摘要:
A process for preparing an encapsulated pigment dispersion suitable for use in an ink jet printing ink comprising the following steps in the order I) followed by II): I) providing a dispersion comprising a pigment, a liquid medium and a dispersant comprising the repeat units from copolymerizing the ethylenically unsaturated monomers in components a) to c): a) from 75 to 97 parts of one or more hydrophobic ethylenically unsaturated monomers comprising at least 50 parts benzyl (meth) acrylate; b) from 3 to 25 parts one or more hydrophilic ethylenically unsaturated monomers having one or more ionic group(s); c) from 0 to 2 parts of one or more hydrophilic ethylenically unsaturated monomers having a hydrophilic non-ionic group; and wherein the parts are by weight and the sum of the parts a) to c) add up to 100; II) cross-linking the dispersant in the presence of the pigment and the liquid medium.
摘要:
A dispersion comprising a particulate solid, a liquid vehicle and a first polymer, wherein: the first polymer is obtained or obtainable by a process comprising reacting at least the components i), ii) and optionally iii) to form a pre-polymer: i) a compound of the Formula (1); wherein T1, T2, Q1, Q2, A1, A2 and Z are as defined in claim 1; ii) a diisocyanate; iii) an isocyanate-reactive compound; and then reacting the pre-polymer with at least component iv): iv) one or more compounds selected from an organic amine, alcohol or thiol provided that at least one of the said one or more organic compounds in component iv) has at least one ionic group; wherein the particulate solid is surface-modified with ionic groups and/or the particulate solid has situated on its surface one or more second polymers which is/are different from the first polymer.
摘要:
A composite membrane comprising: a. a porous support; b. a polymeric layer comprising dialkylsiloxane groups and a metal, the polymeric layer being present on the porous support; c. a discriminating layer present on the polymeric layer; and d. optionally a protective layer present on the discriminating layer wherein the polymeric layer has a molar ratio of metal:silicon of at least 0.0005.
摘要:
A process for the preparation of a dispersion, comprising: dispersing a composition comprising a particulate solid, a liquid medium and a dispersant; wherein the dispersant is obtained by a process comprising at least the steps a) and b): a) co-polymerising a monomer composition comprising at least the components i) and ii) so as to form a phospho-ester functional polymer: i) a monomer having at least one phospho-ester group and two groups independently selected from hydroxyl, amino, thiol and hydrazo groups, ii) a diisocyanate; and b) hydrolysing at least some of the phospho-ester groups in the phospho-ester functional polymer so as to result in a dispersant having phosphorus containing anionic groups.
摘要:
A process for printing an ink onto a substrate wherein: the ink comprises an encapsulated particulate solid and a liquid vehicle; the encapsulated particulate solid comprises a particulate solid encapsulated with a cross-linked dispersant shell; and the ink is printed onto a substrate which is or comprises corrugated paper.
摘要:
A composite membrane comprising: a.a porous support; b.a polymeric layer comprising dialkylsiloxane groups and a metal, the polymeric layer being present on the porous support; c.a discriminating layer present on the polymeric layer; and d.optionally a protective layer present on the discriminating layer whereinthe polymeric layer has a molar ratio of metal:silicon of at least 0.0005.
摘要:
A polymeric dispersant obtained or obtainable by copolymerising a monomer composition comprising at least the components: i) benzyl (meth)acrylate; ii) propylene glycol (meth)acrylate; wherein the weight ratio of component i) to component ii) is greater than 10:1.
摘要:
A process for preparing a dispersion comprising the stages: i) providing a dispersion comprising a particulate solid, a liquid medium and a dispersant having cross-linkable groups and a weight averaged molecular weight of from 1,000 to 70,000; and ii) cross-linking the dispersant in the presence of the particulate solid and the liquid medium thereby preparing a dispersion of an encapsulated particulate solid, wherein the cross-linking is performed such that 0.01 to 0.5 mmoles of cross-linkable groups in the dispersant are cross-linked per g of dispersant; said process also comprising at any stage: iii) adding a metal chelating agent to the dispersion; and after stage iii) the stage of: iv) removing at least some of the metal chelating agent from the dispersion.
摘要:
A process for printing on a textile substrate comprising the steps of: (I) preparing an ink comprising the following components: (a) from 1 to 8 parts of a self-dispersible pigment which comprises a carboxy-functional dispersant crosslinked around a pigment core by a crosslinking agent having at least two groups selected from oxetane, carbodiimide, hydrazide, oxazoline, aziridine, isocyanate, N-methylol, keteneimine, isocyanurate and epoxy groups; (b) from 0 to 16 parts of a binder selected from one or more of an acrylic latex binder, a styrene acrylic latex binder and a styrene butadiene latex binder wherein the binder has a Tg in the range of from −25° C. to 35° C.; (c) from 1 to 30 parts of one or more water-miscible organic solvents (d) from 0.1 to 3 parts of a surfactant; (e) from 0 to 5 parts of biocide; (f) from 0 to 10 parts of a viscosity modifier; (g) from 0 to 10 parts of a polyurethane latex binder with a Tg in the range of from −25° C. to 35° C.; (h) from 0 to 6 parts of a cross linking agent; and (i) the balance to 100 parts water: (II) optionally preparing a latex binders solution comprising; i) from 1 to 16 parts of one or more latex binders selected from an acrylic latex binder, a styrene acrylic latex binder and a styrene butadiene latex binder where the latex binder(s) have a Tg in the range of from −25° C. to 35° C.; ii) from 0 to 6 parts of a polyurethane latex binder; and iii) from 0 to 5 parts of a cross linking agent: (III) printing the ink prepared in step (I) on to a textile substrate using a ink jet printer with a single pass print head and optionally pre-printing or overprinting with the latex binder solution from step (II) (IV) curing the printed textile substrate from step (III): provided that if component (b) in the ink prepared in step (a) is 0 then optional step (II) is compulsory. Also inks, ink-sets, ink containers and ink-jet printers.
摘要:
A process for preparing a dispersion comprising the stages: i) providing a dispersion comprising a particulate solid, a liquid medium and a dispersant having cross-linkable groups and a weight averaged molecular weight of from 1,000 to 70,000; and ii) cross-linking the dispersant in the presence of the particulate solid and the liquid medium thereby preparing a dispersion of an encapsulated particulate solid, wherein the cross-linking is performed such that 0.01 to 0.5 mmoles of cross-linkable groups in the dispersant are cross-linked per g of dispersant; said process also comprising at any stage: iii) adding a metal chelating agent to the dispersion; and after stage iii) the stage of: iv) removing at least some of the metal chelating agent from the dispersion.