与一种或多种含有机溶剂或有机溶剂混合物的流体接触来制备催化剂的方法。 在一个实施方案中，当在20℃至25℃的温度下测量时，每种有机溶剂的介电常数在约5至约55的范围内。如此制备的催化剂可用于制备马来酸酐的方法。

公开(公告)号：US09522898B2

公开(公告)日：2016-12-20

申请号：US14765855

申请日：2014-02-05

Applicant: RHODIA OPERATIONS ,  Centre National De La Recherche Scientifique

Inventor： Jean-Marc Clacens ,  Floryan Decampo ,  Fabien Grasset ,  Benjamin Katryniok ,  Franck Dumeignil ,  Sebastien Paul ,  Veronique Rataj

IPC: C07D307/46 ,  C07C45/38 ,  B01J21/18 ,  B01J27/198

CPC classification number: C07D307/46 ,  B01J21/18 ,  B01J27/198 ,  C07C45/38 ,  C07C47/12 ,  C07C47/228

Abstract: The present invention concerns a process for the production of an aldehyde compound by an oxidation reaction of an alcohol compound in the presence of a mesostructured vanadium phosphorus mixed oxide catalyst, at a temperature comprised between 50° C. and 200° C., in presence of an oxidant. The reaction medium may also comprise a solvent.

Abstract translation: 本发明涉及通过醇化合物在介质结构化的钒磷混合氧化物催化剂存在下的氧化反应生产醛化合物的方法，在50℃和200℃之间的温度下，在存在 的氧化剂。 反应介质还可以包含溶剂。

公开(公告)号：US09233360B1

公开(公告)日：2016-01-12

申请号：US14482313

申请日：2014-09-10

Applicant: Kandaswamy Jothimurugesan ,  Mark Muraoka

Inventor： Kandaswamy Jothimurugesan ,  Mark Muraoka

IPC: B01J21/04 ,  B01J23/75 ,  B01J23/70 ,  B01J27/185 ,  B01J23/89 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  C10G2/00

CPC classification number: B01J27/1856 ,  B01J21/04 ,  B01J23/70 ,  B01J23/75 ,  B01J23/80 ,  B01J23/8946 ,  B01J23/8953 ,  B01J23/896 ,  B01J23/8966 ,  B01J23/898 ,  B01J23/8993 ,  B01J27/188 ,  B01J27/19 ,  B01J27/198 ,  B01J35/002 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/024 ,  B01J37/08 ,  B01J37/18 ,  C10G2/332 ,  C10G2/333

Abstract: A process has been developed for preparing a Fischer-Tropsch catalyst precursor and a Fischer-Tropsch catalyst made from the precursor. The process includes contacting a gamma alumina catalyst support material with a first solution containing a compound containing zinc and optionally containing P, Ti, V, Co, Ga, Ge, Mo, W and/or Pr to obtain a modified catalyst support material. The modified catalyst support material is calcined at a temperature of at least 500° C. The calcined modified catalyst support has a pore volume of at least 0.4 cc/g. The modified catalyst support is less soluble in acid solutions than an equivalent unmodified catalyst support. The modified catalyst support is contacted with a second solution which includes a precursor compound of an active cobalt catalyst component to obtain a catalyst precursor. The catalyst precursor is reduced to activate the catalyst precursor to obtain the Fischer-Tropsch catalyst. The catalyst has enhanced hydrothermal stability as measured by losing no more than 20% of its pore volume when exposed to water vapor.

Abstract translation: 已经开发了制备费 - 托催化剂前体和由前体制备的费 - 托催化剂的方法。 该方法包括使γ氧化铝催化剂载体材料与含有锌化合物和任选地含有P，Ti，V，Co，Ga，Ge，Mo，W和/或Pr的第一溶液接触，以获得改性的催化剂载体材料。 改性的催化剂载体材料在至少500℃的温度下煅烧。煅烧的改性催化剂载体的孔体积至少为0.4cc / g。 改性的催化剂载体在酸溶液中比相当的未改性的催化剂载体更难溶解。 将改性的催化剂载体与包含活性钴催化剂组分的前体化合物的第二溶液接触以获得催化剂前体。 催化剂前体被还原以活化催化剂前体以获得费 - 托催化剂。 催化剂具有增强的水热稳定性，当暴露于水蒸气时，其通过损失其不超过其孔体积的20％来测量。