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公开(公告)号：US07311801B2
公开(公告)日：2007-12-25
申请号：US10780558
申请日：2004-02-19
CPC分类号： D21H21/16 , D21H11/08 , D21H11/14 , D21H17/17 , D21H17/675 , D21H19/10 , D21H21/52 , Y10T428/24802
摘要： The object of the present invention provides a newsprint paper having a friction coefficient in an appropriate range, a sufficient sizing quality, a low “neppari” strength and excellent printability. A newsprint paper having a static friction coefficient in an appropriate range of 0.44-0.74, a sufficient sizing quality and a low “neppari” strength can be obtained by applying a coating solution containing an alkenyl ketene dimer represented by general formula 1 below and a paper surface-modifying agent on a newsprint base paper, especially a neutralized newsprint base paper containing 1% by weight or more and 30% by weight or less of calcium carbonate as a filler and 50% by weight or more of deinked pulp. wherein R1 and R2 represent an unsaturated hydrocarbon group containing 8-30 carbon atoms.
摘要翻译： 本发明的目的是提供一种具有适当范围的摩擦系数，足够的施胶质量，低的“neppari”强度和优异的可印刷性的新闻纸。 通过涂布含有下述通式1表示的烯基烯酮二聚体的涂布溶液和纸张，可以获得静态摩擦系数在适合的范围为0.44-0.74，足够的施胶质量和低的“neppari”强度的新闻纸 在新闻纸原纸上，特别是含有1重量％以上且30重量％以下的碳酸钙作为填料的中和的新闻纸原纸，以及50重量％以上的脱墨纸浆的表面改性剂。 其中R 1和R 2代表含有8-30个碳原子的不饱和烃基。
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公开(公告)号：US20060225854A1
公开(公告)日：2006-10-12
申请号：US10563621
申请日：2004-06-24
CPC分类号： D21H21/16 , D21H17/28 , D21H17/35 , D21H17/36 , D21H17/375 , Y10T428/273 , Y10T428/277
摘要： Newsprint for offset printing having sufficient water absorption resistance to provide a clear printing image with less color registration problems upon offset printing is manufactured by coating base paper, to which aluminum sulfate (a 50% by weight Al2O3.14H2O product) is added at a ratio of less than 3.0% by weight upon paper making, with a surface treating agent mainly comprised of (A) a water-soluble macromolecular substance selected from starches, PVAs, polyacrylamides, and cellulose derivatives, (B) a copolymer obtained by the copolymerization of a styrene monomer and a cationic monomer, a water-soluble copolymer obtained by the copolymerization of a styrene monomer, a cationic monomer and a hydrophobic monomer, or a water-soluble copolymer obtained by treating one of these copolymers in which a tertiary amine-containing vinyl monomer is used as a cationic monomer, with a quaternizing agent.
摘要翻译： 具有足够的吸水性以提供具有较少的胶版印刷时的颜色配准问题的清晰印刷图像的印刷用新闻纸是通过涂布原纸来制造的，向其中加入硫酸铝（50重量％的Al 2 O 3 在制纸时以小于3.0重量％的比例加入3％（重量）的产物），表面处理剂主要由（A）水 选自淀粉，PVA，聚丙烯酰胺和纤维素衍生物的可溶性大分子物质，（B）通过苯乙烯单体和阳离子单体的共聚获得的共聚物，通过苯乙烯单体共聚得到的水溶性共聚物，阳离子性 单体和疏水性单体，或通过用季铵化剂处理其中含有含叔胺的乙烯基单体的这些共聚物之一得到的水溶性共聚物。
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公开(公告)号：US06932887B2
公开(公告)日：2005-08-23
申请号：US10264178
申请日：2002-10-03
CPC分类号： D21H17/28 , B41M1/06 , B41M5/5236 , Y10T442/20 , Y10T442/2402 , Y10T442/2762 , Y10T442/277
摘要： A surface-treatment agent containing at least one type of processed starch selected from a) to c) as listed below is applied to a base paper of a newspaper so that a product of a B-type viscosity of the surface-treatment agent, measured under conditions of 10% concentration at 50° C. (rotor No. 1 at 60 rpm), and an application amount of the surface-treatment agent (both sides) is within a range of 2 to 15 cps·g/m2; a) Etherified starch, which is etherified by the compound defined in the general formula (1) given below: (AO)nH (1) wherein A represents an ethylene group or propylene group, while n represents an integer of 1 to 15, b) Carboxylic acid esterified starch, which is esterified by monocarboxylic acid or dicarboxylic acid containing a linear, branched or cyclic alkyl group or alkenyl group having carbon atoms of 4 to 18, and c) Aldehyde starch.
