Preparation of asymmetric membranes using hot-filament chemical vapor deposition
    7.
    发明申请
    Preparation of asymmetric membranes using hot-filament chemical vapor deposition 审中-公开
    使用热丝化学气相沉积制备不对称膜

    公开(公告)号:US20060040053A1

    公开(公告)日:2006-02-23

    申请号:US10513880

    申请日:2003-05-09

    IPC分类号: C23C16/00

    摘要: One aspect of the present invention relates to a method for modifying one side of a PTFE membrane by using HFCVD to deposit a PTFE film on one side of the PTFE membrane. The precursor fluorocarbon gas is preferably hexafluoropropylene oxide, which upon pyrolysis under HFCVD conditions forms reactive CF2 species. The present invention also relates to a modified PTFE membrane having a PTFE film on only one side, wherein the PTFE film has a porosity of greater than about 30% and a dangling bond density of less than about 1018 spins/cm3. The invention further provides a method of filtering a liquid or gas or a mixture of the two, comprising passing the liquid or gas or mixture of the two through the modified PTFE membrane of the present invention.

    摘要翻译: 本发明的一个方面涉及通过使用HFCVD在PTFE膜的一侧上淀积PTFE膜来改变PTFE膜的一面的方法。 前体碳氟化合物气体优选为六氟环氧丙烷,其在HFCVD条件下热解形成反应性CF 2物质。 本发明还涉及仅在一侧具有PTFE膜的改性PTFE膜,其中PTFE膜的孔隙率大于约30%,悬挂键密度小于约1018自旋/ cm3。 本发明还提供一种过滤液体或气体或二者的混合物的方法,包括使液体或气体或其混合物通过本发明的改性PTFE膜。

    Method of producing a reactive coating by after-glow plasma polymerization
    8.
    发明授权
    Method of producing a reactive coating by after-glow plasma polymerization 失效
    通过后辉度等离子体聚合制备反应性涂层的方法

    公开(公告)号:US06436481B1

    公开(公告)日:2002-08-20

    申请号:US09331516

    申请日:1999-06-22

    IPC分类号: C08J718

    摘要: The present invention describes coated articles and methods for preparing such articles, wherein the primary coating comprises a plasma-induced polymer carrying reactive groups. The invention further relates to the reaction of said primary coatings carrying reactive groups with monomeric, oligomeric or macromolecular compounds of synthetic, semisynthetic or biological origin to provide hybrid-type coated articles (secondary coatings).

    摘要翻译: 本发明描述了涂覆制品和制备这种制品的方法,其中初级涂层包含带有反应性基团的等离子体诱导聚合物。 本发明还涉及所述带有反应性基团的初级涂料与合成,半合成或生物来源的单体,低聚物或大分子化合物的反应,以提供混合型涂覆制品(二次涂料)。

    Plasma-annealed porous polymers
    9.
    发明授权
    Plasma-annealed porous polymers 有权
    等离子体退火多孔聚合物

    公开(公告)号:US06203850B1

    公开(公告)日:2001-03-20

    申请号:US09314269

    申请日:1999-05-18

    申请人: Hiroshi Nomura

    发明人: Hiroshi Nomura

    IPC分类号: C08J936

    摘要: Porous polymeric materials are hardened by a process of plasma-annealing, involving treatment of at least one surface with a gas plasma formed by glow discharge through a gas containing a saturated alkane or an acetylene. Plasma-annealed porous polymers with reduced adsorption toward proteins were obtained by exposure to a glow discharge through a gas mixture containing an alkane such as methane in combination with oxygen, air, or a hydrophilic unsaturated organic monomer. For example, porous polysulfone sheet and hollow fiber were plasma-annealed by treatment with a gas plasma containing methane and air or acrylic acid with simultaneous deposition of a hydrophilic polymerizate thereon.

    摘要翻译: 多孔聚合材料通过等离子体退火工艺进行硬化,包括用通过含有饱和烷烃或乙炔的气体通过辉光放电形成的气体等离子体处理至少一个表面。 通过与氧,空气或亲水性不饱和有机单体组合的含有烷烃如甲烷的气体混合物暴露于辉光放电,获得具有减少对蛋白质吸附的等离子体退火多孔聚合物。 例如,通过用含有甲烷和空气或丙烯酸的气体等离子体处理同时沉积亲水性聚合物而对多孔聚砜片和中空纤维进行等离子体退火。

    Method and apparatus for selectively removing a component from a
multicomponent gas/vapor mixture
    10.
    发明授权
    Method and apparatus for selectively removing a component from a multicomponent gas/vapor mixture 失效
    用于从多组分气体/蒸汽混合物中选择性地除去组分的方法和装置

    公开(公告)号:US5753009A

    公开(公告)日:1998-05-19

    申请号:US645509

    申请日:1996-05-14

    摘要: A device and method for selectively removing one or more components from a multicomponent gas/vapor mixture by membrane fractionation. The membrane fractionation gas removal system preferably comprises: a feed chamber which contains the gas/vapor mixture; at least one porous membrane having a first side which contacts the gas/vapor mixture in the feed chamber, and a second side; at least one nonporous membrane having a first side which contacts the second side of the at least one porous membrane, and a second side, the nonporous membrane having a permeability selective to one or more components; an exit chamber connected to the second side of the at least one nonporous membrane such that the component exiting the nonporous gas enters the exit chamber; and an evacuation member connected to the exit chamber for evacuating one or more components from within the exit chamber. The one or more components are transported through the porous membrane, adsorbed out of the gas/vapor multicomponent gas mixture onto the surface of the porous membrane, through the nonporous membrane, and into the exit chamber. The one or more components preferably condense within the pores of the at least one porous membrane.

    摘要翻译: 一种用于通过膜分级从多组分气体/蒸汽混合物中选择性地除去一种或多种组分的装置和方法。 膜分馏气体去除系统优选包括:包含气体/蒸汽混合物的进料室; 至少一个多孔膜,其具有与进料室中的气体/蒸气混合物接触的第一侧和第二侧; 至少一个无孔膜,其具有接触所述至少一个多孔膜的第二侧的第一侧和第二侧,所述无孔膜具有对一种或多种组分的选择性; 出口室,连接到所述至少一个无孔膜的第二侧,使得离开所述无孔气体的组分进入所述出口室; 以及排出构件,其连接到出口室,用于从出口室排出一个或多个组件。 将一种或多种组分通过多孔膜,通过无孔膜从气体/蒸汽多组分气体混合物吸附到多孔膜的表面上并进入出口室。 一种或多种组分优选在至少一个多孔膜的孔内冷凝。