摘要翻译： 将包含至少一种选自a）至c）的加工淀粉的表面处理剂施加到报纸的原纸上，使得表面处理剂的B型粘度的产物被测量 在50℃下10％浓度的条件下（转子No.1以60rpm），表面处理剂（两面）的涂布量在2〜15cps.g / m·SUP > 2 ; （a）通过下述通式（1）中定义的化合物醚化的醚化淀粉：<？in-line-formula description =“In-line formula”end =“lead”？>（AO） 其中A表示亚乙基或亚丙基，n表示1〜15的整数，n表示1〜15的整数，n表示1〜15的整数， b）羧酸酯化淀粉，其通过一元羧酸或含有碳原子数为4〜18的直链，支链或环状烷基或烯基的二羧酸酯化，和c）醛淀粉。
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公开(公告)号：US20100170650A1
公开(公告)日：2010-07-08
申请号：US12659438
申请日：2010-03-09
IPC分类号： D21H23/22
CPC分类号： D21H19/20
摘要： A printability improving agent for use in a neutral newsprint base paper which is printed with ecological inks, containing (I) a cationic copolymer obtained by polymerizing one or more hydrophobic monomer unit(s) selected from styrenes and alkyl acrylates and/or alkyl methacrylates with a quaternary ammonium salt-containing monomer unit, and (II) a copolymer obtained by polymerizing 100 parts by weight of one or more hydrophobic monomer(s) selected from the group above in the presence of 1-10 parts by weight of a surfactant.
摘要翻译： 一种用于印刷生态油墨的中性新闻纸原纸中的可印刷性改进剂，其包含（I）通过将选自苯乙烯和丙烯酸烷基酯和/或甲基丙烯酸烷基酯中的一种或多种疏水性单体单元聚合而获得的阳离子共聚物与 含有季铵盐的单体单元，和（II）通过在1-10重量份表面活性剂的存在下聚合100重量份的选自上述的一种或多种疏水性单体得到的共聚物。
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公开(公告)号：US07691231B2
公开(公告)日：2010-04-06
申请号：US10563621
申请日：2004-06-24
CPC分类号： D21H21/16 , D21H17/28 , D21H17/35 , D21H17/36 , D21H17/375 , Y10T428/273 , Y10T428/277
摘要： Newsprint for offset printing having sufficient water absorption resistance to provide a clear printing image with less color registration problems upon offset printing is manufactured by coating base paper, to which aluminum sulfate (a 50% by weight Al2O3.14H2O product) is added at a ratio of less than 3.0% by weight upon paper making, with a surface treating agent mainly comprised of (A) a water-soluble macromolecular substance selected from starches, PVAs, polyacrylamides, and cellulose derivatives, (B) a copolymer obtained by the copolymerization of a styrene monomer and a cationic monomer, a water-soluble copolymer obtained by the copolymerization of a styrene monomer, a cat ionic monomer and a hydrophobic monomer, or a water-soluble copolymer obtained by treating one of these copolymers in which a tertiary amine-containing vinyl monomer is used as a cationic monomer, with a quaternizing agent.
摘要翻译： 印刷胶版印刷具有足够的耐吸水性以提供在胶版印刷时具有较少颜色配准问题的清晰印刷图像，通过涂布原纸制成，其中加入硫酸铝（一种50重量％的Al 2 O 3·14H 2 O产品） 造纸时重量小于3.0％，主要由（A）选自淀粉，PVAs，聚丙烯酰胺和纤维素衍生物的水溶性大分子物质组成的表面处理剂，（B）通过共聚获得的共聚物 苯乙烯单体和阳离子单体，通过苯乙烯单体，阳离子单体和疏水性单体的共聚获得的水溶性共聚物，或通过处理这些共聚物之一得到的水溶性共聚物，其中含叔胺 使用乙烯基单体作为阳离子单体与季铵化剂。
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公开(公告)号：US08377260B2
公开(公告)日：2013-02-19
申请号：US13212722
申请日：2011-08-18
CPC分类号： D21H17/675 , D21H11/14 , Y10T428/24934
摘要： A method of manufacturing a newsprint paper for offset printing, includes: selecting a filler or fillers having an average grain size of 0.5 to 5 μm and a zeta potential of 0 mV or above; providing a pulp slurry for making a base paper; adding the filler or fillers to the pulp slurry in an amount of more than 15 percent by weight but less than 40 percent by weight as ash relative to the dry weight of the base paper; and subjecting the resultant slurry to a papermaking machine to obtain the base paper.
摘要翻译： 一种胶版印刷用新闻纸的制造方法，包括：选择平均粒径为0.5〜5μm，ζ电位为0mV以上的填料或填料; 提供用于制造原纸的纸浆; 以相对于原纸的干重为灰分，以大于15重量％但小于40重量％的量将浆料或填料添加到纸浆中; 并将得到的浆料经造纸机取得原纸。
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公开(公告)号：US20110303377A1
公开(公告)日：2011-12-15
申请号：US13212722
申请日：2011-08-18
CPC分类号： D21H17/675 , D21H11/14 , Y10T428/24934
摘要： A method of manufacturing a newsprint paper for offset printing, includes: selecting a filler or fillers having an average grain size of 0.5 to 5 μm and a zeta potential of 0 mV or above; providing a pulp slurry for making a base paper; adding the filler or fillers to the pulp slurry in an amount of more than 15 percent by weight but less than 40 percent by weight as ash relative to the dry weight of the base paper; and subjecting the resultant slurry to a papermaking machine to obtain the base paper.
摘要翻译： 一种胶版印刷用新闻纸的制造方法，包括：选择平均粒径为0.5〜5μm，ζ电位为0mV以上的填料或填料; 提供用于制造原纸的纸浆; 以相对于原纸的干重为灰分，以大于15重量％但小于40重量％的量将浆料或填料添加到纸浆中; 并将得到的浆料经造纸机取得原纸。
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公开(公告)号：US20090162642A1
公开(公告)日：2009-06-25
申请号：US12162325
申请日：2007-01-26
申请人： Katsumasa Ono , Koji Kutsuwa , Tomohiro Yokohara , Fuminari Nonomura , Masayuki Watanabe , Hiroshi Koyamoto , Akinobu Chatani , Yoshiharu Kimura , Takao Sezaki
发明人： Katsumasa Ono , Koji Kutsuwa , Tomohiro Yokohara , Fuminari Nonomura , Masayuki Watanabe , Hiroshi Koyamoto , Akinobu Chatani , Yoshiharu Kimura , Takao Sezaki
CPC分类号： G03G7/0033 , D21H17/24 , D21H17/45 , D21H17/67 , D21H19/10 , D21H19/36 , G03G7/0046 , Y10T428/25 , Y10T428/258
摘要： Provide a paper offering good paper strength properties in terms of strength and stiffness, high smoothness and excellent printing quality by adjusting the ash content in paper to a range of 3 to 40 percent by solid weight and allowing the paper to contain a pre-coagulated filler having an average particle size of 10 to 80 μm as measured by the laser diffraction method, wherein such filler is obtained by processing a filler using a composite acrylamide copolymer comprising (A) an anionic polysaccharide and (B) a cationic and/or amphoteric acrylamide copolymer.
摘要翻译： 通过将纸张中的灰分含量调整到固体重量的3〜40％范围内，提供纸张强度和刚度，高平滑度和优异的印刷质量的纸张，并使纸张含有预凝固填料 通过激光衍射法测量的平均粒度为10至80μm，其中通过使用包含（A）阴离子多糖和（B）阳离子和/或两性丙烯酰胺的复合丙烯酰胺共聚物加工填料获得这种填料 共聚物。
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9.发明授权Slipping property imparting agent for clear coating and clear coating paper having the agent applied thereon 失效用于透明涂层的滑动性赋予剂和施加有该试剂的透明涂布纸公开(公告)号：US07348065B2
公开(公告)日：2008-03-25
申请号：US10509226
申请日：2003-03-26
IPC分类号： B32B23/08
摘要： Produce a slipping property imparting agent for clear coat that reduces scum production: wherein, (1) the agent comprises a copolymer whose constituents are unsaturated olefin (constituent (a)) and unsaturated carboxylic acid (carboxylate) (constituent (b)); (2) constituent (a) accounts for 50 to 99 mol percent and constituent (b) accounts for 50 to 1 mol percent, respectively, of the total mol number of constituents (a) and (b) combined; and (3) a constituent (c) that can be polymerized with the constituents (a) and (b) is contained, as necessary, by up to 20 mol percent of the total mol number of constituents (a) and (b) combined.
摘要翻译： 制备减少浮渣生产的透明涂层的滑动性赋予剂：其中，（1）该试剂包含其成分为不饱和烯烃（组分（a））和不饱和羧酸（羧酸酯）（组分（b））的共聚物; （2）成分（a）占组合物（a）和（b）总摩尔数的50〜99摩尔％，成分（b）分别占组合物总摩尔数的50〜1摩尔％ 和（3）可以根据需要含有组分（a）和（b）可以聚合的组分（c）至多20摩尔％的组分（a）和（b）的总摩尔数组合 。
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公开(公告)号：US20080023163A1
公开(公告)日：2008-01-31
申请号：US11630787
申请日：2005-06-23
IPC分类号： D21H19/20
CPC分类号： D21H19/20
摘要： The present invention aims to provide printability improving agents and surface-treating agents capable of improving offset printability of papers, especially newsprint papers to be printed with offset inks as well as papers, especially newsprint papers that can be successfully printed with offset inks. According to a first aspect of the present invention, a printability improving agent comprising a cationic copolymer consisting of one or more hydrophobic monomer unit(s) selected from a specific group and a quaternary ammonium salt-containing monomer unit or a surface-treating agent comprising the printability improving agent and a water-soluble polymer material selected from a specific group is applied on the surface of a base paper, especially a newsprint base paper. According to a second aspect of the present invention, a hydrophobic monomer unit selected from a specific group and a quaternary ammonium salt-containing monomer unit is polymerized to give a cationic copolymer, which is then further polymerized with a hydrophobic monomer to give a copolymer. Alternatively, a hydrophobic monomer unit selected from a specific group and a quaternary ammonium salt-containing monomer unit is polymerized to give a cationic copolymer, which is further polymerized with a hydrophobic monomer in the presence of a surfactant to give a copolymer. A printability improving agent comprising the copolymer or a surface-treating agent comprising the printability improving agent and a water-soluble polymer material selected from a specific group is applied on the surface of a base paper, especially a newsprint base paper.
摘要翻译： 本发明的目的在于提供可印刷性提高剂和表面处理剂，其能够改善纸，特别是用胶印油墨印刷的新闻纸的胶版印刷性，以及纸，特别是可以用胶印油墨成功印刷的新闻纸。 根据本发明的第一方面，提供了一种包含阳离子共聚物的可印花改性剂，所述阳离子共聚物由选自特定基团和含季铵盐单体单元的一种或多种疏水性单体单元或表面处理剂组成， 将可印刷性改进剂和选自特定组的水溶性聚合物材料施加在原纸，特别是新闻纸原纸的表面上。 根据本发明的第二方面，将选自特定基团和含季铵盐的单体单元的疏水性单体单元聚合，得到阳离子共聚物，然后与疏水性单体进一步聚合，得到共聚物。 或者，将选自特定基团和含季铵盐的单体单元的疏水性单体单元聚合，得到阳离子共聚物，其在表面活性剂存在下进一步与疏水性单体聚合，得到共聚物。 包含共聚物或包含可印刷性改进剂的表面处理剂和选自特定组的水溶性聚合物材料的可印刷性改进剂施加在原纸，特别是新闻纸原纸的表面上。
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